IP Library Granted Patent US 12,338,144
Granted Patent B2
US 12,338,144 · App. 16/621,930 · Granted Jun 24, 2025

Decontamination of fluids via joule-heating

Inventors: Jason Patrick Trembly (Athens, OH); David Drown Ogden (Athens, OH)
Assignee: Ohio University
C02F1/4608C02F1/06C02F1/52C02F2201/46C02F2209/03
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Quick Facts
Patent No.
US 12,338,144
App. No.
16/621,930
Granted
Jun 24, 2025
Kind
B2
Abstract

A method of, and apparatus and system for, decontaminating a liquid containing dissolved solids including subjecting liquid containing dissolved solids to Joule heating under conditions effective to cause said dissolved solids to precipitate out of solution.

Claims (23)

1. An apparatus to decontaminate a liquid including dissolved solids comprising:

a reactor having a first electrode and a second electrode; and

a liquid flow path between said first and second electrodes, wherein the reactor is adapted to generate electrical current such that liquid in the liquid flow path reaches at least a pseudocritical temperature, and wherein the reactor is incapable of generating the electrical current such that the liquid in the liquid flow path reaches a temperature indicative of electrolysis.

2. The apparatus of claim 1 , wherein said first electrode comprises a wall of said reactor.

3. The apparatus of claim 2 , wherein at least a portion of said wall defines an interior space of said reactor, and wherein at least a portion of said second electrode is disposed within said interior space.

4. The apparatus of claim 3 , wherein said reactor is tubular and said second electrode runs along a length of said tubular reactor.

5. The apparatus of claim 3 , further comprising at least one electrode sealing fitting that insulates said wall of said reactor from said second electrode.

6. The apparatus of claim 5 , further comprising an alumina insulator associated with said at least one electrode sealing fitting.

7. The apparatus of claim 3 , further comprising an alumina insulating washer positioned between a first piece and a second piece of the second electrode to prevent ejection of the second piece from the first piece.

8. The apparatus of claim 2 , wherein said wall of said reactor includes a material that is corrosion-resistant.

9. The apparatus of claim 8 , wherein said material includes a high nickel alloy.

10. The apparatus of claim 1 , further comprising a liquid inlet and a liquid outlet located in a first section of said reactor, and a vapor outlet located in a second section of said reactor.

11. The apparatus of claim 10 , wherein said vapor outlet is connected to said liquid outlet.

12. The apparatus of claim 10 , wherein said first section of said reactor is a lower section, and said second section of said reactor is an upper section.

13. The apparatus of claim 1 , further comprising a pressure regulator.

14. An apparatus to decontaminate a liquid including dissolved solids comprising:

a reactor having a first electrode and a second electrode;

an alumina insulating washer positioned between a first piece and a second piece of the second electrode to prevent ejection of the second piece from the first piece; and

a liquid flow path between said first and second electrodes.

15. An apparatus to decontaminate a liquid including dissolved solids comprising:

a reactor having a first electrode and a second electrode, wherein said first electrode comprises a wall of said reactor, wherein at least a portion of said wall defines an interior space of said reactor, and wherein at least a portion of said second electrode is disposed within said interior space;

an alumina insulating washer positioned between a first piece and a second piece of the second electrode to prevent ejection of the second piece from the first piece; and

a liquid flow path between said first and second electrodes.

Assignments (2)
CONFIRMATORY LICENSE Recorded Apr 24, 2020
From: OHIO UNIVERSITY ATHENS
To: UNITED STATES DEPARTMENT OF ENERGY
Reel/Frame 052492/0092 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Feb 7, 2020
From: TREMBLY, JASON PATRICK; OGDEN, DAVID DROWN
To: OHIO UNIVERSITY
Reel/Frame 051750/0346 →
Continuity (2)
Provisional Application 62527248 · Jun 30, 2017
Related Publication 20200115258A1 · Apr 16, 2020
References Cited (77)
US 3686474A · Power · 1972 [cited by examiner]
US 20030196938A1 · Arnaud · 2003 [cited by examiner]
US 20110011801A1 · Cho · 2011 [cited by applicant]
US 20110108491A1 · Lean et al. · 2011 [cited by applicant]
US 20110244305A1 · Zhang · 2011 [cited by examiner]
US 20140054242A1 · Imai · 2014 [cited by examiner]
US 20140346114A1 · Trembly · 2014 [cited by applicant]
US 20140360885A1 · Pajari · 2014 [cited by examiner]
WO WO2014174309A1 · 2014 [cited by examiner]
Pseudocritical line—Pseudocritical points, nuclear-power.com, available at https://shorturl.at/zK068. (Year: 2023). [cited by examiner]
Specific Heat Calculator, omnicalculator.com, https://www.omnicalculator.com/physics/specific-heat (last visited Jul. 13, 2023). (Year: 2023). [cited by examiner]
Heat Capacity and Specific Heat, chem.libretexts.org, available at https://shorturl.at/iowA9 (last visited Jul. 13, 2023). (Year: 2023). [cited by examiner]
Facts About Platinum, LiveScience.org, https://www.livescience.com/39144-platinum.html (last visited Mar. 26, 2022). (Year: 2022). [cited by examiner]
Shaffer, D. L. et al., “Desalination and Reuse of High-Salinity Shale Gas Produced Water: Drivers, Technologies, and Future Directions,” Environ. Sci. Technol., vol. 47, No. 17, pp. 9569-9583, Sep. 2013. [cited by applicant]
Thiel, G. P. et al., “Energy consumption in desalinating produced water from shale oil and gas extraction,” Desalination, p. 94, 2015. [cited by applicant]
Toner, J. D. et al., “A Low-Temperature Thermodynamic Model for the Na—K—Ca—Mg—Cl System Incorporating New Experimental Heat Capacities in KCl, MgCl2 , and CaCl2 Solutions,” Journal of Chemical & Engineering Data, vol. … [cited by applicant]
Van Wyk, S. et al., “Design and results of a first generation pilot plant for supercritical water desalination (SCWD),” Desalination, vol. 439, pp. 80-92, Aug. 2018. [cited by applicant]
Veil, J. A. et al., “NORM disposal options, costs vary,” Oil Gas J., vol. 97, No. 1, pp. 37-43, 1999. [cited by applicant]
Veil, J. A. et al., “Produced water volume estimates and management practices,” SPE Production & Operations, vol. 26, No. 03, pp. 234-239, 2011. [cited by applicant]
Zhang, T. et al., “Co-precipitation of Radium with Barium and Strontium Sulfate and Its Impact on the Fate of Radium during Treatment of Produced Water from Unconventional Gas Extraction,” Environ. Sci. Technol., vol. 4… [cited by applicant]
Ziemkiewicz, P. F. et al., “Evolution of water chemistry during Marcellus Shale gas development: A case study in West Virginia,” Chemosphere, vol. 134, pp. 224-231, Sep. 2015. [cited by applicant]
Zoback, M. et al., “Addressing the environmental risks from shale gas development,” Worldwatch Institute, Briefing Paper, Jul. 2010. [cited by applicant]
International Search Report and Written Opinion in International Patent Application No. PCT/US2018/040327, mailed Nov. 19, 2018, 11 pgs. [cited by applicant]
Pioro et al., “Thermophysical Properties at Critical and Supercritical Conditions”, Jan. 28, 2011 (Jan. 28, 2011); retrieved on Aug. 30, 2018 from <https://www.intechopen.com/books/heat-transfer-theoretical-analysis-exp… [cited by applicant]
Wikipedia, “Joule heating”, Apr. 5, 2017 (Apr. 5, 2017), retrieved on Aug. 30, 2018 from <https://en.wikipedia.org/w/index.php?title=Joule_heating&oldid=773933488> ; entire document, especially p. 1 para 1, p. 2 para 5. [cited by applicant]
Pioro, et al., Thermophysical Properties at Critical and Supercritical Pressures, Heat Transfer—Theoretical Analysis, Experimental Investigations and Industrial Systems, Jan. 2011, pp. 573-592, IntechOpen, London, UK. [cited by applicant]
Todd, et al., Corrigendum to “Thermodynamics of high-temperature, high-pressue water electrolysis”, Journal of Power Sources 289, 2015, pp. 184-186, Elsevier B.V., Netherlands. [cited by applicant]
Abdullah, J. A. et al., “An innovative procedure for NORM scales treatment and radionuclides separation,” Appl. Radiat. Isot., vol. 125, pp. 139-143. [cited by applicant]
Adams, L. H. et al., “Equilibrium in binary systems under pressure. I. An experimental and thermodynamic investigation of the system, NaCl—H2O, at 25°,” Journal of the American Chemical Society, vol. 53, No. 10, pp. 376… [cited by applicant]
Archer, D., “Thermodynamic properties of NaCl+H2O system I. Thermodynamic properties of NaCl(cr),” Journal of Physical and Chemical reference Data, vol. 21, No. 1, p. 121, 1992. [cited by applicant]
Archer, D., “Thermodynamic properties of NaCl+H2O system II. Thermodynamic properties of NaCl(aq), NaCl—2H2O(cr), and phase equilibria,” Journal of Physical and Chemical reference Data, vol. 21, No. 4, pp. 793-829, 1992. [cited by applicant]
Armellini, F. “Phase equilibria and precipitation phenomena of sodium chloride and sodium sulfate in sub- and supercritical water,” Massachusetts Institute of Technology, 1993. [cited by applicant]
Bames, H. L. et al., “Chemical aspects of acid mine drainage,” Water Polution Control Federation, vol. 40, No. 3, pp. 371-384, Mar. 1968. [cited by applicant]
Benavides, P. T. et al., “Optimal design of adsorbents for NORM removal from produced water in natural gas fracking. Part 1: Group contribution method for adsorption,” Chem. Eng. Sci., vol. 137, pp. 964-976, Dec. 2015. [cited by applicant]
Benavides, P. T. et al., “Optimal design of adsorbents for NORM removal from produced water in natural gas fracking. Part 2: CAMD for adsorption of radium and barium,” Chem. Eng. Sci., vol. 137, pp. 977-985, Dec. 2015. [cited by applicant]
Bergmo, P. E. S. et al., “Simultaneous CO2 injection and water production to optimise aquifer storage capacity,” International Journal of Greenhouse Gas Control, vol. 5, No. 3, pp. 555-564, May 2011. [cited by applicant]
Bischoff, J. L. et al., “Liquid-vapor relations for the system NaCl—H2O: summary of the P-T-x surface from 300° to 500° C.,” American Journal of Science, vol. 289, pp. 217-248, 1989. [cited by applicant]
Bischoff, J. L. et al., “The system NaCl—H2O: Relations of vapor-liquid near the critical temperature of water and of vapor-liquid-halite from 300° to 500° C.,” Geochim. Cosmochim. Acta, vol. 50, No. 7, pp. 1437-1444, 1… [cited by applicant]
Blondes, M. S. et al., “US Geological Survey National Produced Waters Geochemical Database v2. 3 (Provisional) Documentation,” USGS Dec. 2017. [cited by applicant]
Blount, C. W. et al., “The solubility of anhydrite (CaSO4) in NaCl—H2Ofrom 100 to 450° C. and 1 to 1000 bars,” Geochimica et Cosmochimica Acta, vol. 33, pp. 227-245, Jan. 1969. [cited by applicant]
Brown, P. L. et al., “Hydrolysis of magnesium(II) at elevated temperatures,” J. Chem. Soc., Dalton Trans., 1996, pp. 3071-3075. [cited by applicant]
Clark, C. E. et al., “Produced water volumes and management practices in the United States,” Argonne National Laboratory (ANL), 2009. [cited by applicant]
Coday, B. D. et al., “Forward Osmosis: Novel desalination of produced water and fracturing flowback,” Journal American Water Works Association, vol. 106, pp. E55-E66, Feb. 2014. [cited by applicant]
Dastgheib, S. A. et al., “Produced Water from CO2-EOR in the Illinois Basin,” Energy Procedia, vol. 63, pp. 6878-6886, 2014. [cited by applicant]
DiPippo, M. M. et al., “Ternary phase equilibria for the sodium chloride-sodium sulfate-water system at 200 and 250 bar up to 400° C.,” Fluid Phase Equilibria, vol. 157, No. 2, pp. 229-255, 1999. [cited by applicant]
Dong, et al., “Techno-economic analysis of hydraulic fracking flowback and produced water treatment in supercritical water reactor,” Energy, vol. 133, pp. 777-783, Aug. 2017. [cited by applicant]
Driesner, T. et al., “The system H2O—NaCl. Part I: Correlation formulae for phase relations in temperature-pressure-composition space from 0 to 1000° C., 0 to 5000 bar, and 0 to 1 XNaCl,” Geochimica et Cosmochimica Acta… [cited by applicant]
Driesner, T., “The system H2O—NaCl. Part II: Correlations for molar volume enthalpy, and isobaric heat capacity from 0 to 1000° C., 1 to 5000 bar, and 0 to 1 XNaCl,” Geochimica et Cosmochimica Acta, vol. 71, pp. 4902-49… [cited by applicant]
Fan, W. et al., “Radium-226 Removal from Simulated Produced Water Using Natural Zeolite and Ion-Exchange Resin,” Ind. Eng. Chem. Res., vol. 55, No. 48, pp. 12502-12505, Dec. 2016. [cited by applicant]
Gray, M. R. et al., “Kinetics of Hydrolysis of Chloride Salts in Model Crude Oil,” Pet. Sci. Technol., vol. 26, No. 16, pp. 1924-1933, Oct. 2008. [cited by applicant]
Greenlee, L. F. et al., “Reverse osmosis desalination: Water sources, technology, and today's challenges,” Water Res., vol. 43, No. 9, pp. 2317-2348, May 2009. [cited by applicant]
Guerra, K. et al., “Oil and gas producted water management and beneficial use in the westem United States,” U.S. Department of Interior Bureau of Reclamation, 157, Sep. 2011. [cited by applicant]
Haluszczak, L. O. et al., “Geochemical evaluation of flowback brine from Marcellus gas wells in Pennsylvania, U.S.A.,” Applied Geochemistry, vol. 28, pp. 55-61, Jan. 2013. [cited by applicant]
Hardy, A. et al., “NORM Mitigation and Clean Water Recovery from Marcellus Produced Water,” p. 143. [cited by applicant]
Heijman, S. G. J. et al., “Zero liquid discharge: Heading for 99% recovery in nanofiltration and reverse osmosis,” Desalination, vol. 236, No. 1-3, pp. 357-362, Jan. 2009. [cited by applicant]
Hnedkovsky L. et al., “A new version of differential flow heat capacity calorimeter, tests of heat loss corrections and heat capacities of aqueous NaCl from T=300 K to T=623 K,” The Journal of Chemical Thermodynamics, v… [cited by applicant]
Hovey, J. K. et al., “Vapor-liquid phase equilibria of potassium chloride-water mixtures: equation-of-state representation for KCl—H2O and NaCl—H2O,” Journal of Physical Chemistry, vol. 94, No. 3, pp. 1175-1179, 1990. [cited by applicant]
Kaplan, R. et al., “Assessment of desalination technologies for treatment of a highly saline brine from a potential CO2 storage site,” Desalination, vol. 404, pp. 87-101, Feb. 2017. [cited by applicant]
Keevil, N. B., “Vapor pressures of aqueous solutions at high temperatures,” Journal of the American Chemical Society, vol. 64, No. 4, pp. 841-850, 1942. [cited by applicant]
Konikow, L. F., “Long-Term Groundwater Depletion in the United States,” Groundwater, vol. 53, No. 1, pp. 2-9, 2015. [cited by applicant]
Land, L. S. et al., “The origin and evolution of saline formation water, lower cretaceous carbonates, south-central Texas, U.S.A.,” Joumal of Hydrology, vol. 54, No. 1-3, pp. 51-74, 1981. [cited by applicant]
Leusbrock, I. et al., “Quantitative approaches for the description of solubilities of inorganic compounds in near-critical and supercritical water,” J. of Supercritical Fluids 47 (2008) 117-127. [cited by applicant]
Leusbrock, I. et al., “Solubility of 1:1 Alkali Nitrates and Chlorides in Near-Critical and Supercritical Water,” Journal of Chemical & Engineering Data, vol. 54, No. 12, pp. 3215-3223, Dec. 2009. [cited by applicant]
Leusbrock, I. et al., “The solubility of magnesium chloride and calcium chloride in near-critical and supercritical water,” The Journal of Supercritical Fluids, vol. 53, No. 1-3, pp. 17-24, Jun. 2010. [cited by applicant]
Leusbrock, I., “Removal of inorganic compounds via supercritical water,” University of Groningen, 2011. [cited by applicant]
Lopez, D. E. et al., “Desalination of hypersaline brines with joule-heating and chemical pre-treatment: Conceptual design and economics,” Desalination, vol. 415, pp. 49-57, Aug. 2017. [cited by applicant]
Mangelson, K. A. et al., “Removing and disposing of radium from well water,” J. Am. Water Works Assoc., vol. 82, No. 6, pp. 72-76, 1990. [cited by applicant]
Mielke, E. et al., “Water Consumption of Energy Resource Extraction, Processing, and Conversion,” Energy Technology Innovation Policy Research Group, Oct. 2010. [cited by applicant]
Moon, D. et al., “Preconcentration of radium isotopes from natural waters using MnO2 Resin,” Appl. Radiat. Isot., vol. 59, No. 4, pp. 255-262, Oct. 2003. [cited by applicant]
Odu, S. O. et al., “Design of a process for supercritical water desalination with zero liquid discharge,” Industrial and Engineering Chemistry Research, vol. 54, pp. 5527-5535, 2015. [cited by applicant]
Ogden, D. D. et al., “Desalination of hypersaline brines via Joule-heating: Experimental investigations and comparison of results to existing models,” Desalination, vol. 424, pp. 149-158, Dec. 2017. [cited by applicant]
Oren, Y. et al., “Pilot studies on high recovery BWRO-EDR for near zero liquid discharge approach,” Desalination, vol. 261, No. 3, pp. 321-330, Oct. 2010. [cited by applicant]
Palliser, C. et al., “A model for deep geothermal brines, II: thermodynamic properties—density,” Transport in Porous Media, vol. 33, pp. 129-154, 1998. [cited by applicant]
Palliser, C., “A model for deep geothermal brines: state space description and thermodymanic properties,” Massey University, 1998. [cited by applicant]
Rubinstein, J. L. et al., “Myths and Facts on Wastewater Injection, Hydraulic Fracturing, Enhanced Oil Recovery, and Induced Seismicity,” Seismol. Res. Lett., vol. 86, No. 4, pp. 1060-1067, Jul. 2015. [cited by applicant]
Savage, P. E. et al., “Reactions at supercritical conditions: Applications and fundamentals,” AIChE Journal, vol. 41, No. 7, pp. 1723-1778, Jul. 1995. [cited by applicant]
Schubert, M. et al., “Continuous salt precipitation and separation from supercritical water. Part 2. Type 2 salts and mixtures of two salts,” The Journal of Supercritical Fluids, vol. 52, No. 1, pp. 113-124, Feb. 2010. [cited by applicant]