Scalable fabrication of pristine holey graphene nanoplatelets via dry microwave irradiation
View Patent ↗Disclosed are the methods for fabricating holey graphene nanoplatelets using microwave irradiation to treat a dry graphite powder. In particular, the methods can be used to treat graphite intercalation compounds either with or without partial oxidation to obtain holey graphene nanoplatelets with predetermined hole size, hole edge shape, thickness and lateral dimension. The method does not involve any toxic reagents or metal-containing compounds, and without generating toxic byproducts, thus enabling a variety of eco-friendly applications.
1. A method for fabricating holey graphene nanoplatelets, the method comprising:
subjecting partially oxidized graphite intercalation compounds (PO-GICs), oxygen intercalated graphite intercalation compounds (OI-GICs), or commercial expandable graphite (CEG) to one or more microwave irradiation treatments to obtain holey graphene nanoplatelets,
wherein the holey graphene nanoplatelets comprise one or more expanded graphene sheets having a plurality of holes on the basal planes thereof, and
wherein the microwave irradiation treatments further comprise: a first microwave irradiation to remedy existing defects on the basal planes of the expanded graphene sheets; a second microwave irradiation to generate baby holes on the basal planes of the expanded graphene sheets; and a third microwave irradiation to obtain the plurality of holes by fine-tuning the generated baby holes, such that the expanded graphene sheets of the holey graphene nanoplatelets have a predetermined number of holes of predetermined size and geometry on the basal planes of the expanded graphene sheets.
2. The method of claim 1 , wherein the partially oxidized graphite intercalation compounds (PO-GICs) are prepared by:
adding graphite flakes to a mixture of ammonium persulfate and sulfuric acid to form a reversible graphite intercalation compound;
purging the mixture containing the reversible graphite intercalation compound with oxygen gas; and
heating the mixture to obtain the partially oxidized graphite intercalation compounds (PO-GICs).
3. The method of claim 1 , wherein the partially oxidized graphite intercalation compounds (PO-GICs) are prepared by:
exposing graphite flakes to a mixture of hydrogen peroxide and sulfuric acid.
4. The method of claim 1 , wherein the oxygen intercalated graphite intercalation compounds (OI-GICs) are prepared by:
adding graphite flakes to a mixture of ammonium persulfate and sulfuric acid to form a reversible graphite intercalation compound; and
purging the mixture containing the reversible graphite intercalation compound with oxygen gas.
5. The method of claim 1 , wherein the oxygen intercalated graphite intercalation compounds (OI-GICs) are oxygen intercalated few layer graphene (OIG).
6. The method of claim 5 , wherein the oxygen intercalated few layer graphene (OIG) is prepared by:
adding few layer graphene platelets to a mixture of ammonium persulfate and sulfuric acid to form a reversible graphite intercalation compound; and
purging the mixture containing the reversible graphite intercalation compound with oxygen gas.
7. The method of claim 2 , wherein the step of purging the mixture comprises purging the mixture containing the reversible graphite intercalation compound with oxygen gas at a rate of between about 90 ml/min and about 120 ml/min for a period of between about 30 minutes and about 120 minutes.
8. The method of claim 1 , wherein one or more parameters of the microwave irradiation treatments are selected to induce a Joule heating mechanism or a combination of a Joule heating mechanism and a micro-plasma etching mechanism to obtain a predetermined number of holes of predetermined size and geometry on the basal planes of the expanded graphene sheets, one or more parameters comprising duration, power, and intervals of microwave irradiation pulses.
9. The method of claim 1 , wherein the microwave irradiation treatments comprise one or more microwave irradiation pulses at the power of between about 10 Watt and about 300 Watt for a period of about 3 seconds and about 150 seconds.
10. The method of claim 1 , wherein said plurality of holes have a geometrical structure of hole edges predominantly in a zigzag configuration.
11. The method of claim 1 , wherein said plurality of holes are uniformly distributed across the basal planes of the expanded graphene sheets.
12. The method of claim 1 , wherein the mean hole size of said plurality of holes is about 5 nm to about 500 nm.
13. The method of claim 1 , wherein the mean thickness of the holey graphene nanoplatelets is from about 0.4 nm to about 14 nm.
14. The method of claim 1 , wherein the mean lateral dimension of the holey graphene nanoplatelets is from about 0.5 μm to about 20 μm.
15. The method of claim 1 , wherein the holey graphene nanoplatelets have a conductivity between about 7000 S/m and about 100,000 S/m.
16. The method of claim 1 , wherein the holey graphene nanoplatelets have a C:O molar ratio between 15:1 and 55:1.
17. Holey graphene nanoplatelets prepared by the method according to claim 1 , wherein the plurality of holes having a geometrical structure of hole edges predominantly in a zigzag configuration, and wherein the holey graphene nanoplatelets have a conductivity between about 7000 S/m and about 100,000 S/m.
18. The holey graphene nanoplatelets of claim 17 , wherein the holey graphene nanoplatelets have a C:O ratio between 15:1 and 55:1.
19. A product comprising the holey graphene nanoplatelets of claim 17 , wherein the product is electrodes of batteries or electrodes of capacitors.