Electrolyte solution including multi-cyano compound additive and battery including the same
The present application relates to the field of energy storage materials, and particularly, to an electrolytic solution and a battery using the electrolytic solution. The electrolytic solution of the present application contains an additive, the additive including a multi-cyano compound represented by formula (I). The multi-cyano compound of the present application has a stronger complexation with a transition metal on the surface of a positive electrode material, and therefore a protective film can be formed on the surface of the positive electrode material, and the dissolution of the transition metal is effectively suppressed; the surface activity of the positive electrode material is reduced, thereby suppressing side reactions, such as the decomposition of the electrolytic solution on the surface of the positive electrode material; and the cycle performance and storage performance of a battery under wide range of working voltage and wide range of operating temperature conditions are thus improved.
1. An electrolytic solution, comprising an additive,
the additive comprising a multi-cyano compound,
wherein the multi-cyano compound is at least one of compounds represented by Formula I-2:
wherein R 21 , R 22 , R 23 , and R 24 are each independently selected from the group consisting of a substituted or unsubstituted C 2 -C 8 carbalkoxy, a substituted or unsubstituted C 7 -C 16 aromatic ester group, a substituted or unsubstituted C 2 -C 8 alkylcarbonyl, and a substituted or unsubstituted C 7 -C 16 arylcarbonyl,
at least one of R 21 , R 22 , R 23 , and R 24 is a substituted or unsubstituted C 7 -C 16 aromatic ester group, a substituted or unsubstituted C 2 -C 8 alkylcarbonyl, or a substituted or unsubstituted C 7 -C 16 arylcarbonyl,
the substituent, if present, is selected from the group consisting of halogen, cyano, C 1 -C 6 alkyl, and combinations thereof.
2. The electrolytic solution according to claim 1 , wherein a mass percentage of the multi-cyano compound in the electrolytic solution is 0.001% to 10%.
3. The electrolytic solution according to claim 1 , wherein a mass percentage of the multi-cyano compound in the electrolytic solution is 0.1% to 3.5%.
4. The electrolytic solution according to claim 1 , wherein the multi-cyano compound is at least one of compounds represented by Formula I-2a:
5. The electrolytic solution according to claim 1 , wherein the additive further comprises an additive A, and the additive A is selected from the group consisting of an unsaturated cyclic carbonate compound, a halogenated cyclic carbonate compound, a sulfate compound, a sulfite compounds, a sultone compound, a disulfonic acid compound, a nitrile compound, an aromatic compound, an isocyanate compound, a phosphazene compound, a cyclic anhydride compound, a phosphite compound, a phosphate compound, a borate compound, a carboxylate compound, and combinations thereof.
6. The electrolytic solution according to claim 5 , wherein a mass percentage of the additive A in the electrolytic solution is 0.01% to 30%.
7. A battery, comprising a positive electrode plate, a negative electrode plate, a separator disposed between the positive electrode plate and the negative electrode plate, and an electrolytic solution, wherein the electrolytic solution is the electrolytic solution according to claim 1 .
8. The battery according to claim 7 , wherein the battery is a lithium ion battery, wherein a charging cut-off voltage of the battery is not lower than 4.2V.