Expandable, expanding-agent-containing granules based on high-temperature thermoplastics
Expandable, blowing agent-containing pellets based on high temperature thermoplastics having a glass transition temperature according to ISO 11357-2-1999 of at least 180° C., wherein the expandable, blowing agent-containing pellets comprise at least one nucleating agent and have a poured density according to DIN ISO 697:1982 in the range from 400 to 900 kg/m 3 and a mass in the range from 1 to 5 mg/pellet, processes for production thereof and foam particles obtainable therefrom having a glass transition temperature according to ISO 11357-2-1999 of at least 180° C., wherein the expanded foam particles comprise at least one nucleating agent and have a poured density according to DIN ISO 697:1982 in the range from 10 to 200 kg/m 3 , and particle foams obtainable therefrom and the use thereof for producing components for aviation.
1. A process for producing expandable, blowing agent-containing pellets based on high temperature thermoplastics comprising the steps of:
a) producing a polymer melt consisting of at least one polyethersulfone by melting the at least one polyethersulfone having a glass transition temperature according to ISO 11357-2-1999 of at least 180° C. and mixing with at least one nucleating agent in an extruder at temperatures in the range from 320° C. to 350° C.,
b) adding a blowing agent to the polymer melt,
c) cooling the blowing agent-containing polymer melt to a temperature in the range from 180° C. to 215° C.,
d) optionally conveying the polymer melt by means of a gear pump,
e) conveying the blowing agent-containing polymer melt at a temperature in the range from 180° C. to 215° C. through a perforated plate and pelletizing the blowing agent-laden polymer melt in an underwater pelletizer operated at a water temperature in the range from 75° C. to 99° C. and a pressure in the range from 10 to 20 bar.
2. The process according to claim 1 , wherein acetone, isobutane, ethanol, isopropanol, water or mixtures thereof are employed as the blowing agent.
3. The process according to claim 2 , wherein acetone is used as the blowing agent and the expandable blowing agent containing pellets comprise 3% to 15% by weight of the acetone.
4. The process according to claim 1 , wherein talc, titanium dioxide, graphite, carbon black or mixtures thereof are employed as the nucleating agent.
5. The process according to claim 4 , wherein the expandable blowing agent containing pellets comprise as the nucleating agent 0.01% to 2.0% by weight of the talc, the titanium dioxide, the graphite, the carbon black or mixtures thereof based on the sum of the high temperature thermoplastics and the nucleating agent.
6. The process according to claim 1 , wherein mixtures of polyethersulfones having different average molecular weights M w are employed as the polymer.
7. The process according to claim 1 , wherein the expandable, blowing-agent containing pellets have a poured density according to DIN ISO 697:1982 in the range from 400 to 900 kg/m 3 after the pelletizing.