Non-aqueous electrolyte for lithium ion battery and lithium ion battery
Provide is a non-aqueous electrolyte for lithium ion battery, comprising a compound represented by structural formula I: In formula I, R 1 , R 2 , R 3 and R 4 are each independently selected from hydrogen atom, fluorine atom, cyano group, hydrocarbyl group or halogenated hydrocarbyl group having 1-5 carbon atoms, oxygen-containing hydrocarbyl group having 1-5 carbon atoms, silicon-containing hydrocarbyl group having 1-5 carbon atoms, X is a —O—R 5 —CN group, R 5 is a hydrocarbyl group or a halogenated hydrocarbyl group having 1-5 carbon atoms, m, n, z and y are integers of 0 or 1, and m+n+y+z≠0. When the non-aqueous electrolyte is used for lithium ion battery, the decomposition of electrolyte on the surface of electrode can be inhibited, and the high-temperature storage performance is improved with less gas generation and small expansion rate, therefore the high-temperature cycle performance and high-temperature storage performance of the battery are effectively improved.
1. A non-aqueous electrolyte for lithium ion battery, comprising a compound represented by structural formula I:
in formula I, R 1 , R 2 , R 3 and R 4 are each independently selected from hydrogen atom, fluorine atom, cyano group, hydrocarbyl group or halogenated hydrocarbyl group having 1-5 carbon atoms, silicon-containing hydrocarbyl group having 1-5 carbon atoms, X is a —O—R 5 —CN group, R 5 is a hydrocarbyl group or a halogenated hydrocarbyl group having 1-5 carbon atoms, m, n, z and y are integers of 0 or 1, and m+n+y+z≠0.
2. The non-aqueous electrolyte for lithium ion battery according to claim 1 , wherein R 1 , R 2 , R 3 and R 4 are each independently selected from one of hydrogen atom, fluorine atom, cyano group, methyl group, ethyl group, propyl group, butyl group, fluorinated methyl group, fluorinated ethyl group, fluorinated propyl group, fluorinated butyl group, methylene group, ethylidene group, propylidene group, butylidene group, fluorinated methylene group, fluorinated ethylidene group, fluorinated propylidene group, and fluorinated butylidene group.
3. The non-aqueous electrolyte for lithium ion battery according to claim 1 , wherein the compound represented by structural formula I is selected from the group consisting of:
4. The non-aqueous electrolyte for lithium ion battery according to claim 1 , wherein a percentage mass content of the compound represented by structural formula I is 0.1% to 10.0% based on a total mass of the non-aqueous electrolyte for lithium ion battery being 100%.
5. The non-aqueous electrolyte for lithium ion battery according to claim 1 , wherein the non-aqueous electrolyte for lithium ion battery further comprises at least one of unsaturated cyclic carbonate, fluorinated cyclic carbonate, cyclic sultones, cyclic sulfate, and nitriles.
6. The non-aqueous electrolyte for lithium ion battery according to claim 5 , wherein the unsaturated cyclic carbonate is at least one selected from vinylene carbonate, vinylethylene carbonate, and methylene vinyl carbonate;
the fluorinated cyclic carbonate is at least one selected from fluoroethylene carbonate, trifluoromethyl vinyl carbonate and difluoroethylene carbonate;
the cyclic sultones is at least one selected from 1,3- propane sultone, 1,4- butane sultone and propenyl-1,3-sultone;
the cyclic sulfate is at least one selected from ethylene sulfate and 4- methyl vinyl sulfate;
the nitriles are selected from at least one of succinonitrile, adiponitrile, 1,2-bis (2-cyanoethoxy) ethane, 1,4-dicyano-2-butene, hexane-1,3,6-tricarbonitrile, and 1,2,3-tris (2-cyanoethoxy) propane.
7. The non-aqueous electrolyte for lithium ion battery according to claim 5 , wherein based on a total mass of the non-aqueous electrolyte for lithium ion battery being 100%, a percentage mass content of the unsaturated cyclic carbonate is 0.1-5%; a percentage mass content of the fluorinated cyclic carbonate is 0.1-80%; a percentage mass content of the cyclic sultones is 0.1-5%; the a percentage mass content of the unsaturated cyclic sulfate is 0.1-5%; the a percentage mass content of the nitriles is 0.1-5%.
8. The non-aqueous electrolyte for lithium ion battery according to claim 1 , wherein the non-aqueous electrolyte for lithium ion battery comprises a solvent and a lithium salt;
the solvent comprises at least one of cyclic carbonate, chain carbonate, fluorine-containing chain carbonate, carboxylic acid ester, fluorine-containing carboxylic acid ester and fluorine-containing aromatic hydrocarbon;
the lithium salt is selected from at least one of LiPF 6 , LiBF 4 , LiN(SO 2 CF 3 ) 2 , LiN(SO 2 C 2 F 5 ) 2 , LiC(SO 2 CF 3 ) 3 and LiN(SO 2 F) 2 .
9. A lithium ion battery, comprising a positive electrode, a negative electrode, a separator for separating the positive electrode and the negative electrode, and an electrolyte, wherein the electrolyte is the non-aqueous electrolyte for lithium ion battery according to claim 1 .
10. The lithium ion battery according to claim 9 , wherein the positive electrode comprises a positive electrode active material, and the active material of the positive electrode is at least one of LiNi x Co y Mn z L (1−x−y−z) O 2 , LiCo x L (1−x′) O 2 , LiNi x″ L′ y′ Mn (2−x″−y′) O 4 and Li z′ MPO 4 , wherein, L is at least one of Al, Sr, Mg, Ti, Ca, Zr, Zn, Si or Fe, 0≤x≤1, 0≤y≤1, 0≤z≤1, 0 21 x+y+z≤1, 0<x′≤1, 0.3≤x″≤0.6, 0.01≤y′≤0.2, L′ is at least one of Co, Al, Sr, Mg, Ti, Ca, Zr, Zn, Si and Fe; 0.5≤z′≤1, M is at least one of Fe, Mn and Co.
11. The non-aqueous electrolyte for lithium ion battery according to claim 8 , wherein the cyclic carbonate is selected from at least one of ethylene carbonate, propylene carbonate and butylene carbonate; the chain carbonate is selected from at least one of dimethyl carbonate, diethyl carbonate, methyl ethyl carbonate and methyl propyl carbonate; the carboxylic acid ester is selected from at least one of methyl acetate, ethyl acetate, propyl acetate, methyl propionate, ethyl propionate and propyl propionate; the fluorine-containing aromatic hydrocarbon is selected from at least one of benzene compounds substituted with one or more fluorines.