Phosphorus acid and alkylamine or alkanolamine stabilized copper compound containing compositions for controlling a plant disease caused by a phytopathogenic organism
The present application relates to aqueous compositions for controlling a plant disease caused by a phytopathogenic organism, to methods of preparing such compositions and to uses of such compositions, for example for controlling a plant disease caused by a phytopathogenic organism. The aqueous compositions comprise copper ions, phosphorous acid and/or a salt thereof and an effective amount of an amine selected from an alkylamine, an alkanolamine and mixtures thereof. The pH of the compositions is from about 6 to about 10.
1. An aqueous composition for controlling a plant disease caused by a phytopathogenic organism, the composition comprising:
(a) copper ions;
(b) phosphorous acid and/or a salt thereof; and
(c) an alkylamine,
wherein the aqueous composition is prepared by combining a source of copper ions in an amount of from about 0.5 wt % to about 5 wt %;
the phosphorous acid in an amount of about 24 wt %, and an effective amount of the alkylamine,
wherein
the alkylamine is triethylenetetramine and the effective amount of the triethylenetetramine is about 12 wt % to less than 17 wt %, or
the alkylamine is diethylenetriamine and the effective amount of the diethylenetriamine is about 9 wt % to about 17 wt %, or
the alkylamine is 1,3-diaminopropane and the effective amount of the 1,3-diaminopropane is greater than 12 wt % and less than 15 wt %; and
the pH of the composition is from about 6 to about 10, and all wt % are based on the total weight of the composition, and
wherein the aqueous composition is a stable aqueous composition such that no detectable precipitate forms for a time of at least one month of storage at ambient temperature and pressure.
2. The composition of claim 1 , wherein the composition is prepared by further combining the source of copper ions, the phosphorus acid and alkylamine with an alkali metal inorganic base.
3. The composition of claim 1 , wherein:
the alkylamine is 1,3-diaminopropane and the effective amount of the 1,3-diaminopropane is about 13 wt % to about 14 wt %, based on the total weight of the composition.
4. The composition of claim 1 , wherein:
the alkylamine is triethylenetetramine and the effective amount of the triethylenetetramine is about 12 wt % to about 15 wt %, based on the total weight of the composition.
5. The composition of claim 1 , wherein
the alkylamine is diethylenetriamine and the effective amount of the diethylenetriamine is about 9 wt % to about 17 wt %, based on the total weight of the composition, and wherein the phosphorus acid and the diethylenetriamine are further combined with about 11 wt % to about 12 wt %, based on the total weight of the composition, of potassium carbonate.
6. The composition of claim 1 , wherein the amount of the source of copper ions is about 2 wt %, based on the total weight of the composition.
7. The composition of claim 6 , wherein the source of copper ions is selected from copper chloride, copper hydroxide, copper oxychloride sulfate, copper sulfate, basic copper sulfate, copper carbonate, basic copper carbonate, copper oxide, copper oxychloride, copper ethylenediaminetetraacetic acid (EDTA) and mixtures thereof.
8. The composition of claim 7 , wherein the source of the copper ions is selected from basic copper sulfate, copper hydroxide and basic copper carbonate.
9. The composition of claim 8 , wherein the source of the copper ions is basic copper carbonate.
10. The composition of claim 2 , wherein the alkali metal inorganic base is potassium carbonate, sodium carbonate, potassium bicarbonate, sodium bicarbonate, potassium hydroxide, sodium hydroxide or mixtures thereof.
11. The composition of claim 2 , wherein an alkali metal salt of phosphorous acid is prepared in situ by combining the phosphorous acid and the alkali metal inorganic base in the composition.
12. The composition of claim 2 , wherein the composition is prepared by a method comprising mixing the source of copper ions, the alkylamine, the alkali metal inorganic base with an aqueous solution comprising the phosphorous acid under conditions to obtain the composition.
13. The composition of claim 11 , wherein the alkali metal salt of phosphorous acid is K 2 HPO 3 , KNaHPO 3 , Na 2 HPO 3 , KH 2 PO 3 , NaH 2 PO 3 or mixtures thereof.
14. The composition of claim 4 , wherein the effective amount of the triethylenetetramine is about 14 wt %, based on the total weight of the composition.
15. The composition of claim 4 , wherein the phosphorus acid and the triethylenetetramine are further combined with about 11 wt %, based on the total weight of the composition, of potassium carbonate.
16. The composition of claim 5 , wherein the effective amount of the diethylenetriamine is about 9 wt %, about 12 wt %, about 15 wt % or about 17 wt %, based on the total weight of the composition.
17. A method for controlling a plant disease caused by a phytopathogenic organism, the method comprising contacting a plant and/or the soil surrounding the plant with an effective amount of a composition of claim 1 .
18. The method of claim 17 , wherein the phytopathogenic organism is a phytopathogenic fungus, bacterium, alga or virus.
19. The method of claim 18 , wherein the phytopathogenic organism is a phytopathogenic fungus selected from Basidiomycetes, Ascomycetes, Deuteromycetes, Zygomycetes and Oomycetes.
20. The method of claim 18 , wherein the phytopathogenic organism is a phytopathogenic bacterium selected from Xanthomonas spp., Pseudomonas spp., Pantoea spp., Acidovorax spp. and Erwinia amylovora.
21. The method of claim 17 , wherein the plant is selected from cereals, fruit plants, nut trees, citrus trees, legumes, tubers, vegetables, cucurbitaceae, oleaginous plants, tobacco, coffee, tea, cocoa, sugar beet, sugar cane, herbs, hops, ginseng, grasses and cotton.