Process for preparing cyclic alkylene ureas
A process for producing a cyclic alkylene urea product of Formula I: in which a compound of Formula II and/or Formula III is contacted in a reaction zone with a compound of Formula IV and/or Formula V and in the presence of one or more carbonyl delivering compounds; wherein the compound of Formula II and/or the compound of Formula III are added to a reaction zone comprising compound of Formula IV and/or compound of Formula (V) continuously or semi-continuously over a period of time, or in two or more batches.
1. A process for producing 1-(2-aminoethyl) imidazolidin-2-one (UDETA), the process comprising:
contacting 2-oxazolidinone (CMEA) and/or monoethanolamine (MEA) in a reaction zone with ethyleneurea (EU) and/or ethylenediamine (EDA) and in the presence of one or more carbonyl delivering compounds;
wherein the ethyleneurea (EU) and/or the ethylenediamine (EDA) is present in a reaction zone, and wherein the 2-oxazolidinone (CMEA) and/or the monoethanolamine (MEA) are added to the reaction zone semi-continuously or in two or more batches.
2. The process of claim 1 , wherein the 2-oxazolidinone (CMEA) and/or the monoethanolamine (MEA) are added to the reaction zone semi-continuously.
3. The process of claim 1 , wherein the 2-oxazolidinone (CMEA) and/or the monoethanolamine (MEA) are added to the reaction zone in two or more batches.
4. The process of claim 1 , further comprising limiting an amount of CMEA and MEA and EU and EDA in the reaction zone to a predetermined molar ratio of CMEA and MEA to EU and EDA, wherein the predetermined molar ratio is 0.60:1.
5. The process of claim 1 , further comprising limiting an amount of CMEA and MEA and EU and EDA in the reaction zone to a predetermined molar ratio of CMEA and MEA to EU and EDA, wherein the predetermined molar ratio is 0.30:1.
6. The process of claim 1 , further comprising limiting an amount of CM EA and MEA and EU and EDA in the reaction zone to a predetermined molar ratio of CMEA and MEA to EU and EDA, wherein the predetermined molar ration is 0.25:1.
7. The process of claim 1 , further comprising limiting an amount of CM EA and MEA and EU and EDA in the reaction zone to a predetermined molar ratio of CMEA and MEA to EU and EDA, wherein the predetermined molar ration is 0.20:1.
8. The process of claim 1 , further comprising limiting an amount of CM EA and MEA and EU and EDA in the reaction zone to a predetermined molar ratio of CMEA and MEA to EU and EDA, wherein the predetermined molar ration is 0.16:1.
9. The process of claim 1 , wherein the carbonyl delivering compound is selected from carbon dioxide; inorganic carbonic acid salts; cyclic and non-cyclic carbonic acid esters; urea; optionally substituted alkyl ureas; optionally substituted cyclic alkylene ureas; carbamic acids; carbamic acid salts; and cyclic and non-cyclic carbamic acid esters.
10. The process of claim 1 , wherein the carbonyl delivering compound is selected from 2-oxazolidinone (CMEA) and ethylenediamine (EDA).