High-frequency circuit laminate and method for producing same, and B-stage sheet
Provided is a high-frequency circuit laminate that can reduce the transmission loss of electrical signals in high-frequency circuits and produce circuit boards with excellent smoothness. The high-frequency circuit laminate according to the present invention includes a metal layer and a resin layer which are laminated in contact with each other, the resin layer having an elastic modulus from 0.1 to 3 GPa, and the resin layer having an dielectric loss tangent from 0.001 to 0.01 and a relative permittivity from 2 to 3 at a frequency of 10 GHz at 23° C.
1. A high-frequency circuit laminate, comprising:
a metal layer; and
a resin layer,
wherein the metal layer and the resin layer are laminated in contact with each other,
wherein the resin layer comprises a polymer comprising a repeating unit of formula (1-1), a repeating unit of formula (1-2), and/or a repeating unit of formula (1-3)
wherein in the formulas (1-1) to (1-3), R 1 is independently a halogen atom, a monovalent hydrocarbon group comprising 1 to 20 carbon atoms, a monovalent halogenated hydrocarbon group comprising 1 to 20 carbons, a nitro group, a cyano group, a primary amino group optionally as a salt, a secondary amine group optionally as a salt, or a tertiary amino groups optionally as a salt, n is independently an integer in a range of from 0 to 2, wherein when n is 2, the plurality of R1s optionally differ, and are optionally bonded in any combination to form part of a ring structure,
wherein the resin layer has an elastic modulus ranges from 0.1 to 3 GPa, and
wherein the resin layer has a dielectric loss tangent in a range of from 0.001 to 0.01 and a relative permittivity in as range of from 2 to 3 at a frequency of 10 GHz at 23° C.
2. The laminate of claim 1 , wherein a peel strength between the resin layer and the metal layer is 5 N/cm or greater.
3. The laminate of claim 1 , wherein the resin layer has a thickness in a range of from 10 to 100 μm, and
wherein the metal layer has a thickness in a range of from 10 to 50 μm.
4. The laminate of claim 1 , having a thickness in a range of from 50 to 200 μm.
5. A flexible printed circuit board, comprising:
the high-frequency circuit laminate of claim 1 .
6. A laminate roll, comprising:
the high-frequency circuit laminate of claim 1 ,
wherein the high-frequency circuit laminate is wound around a core having a radius in a range of from 10 to 100 mm.
7. A method for producing a high-frequency circuit laminate, the method comprising:
bonding a B-stage resin layer having a surface roughness Ra in a range of from 1 to 100 nm to a metal layer having a surface roughness Ra in a range of from 10 to 300 nm by heating in a range of from 50 to 200° C. under a linear load in a range of from 1 to 19 kN/m,
wherein the B-stage resin layer comprises a polymer comprising a repeating unit of formula (1-1), a repeating unit of formula (1-2), and/or a repeating unit of formula (1-3)
wherein in the formulas (1-1) to (1-3), R 1 is independently a halogen atom, a monovalent hydrocarbon group comprising 1 to 20 carbon atoms, a monovalent halogenated hydrocarbon group comprising 1 to 20 carbons, a nitro group, a cyano group, a primary amino group optionally as a salt, a secondary amine group optionally as a salt, or a tertiary amino groups optionally as a salt, n is independently an integer in a range of from 0 to 2, wherein when n is 2, the plurality of R 1 s optionally differ, and are optionally bonded in any combination to form part of a ring structure.
8. A B-stage sheet, comprising:
a B-stage resin layer; and
a release layer formed on at least one surface of the B-stage resin layer,
wherein the B-stage resin layer comprises a polymer comprising a repeating unit of formula (1-1), a repeating unit of formula (1-2), and/or a repeating unit of formula (1-3)
wherein in the formulas (1-1) to (1-3), R 1 is independently a halogen atom, a monovalent hydrocarbon group comprising 1 to 20 carbon atoms, a monovalent halogenated hydrocarbon group comprising 1 to 20 carbons, a nitro group, a cyano group, a primary amino group optionally as a salt, a secondary amine group optionally as a salt, or a tertiary amino groups optionally as a salt, n is independently an integer in a range of from 0 to 2, wherein when n is 2, the plurality of R 1 s optionally differ, and are optionally bonded in any combination to form part of a ring structure,
wherein the B-stage resin layer is cured to become a C-stage resin layer having an elastic modulus in a range of from 0.1 to 3 GPa, and
wherein the C-stage resin layer has a dielectric loss tangent in a range of from 0.001 to 0.01 and a relative permittivity in a range of from 2 to 3 at a frequency of 10 GHz at 23° C.
9. The laminate of claim 1 , wherein the polymer further comprises a repeating unit of formula (2):
wherein, in the formula (2),
R 3 and R 4 are independently a halogen atom, a nitro group, a cyano group, or a monovalent organic group comprising 1 to 20 carbon atoms,
c and d are independently an integer in a range of from 0 to 8,
e, f, and y are independently an integer from 0 to 2, and
L is a single bond, —O—, —S—, —CO—, —SO—, —SO 2 —, or a divalent organic group comprising 1 to 20 carbon atoms.
10. The method of claim 7 , wherein the polymer further comprises a repeating unit of formula (2):
wherein, in the formula (2),
R 3 and R 4 are independently a halogen atom, a nitro group, a cyano group, or a monovalent organic group comprising 1 to 20 carbon atoms,
c and d are independently an integer in a range of from 0 to 8,
e, f, and y are independently an integer from 0 to 2, and
L is a single bond, —O—, —S—, —CO—, —SO—, —SO—, or a divalent organic group comprising 1 to 20 carbon atoms.
11. The B-stage sheet of claim 8 , wherein the polymer further comprises a repeating unit of formula (2):
wherein, in the formula (2),
R 3 and R 4 are independently a halogen atom, a nitro group, a cyano group, or a monovalent organic group comprising 1 to 20 carbon atoms,
c and d are independently an integer in a range of from 0 to 8,
e, f, and y are independently an integer from 0 to 2, and
L is a single bond, —O—, —S—, —CO—, —SO—, —SO—, or a divalent organic group comprising 1 to 20 carbon atoms.
12. The laminate of claim 1 , wherein the polymer comprises the repeating unit of formula (1-1).
13. The laminate of claim 1 , wherein the polymer comprises the repeating unit of formula (1-2).
14. The laminate of claim 1 , wherein the polymer comprises the repeating unit of formula (1-3).
15. The laminate of claim 1 , wherein the polymer has a weight average molecular weight in a range of from 30000 to 600000.
16. The laminate of claim 1 , wherein the polymer has a glass transition temperature in a range of from 150 to 320° C.
17. The laminate of claim 1 , wherein the polymer has a glass transition temperature in a range of from 180 to 300° C.
18. The laminate of claim 1 , wherein, in formulas (1-1) to (1-3), n is 0.
19. The laminate of claim 9 , wherein, in the formula (2), L is the divalent organic group comprising 1 to 20 carbon atoms.
20. The laminate of claim 1 , wherein the polymer comprises, as a structural repeating unit,