Lithium-ion batteries recycling process

1. A process for recycling lithium-ion batteries comprising the steps of:

a) shredding the lithium-ion batteries and immersing the residues in an organic solvent to safely discharge the batteries and producing shredded batteries residues and a liquid comprising organic compounds and lithium hexafluorophosphate;

b) feeding the shredded batteries residues in a dryer producing a gaseous organic phase and dried batteries residues;

c) feeding the dried batteries residues comprising magnetic and non-magnetic batteries residues to a magnetic separator removing magnetic particles from the dried batteries residues;

d) grinding the non-magnetic batteries residues producing a particle size distribution comprising an upper range comprising plastics, and a middle and lower range of fine particles comprising aluminum, copper, metal and graphite;

e) mixing the fine particles and an acid producing a slurry and leaching the slurry producing a leachate comprising metal sulfate and non-leachable materials;

f) filtering the leachate to remove the non-leachable materials from the leachate;

g) feeding the leachate into a sulfide precipitation tank removing ionic copper impurities from said leachate;

h) neutralizing the leachate at a pH of 3.5 to 5 removing remaining iron and aluminum from said leachate;

i) mixing the leachate with an organic extraction solvent producing an aqueous phase containing lithium and an organic phase containing cobalt, manganese and nickel;

j) crystallizing sodium sulfate from the aqueous phase containing lithium producing a liquor containing lithium and sodium sulfate crystals;

k) adding sodium carbonate to the liquor and heating up the sodium carbonate and the liquor producing a precipitate of lithium carbonate; and

l) drying and recuperating the lithium carbonate.

2. The process of claim 1 , wherein the organic solvent is an aliphatic carbonate.

3. The process of claim 1 , wherein the lithium ion batteries are shredded to a particle size of about 5-10 millimeters.

4. The process of claim 1 , wherein the shredded batteries residues are separated from the liquid by sieving or filtration.

5. The process of claim 1 , further comprising evaporating the liquid of step a) in an evaporator, producing a slurry and a condensate of light organics.

6. The process of claim 5 , comprising separating dimethyl carbonate (DMC), ethyl methyl carbonate (EMC), diethyl carbonate (DEC) and ethylene carbonate (EC) from the condensate of light organics.

7. The process of claim 5 , further comprising recycling the condensate of light organics as the organic solvent in step a).

8. The process of claim 1 , wherein the shredded batteries residues are dried at a temperature between 200-300° C.

9. The process of claim 1 , wherein the non-magnetic batteries residues are grinded in a hammer mill or in an impact crusher.

10. The process of claim 1 , further comprising extracting with an eddy current separator the aluminum and cooper from the grinded non-magnetic batteries.

11. The process of claim 10 , wherein the aluminum and copper are further separated.

12. The process of claim 1 , wherein the fine particles are mixed with sulfuric acid and water to produce a metal oxides slurry at a solid concentration between 75 to 125 kg of solid per cubic meters of acid solution.

13. The process of claim 1 , further comprising adding a reduction agent to the metal oxides slurry for leaching.

14. The process of claim 13 , wherein the reduction agent is at least one of hydrogen peroxide (H 2 O 2 ), manganese oxide (MnO 2 ), aluminum (Al) and a combination thereof.

15. The process according to any of the preceding claims, further comprising filtering the graphite from the leachate and purifying it in a furnace.

16. The process of claim 1 , further comprising precipitating the ionic copper impurities by precipitation with sulfide ions.

17. The process of claim 1 , further comprising mixing the leachate and the organic extraction solvent in step j) in a diluent.

18. The process of claim 1 , further comprising scrubbing and stripping the organic phase from step i) to extract cobalt and manganese.

19. The process of claim 1 , further comprising increasing the pH of the aqueous phase to a pH between 10 and 12 to precipitate the nickel from said aqueous phase.

20. The process of claim 1 , further comprising electrolysing the sodium sulfate crystals producing sulfuric acid and sodium hydroxide.