IP Library › Granted Patent US 11,390,709
Granted Patent B2
US 11,390,709 · App. 16/650,188 · Granted Jul 19, 2022

Liquid copolymer formed by ring-opening copolymerization of cyclopentene, crosslinkable composition, and crosslinked rubber object

Inventor: Yasuo Tsunogae (Tokyo, JP)
Assignee: ZEON CORPORATION
C08G61/08C08G18/246C08G18/64C08G18/7664
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Quick Facts
Patent No.
US 11,390,709
App. No.
16/650,188
Granted
Jul 19, 2022
Kind
B2
Abstract

A liquid cyclopentene ring-opened copolymer includes a monomer unit derived from cyclopentene and a monomer unit derived from a norbornene compound, the monomer unit derived from cyclopentene being present in an amount of 60 to 95 wt %, the liquid cyclopentene ring-opened copolymer having a hydroxyl group-terminated copolymer chain and having a melt viscosity at 25° C. of less than 500 Pa·s, which is measured using a B-type viscometer.

Claims (13)

1. A liquid cyclopentene ring-opened copolymer comprising a monomer unit derived from cyclopentene and a monomer unit derived from a norbornene compound,

the monomer unit derived from cyclopentene being present in an amount of 60 to 95 wt %,

the liquid cyclopentene ring-opened copolymer having a hydroxyl group-terminated copolymer chain and having a melt viscosity at 25° C. of less than 500 P·s, which is measured using a B-type viscometer at a shear rate of within the range of 1.2 to 10 sec −1 .

2. The liquid cyclopentene ring-opened copolymer according to claim 1 ,

which has a number average molecular weight (Mn) of 500 to 20,000.

3. The liquid cyclopentene ring-opened copolymer according to claim 1 ,

wherein the cis/trans ratio of double bonds in repeating units is 10/90 to 40/60.

4. The liquid cyclopentene ring-opened copolymer according to claim 1 ,

which has a glass transition temperature (Tg) of −50° C. or lower.

5. A method for producing the liquid cyclopentene ring-opened copolymer according to claim 1 , comprising:

performing ring-opening polymerization of monomers including cyclopentene and the norbornene compound in an ether- or ketone-based solvent as a polymerization solvent using a polymerization catalyst containing a ruthenium compound and a hydroxyl group-containing chain transfer agent.

6. A cross-linkable composition comprising a polyfunctional isocyanate compound in an amount of 1 to 100 parts by weight with respect to 100 parts by weight of the liquid cyclopentene ring-opened copolymer according to claim 1 .

7. A cross-linked product obtained by cross-linking the cross-linkable composition according to claim 6 .

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Mar 24, 2020
From: TSUNOGAE, YASUO
To: ZEON CORPORATION
Reel/Frame 052211/0870 →
Priority Claims (1)
JP JP2017-190619 · Sep 29, 2017 · national
Continuity (1)
Related Publication 20200223979A1 · Jul 16, 2020