IP Library Granted Patent US 11,560,476
Granted Patent B2
US 11,560,476 · App. 16/651,015 · Granted Jan 24, 2023

Epoxy resin, epoxy resin composition, epoxy resin cured product, and composite material

Inventors: Naoki Maruyama (Tokyo, JP); Yuka Yoshida (Tokyo, JP); Tomoko Higashiuchi (Tokyo, JP); Kazumasa Fukuda (Tokyo, JP); Keiichiro Nishimura (Tokyo, JP); Yoshitaka Takezawa (Tokyo, JP)
Assignee: Showa Denko Materials Co., Ltd.
C08L63/00C08G59/245
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Quick Facts
Patent No.
US 11,560,476
App. No.
16/651,015
Granted
Jan 24, 2023
Kind
B2
Abstract

An epoxy resin, comprising an epoxy compound A that has at least two mesogenic structures and at least one phenylene group, and an epoxy compound B that has at least two mesogenic structures and at least one divalent biphenyl group.

Claims (11)

1. An epoxy resin composition, comprising:

an epoxy resin comprising:

an epoxy compound A that has at least two mesogenic structures and at least one phenylene group,

an epoxy compound B that has at least two mesogenic structures and at least one divalent biphenyl group, wherein the ratio between epoxy compound A and epoxy compound B (epoxy compound A:epoxy compound B) is from 3:7 to 9:1; and

a curing agent selected from the group consisting of 3,3′-diaminodiphenylsulfone, 4,4′-diaminodiphenylsulfone, 4,4′-diaminodiphenylmethane, 4,4′-diaminodiphenylether, 4,4′-diamino-3,3′-dimethoxybiphenyl, 4,4′-diaminophenylbenzoate, 1,5-diaminonaphthalene, 1,3-diaminonaphthalene, 1,4-diaminonaphthalene, 1,8-diaminonaphthalene, 1,3-diaminobenzene, 1,4-diaminobenzene, 4,4′-diaminobenzanilide, trimethylene-bis-4-aminobenzoate, phenol, o-cresol, m-cresol, p-cresol, catechol, resorcinol, hydroquinone, 1,2,3-trihydroxybenzene, 1,2,4-trihydroxybenzene, and 1,3,5-trihydroxybenzene.

2. The epoxy resin according to claim 1 , wherein at least one of the epoxy compound A or the epoxy compound B has a structure in which the phenylene group or the divalent biphenyl group is disposed between the at least two mesogenic structures.

3. The epoxy resin according to claim 1 , wherein at least one of the at least two mesogenic structures of at least one of the epoxy compound A or the epoxy compound B has a structure represented by the following Formula (3):

wherein, in Formula (3), each of R 3 to R 6 independently represents a hydrogen atom or an alkyl group having 1 to 3 carbon atoms.

4. The epoxy resin composition according to claim 1 , being configured to form a smectic structure in a cured state.

5. An epoxy resin cured product comprising a cured product of the epoxy resin composition according to claim 1 .

6. A reinforcing material, comprising the epoxy resin cured product according to claim 5 and a reinforcing material.

Assignments (5)
CHANGE OF ADDRESS Recorded Feb 14, 2024
From: RESONAC CORPORATION
To: RESONAC CORPORATION
Reel/Frame 066599/0037 →
CORRECTIVE ASSIGNMENT TO CORRECT THE THE ADDRESS OF THE ASSIGNEE PREVIOUSLY RECORDED AT REEL: 06236 FRAME: 0323. ASSIGNOR(S) HEREBY CONFIRMS THE ASSIGNMENT. Recorded Mar 16, 2023
From: SHOWA DENKO MATERIALS CO., LTD.
To: RESONAC CORPORATION
Reel/Frame 063193/0416 →
CHANGE OF NAME Recorded Feb 9, 2023
From: SHOWA DENKO MATERIALS CO., LTD.
To: RESONAC CORPORATION
Reel/Frame 062636/0323 →
CHANGE OF NAME Recorded Aug 24, 2022
From: HITACHI CHEMICAL COMPANY, LTD.
To: SHOWA DENKO MATERIALS CO., LTD.
Reel/Frame 061312/0139 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jun 9, 2020
From: MARUYAMA, NAOKI; YOSHIDA, YUKA; HIGASHIUCHI, TOMOKO; FUKUDA, KAZUMASA; NISHIMURA, KEIICHIRO; TAKEZAWA, YOSHITAKA
To: HITACHI CHEMICAL COMPANY, LTD.
Reel/Frame 052873/0962 →