Sagger for firing secondary battery active material and method for manufacturing secondary battery active material using same
A sagger for firing an object to be fired includes an active material for a secondary battery. Carbon dioxide that is a reaction by-product produced during a positive electrode active material firing process can be smoothly discharged from the sagger, and such a smooth discharge of carbon dioxide can lower a residual lithium concentration of a positive electrode active material and thus can improve dispersibility of a positive electrode active material slurry and also improve capacity of a battery.
1. A sagger for firing an object to be fired including an active material for a secondary battery, the sagger, comprising:
a notch portion that is recessed from an upper portion of a side wall thereof to open a portion of the side wall, wherein a ratio of an area of the notch portion to an area of the side wall is 30 to 70%,
an edge at which a side wall of the sagger contacts a lower surface of the sagger on which the object to be fired is loaded is configured by a rounded portion, and
a radius of curvature of the rounded portion is greater than or equal to 25 mm.
2. The sagger of claim 1 , wherein the notch portion has a depth of 60 to 90% from an upper surface of the sagger.
3. The sagger of claim 1 , wherein the sagger comprises at least a pair of opposing side walls, and the notch portion is formed on the at least a pair of opposing side walls.
4. The sagger of claim 1 , wherein a through-hole is formed on a lower surface of the sagger.
5. The sagger of claim 1 , wherein the sagger is further provided with a cover for covering an upper surface opened for inflow and outflow of an object to be fired.
6. The sagger of claim 5 , wherein a through-hole is formed on the cover.
7. The sagger of claim 1 , wherein the sagger consists of one or more selected from mullite (3Al 2 O 3 2SiO 2 ), cordierite (Mg, Fe +3 )2Al 4 Si 5 O 18 ), spinel (MgAl 2 O 4 ) and zircon (ZrSiO 4 ).
8. A method for manufacturing an active material for a secondary battery comprising operations of:
loading a raw material into the sagger according to claim 1 and inserting the raw material in a firing furnace and then firing; and
recovering the raw material in the sagger after the firing, and cooling and pulverizing to prepare an active material for a secondary battery.
9. The method for manufacturing the active material for the secondary battery of claim 8 , wherein a size of the raw material to be loaded into the sagger by molding powder is increased.
10. The method for manufacturing the active material for the secondary battery of claim 8 , wherein the firing is performed in an oxygen atmosphere or an inert gas atmosphere.
11. The method for manufacturing the active material for the secondary battery of claim 8 , wherein two or more saggers are disposed in the firing furnace.
12. The method for manufacturing the active material for the secondary battery of claim 8 , wherein the two or more saggers are stacked in two or more layers in the firing furnace and then fired.