Stannous oxide powder and method for producing same
Provided is a method for producing stannous oxide, comprising a step of subjecting stannous sulfate to neutralization in an aqueous solution using ammonium carbonate or ammonium bicarbonate, and thereby precipitating stannous oxide. This production method is a novel means for producing stannous oxide in which chlorine, sulfur, sodium, and potassium are sufficiently reduced, and which has excellent solubility.
1. A stannous oxide consisting of a stannous oxide content of 99.99% by mass or more, a chlorine content of 1 ppm or less, and optionally sulfur, sodium, potassium, and antimony.
2. The stannous oxide according to claim 1 , wherein the chlorine content is 1 ppm or less and the sulfur content is less than 10 ppm.
3. A stannous oxide powder comprising the stannous oxide according to claim 2 .
4. The stannous oxide according to claim 1 , wherein the stannous oxide has a sodium content of less than 5 ppm and a potassium content of less than 5 ppm.
5. A stannous oxide powder comprising the stannous oxide according to claim 4 .
6. The stannous oxide according to claim 1 , wherein the stannous oxide has an antimony content of 5 ppm or less.
7. A stannous oxide powder comprising the stannous oxide according to claim 6 .
8. A stannous oxide powder comprising the stannous oxide according to claim 1 .
9. The stannous oxide according to claim 8 , wherein the powder has a water content in a range of from 1 to 10% by weight.
10. The stannous oxide according to claim 8 , wherein the powder has a specific surface area in a range of from 0.1 to 1.0 m 2 /g.
11. The stannous oxide according to claim 8 , wherein the powder has a TAP density in a range of from 1.0 to 4.0 g/cm 3 .
12. The stannous oxide according to claim 8 , wherein the powder has a 50% particle diameter (D50) in a range of from 20 to 60 μm.
13. A method for producing stannous oxide according to claim 1 , the method comprising a step of subjecting stannous sulfate to a neutralization reaction with ammonium carbonate or ammonium bicarbonate in an aqueous solution to deposit stannous oxide,
wherein the neutralization reaction is carried out in an aqueous solution having a pH in a range of from pH 6.0 to pH 8.0,
wherein the step of subjecting stannous sulfate to the neutralization reaction to deposit stannous oxide comprises:
subjecting stannous sulfate to the neutralization reaction at a temperature in a range of from 50 to 80° C.; and
then maintaining the aqueous solution subjected to the neutralization reaction at a temperature in a range of from 60 to 100° C. to deposit stannous oxide.
14. The method according to claim 1 , wherein the step of subjecting stannous sulfate to the neutralization reaction to deposit stannous oxide comprises:
subjecting stannous sulfate to the neutralization reaction at a temperature in a range of from 50 to 80° C. for 1 to 10 hours; and
then maintaining the aqueous solution subjected to the neutralization reaction at a temperature in a range of from 60 to 100° C. for 1 to 10 hours to deposit stannous oxide.
15. The method according to claim 13 , wherein the neutralization reaction is carried out by adding an aqueous stannous sulfate solution to an aqueous ammonium bicarbonate solution.
16. The method according to claim 15 , wherein a concentration of ammonium bicarbonate in the aqueous ammonium bicarbonate solution is in a range of from 50 to 150 g/L.
17. The method according to claim 15 , wherein a concentration of tin in the aqueous stannous sulfate solution is in a range of from 10 to 130 g/L.