Aerogel and method for producing same
The present invention provides a method for producing an aerogel, comprising a sol generating step of generating, by hydrolyzing a silane oligomer, a sol containing a hydrolysis product of the silane oligomer; a wet gel generating step of obtaining a wet gel by gelation of the sol; and a drying step of drying the wet gel to obtain an aerogel, wherein a proportion of silicon atoms each bonded to three oxygen atoms in a total number of silicon atoms contained in the silane oligomer is 50% or more.
1. A method for producing an aerogel, comprising:
a sol generating step of generating, by hydrolyzing a silane oligomer with an acid catalyst, a sol containing a hydrolysis product of the silane oligomer;
a wet gel generating step of obtaining a wet gel by gelation of the sol with a base catalyst; and
a drying step of drying the wet gel to obtain an aerogel,
wherein a proportion of silicon atoms each bonded to three oxygen atoms in a total number of silicon atoms contained in the silane oligomer is 70% or more,
the silane oligomer has an alkoxy group, and
a content of the alkoxy group is 2% by mass or more and 60% by mass or less with respect to a total amount of the silane oligomer.
2. The production method according to claim 1 , wherein a weight average molecular weight of the silane oligomer is 200 or more and 10000 or less.
3. An aerogel obtained as a dried substance of a wet gel, the wet gel being a condensate of a sol containing an acid catalyzed hydrolysis product of a silane oligomer,
wherein a proportion of silicon atoms each bonded to three oxygen atoms in a total number of silicon atoms contained in the silane oligomer is 70% or more,
the silane oligomer has an alkoxy group, and
a content of the alkoxy group is 2% by mass or more and 60% by mass or less with respect to a total amount of the silane oligomer.
4. The aerogel according to claim 3 , wherein a weight average molecular weight of the silane oligomer is 200 or more and 10000 or less.
5. The production method according to claim 1 , wherein the silane oligomer is present in an amount of 5% by mass or more relative to all silicon compounds to be hydrolyzed during the sol generating step.
6. The production method according to claim 1 , wherein the sol generating step further comprises hydrolyzing a silane monomer, and an amount of the silane monomer ranges from 1 part by mass to 5000 parts by mass with respect to 100 parts by mass of the silane oligomer.
7. A method for producing an aerogel, comprising: hydrolyzing a silane oligomer in the presence of an acid catalyst to obtain a sol, a proportion of silicon atoms each bonded to three oxygen atoms in a total number of silicon atoms contained in the silane oligomer being 70% or more, the silane oligomer having an alkoxy group, and a content of the alkoxy group being 2% by mass or more and 60% by mass or less with respect to a total amount of the silane oligomer; gelling the sol in the presence of a base catalyst to obtain a wet gel; and drying the wet gel to obtain an aerogel.