IP Library Granted Patent US 12,311,474
Granted Patent B2
US 12,311,474 · App. 16/670,494 · Granted May 27, 2025

Field girth welding technology for high manganese steel slurry pipelines

Inventors: Andrew J. Wasson (Spring, TX); Timothy D. Anderson (Spring, TX); Douglas P. Fairchild (Sugar Land, TX); Xin Yue (Spring, TX); HyunWoo Jin (Easton, PA); Ning Ma (Whitehouse Station, NJ); IlWook Han (Pohang, KR); Sangchul Lee (Pohang, KR); Bongkeun Lee (Pohang, KR); Jongsub Lee (Seoul, KR)
Assignees: EXXONMOBIL RESEARCH AND ENGINEERING COMPANY; POSCO
B23K35/3073B23K9/025B23K9/09B23K9/16B23K9/173B23K9/23B23K35/0261B23K35/383C22C38/02C22C38/22C22C38/38C22C38/44C22C38/48C22C38/50C22C38/58B23K2103/04C21D2211/001
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Quick Facts
Patent No.
US 12,311,474
App. No.
16/670,494
Granted
May 27, 2025
Kind
B2
Abstract

Welding compositions for high manganese steel base metals, the composition comprising: carbon in a range of about 0.4 wt % to about 0.8 wt %; manganese in a range of about 18 wt % to about 24 wt %; chromium in an amount of about 6 wt %; molybdenum in an amount of about <4 wt %; nickel in an amount of about <5 wt %; silicon in an amount of about 0.4 wt % to about 1.0 wt %; sulfur in an amount of about <200 ppm; phosphorus in an amount of about <200 ppm; and the balance comprising iron.

Claims (31)

1. A weld metal for high manganese steel base metals, the weld metal being created by at least two high manganese steel base metals and a welding wire, the weld metal comprising:

carbon in a range of about 0.4 wt % to about 0.8 wt %;

manganese in a range of about 18 wt % to about 24 wt %;

chromium in an amount of about 6 wt %;

molybdenum in an amount of about <4 wt %;

nickel in an amount of about <5 wt %;

silicon in an amount of about 0.4 wt % to about 1.0 wt %;

sulfur in an amount of about <200 ppm;

phosphorus in an amount of about <200 ppm; and

the balance comprising iron;

wherein the weld metal has an austenitic microstructure; and

wherein the austenitic microstructure transforms into a hard α′-martensite and undergoes microtwinning upon straining.

2. The weld metal of claim 1 , further comprising at least one of:

titanium in an amount of about <2 wt %;

niobium in an amount of about <5 wt %;

tungsten in an amount of about <5 wt %;

aluminum in an amount of about 1.0 wt %;

boron in an amount of about <0.1 wt %;

nitrogen in an amount of about <1.5 wt % or a combination thereof.

3. A method of producing a weld metal of erosion/corrosion resistant high Mn steel,

the method comprising: providing at least two high Mn steel bases to be welded,

melting and cooling a welding filler material to create the weld metal, wherein the weld metal comprises carbon in a range of about 0.4 wt % to about 0.8 wt %, manganese in a range of about 18 wt % to about 24 wt %, chromium in an amount of about 6 wt %, molybdenum in an amount of about <4 wt %, nickel in an amount of about <5 wt %, silicon in a range of about 0.4 wt % to about 1.0 wt %, sulfur in an amount of about <200 ppm, phosphorus in an amount of about <200 ppm, and a balance comprising iron, wherein the weld metal has an austenitic microstructure, and wherein the austenitic microstructure transforms into a hard α′-martensite and undergoes microtwinning upon straining; and wherein an amount of carbon in the weld metal is less than an amount of carbon in a heat affected zone of the at least high Mn two steel bases.

4. The method of claim 3 , wherein melting comprising providing a welding heat input no more than about 2.5 kJ/mm to the welding filler metal.

5. The method of claim 3 , wherein the at least two high Mn steel bases comprise a portion to be welded, the portions having bevels of about 30 degrees to about 37.5 degrees.

6. The method of claim 3 , wherein the weld metal has a yield strength in the as-welded condition greater than a yield strength of a high manganese steel base.

7. The method of claim 3 , wherein the weld metal has a yield strength in the as-welded condition greater than about 70 ksi.

8. The method of claim 3 , wherein the weld metal has an ultimate tensile strength in the as-welded condition greater than about 82.7 ksi.

9. The method of claim 3 , wherein the weld metal has a tensile elongation in the as-welded condition greater than about 16%.

10. The method of claim 3 , wherein the weld metal has a solidification cracking temperature range in the as-welded condition of about 40° C. to about 170° C. at 7% strain.

11. The method of claim 3 , wherein the weld metal and/or a heat affected zone of the bases has a Charpy V-notch (CVN) energy at −29° C. in the as-welded condition greater than 27 J.

12. The method of claim 3 , wherein the at least high Mn two steel bases are an erosion/corrosion resistant high Mn steel.

Assignments (4)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Mar 22, 2024
From: EXXONMOBIL TECHNOLOGY AND ENGINEERING COMPANY; POSCO HOLDINGS, INC.
To: POSCO CO., LTD.
Reel/Frame 066876/0179 →
CHANGE OF NAME Recorded Jan 19, 2024
From: EXXONMOBIL RESEARCH AND ENGINEERING COMPANY
To: EXXONMOBIL TECHNOLOGY AND ENGINEERING COMPANY
Reel/Frame 066356/0101 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Oct 31, 2019
From: WASSON, ANDREW J.; ANDERSON, TIMOTHY D.; FAIRCHILD, DOUGLAS P.; YUE, XIN; JIN, HYUNWOO; MA, NING; HAN, IIWOOK; LEE, SANGCHUL; LEE, BONGKEUN; LEE, JONGSUB
To: EXXONMOBIL RESEARCH AND ENGINEERING COMPANY
Reel/Frame 050900/0121 →
50% OF ASSIGNOR'S RIGHT, TITLE AND INTEREST Recorded Oct 31, 2019
From: EXXONMOBIL RESEARCH AND ENGINEERING COMPANY
To: POSCO
Reel/Frame 050900/0237 →
Continuity (3)
Division 15584794 · May 2, 2017
Provisional Application 62330415 · May 2, 2016
Related Publication 20200086431A1 · Mar 19, 2020
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