IP Library Granted Patent US 11,661,491
Granted Patent B2
US 11,661,491 · App. 16/673,368 · Granted May 30, 2023

Reduced density thermoplastics

Inventor: Michael Waggoner (Seattle, WA)
Assignee: Corumat, Inc.
C08J9/34B29C44/02B29C44/022B29C44/0461B29C44/3453B29C44/352B29C44/60B29C51/428B29C51/46B32B5/20C08J9/36B29B11/02B29B11/08B29C51/02B29C51/10B29C51/264B29C51/422B29C51/426B29K2023/086B29K2067/046B29K2101/12B29K2105/0085B29K2105/04B29K2105/041B29K2105/046B29K2105/256B29K2105/26B29L2009/00B32B2553/00C08J2367/04Y02P70/10Y10T428/24992Y10T428/249953Y10T428/249981
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Quick Facts
Patent No.
US 11,661,491
App. No.
16/673,368
Granted
May 30, 2023
Kind
B2
Abstract

The instant application discloses, among other things, ways to manufacture reduced density thermoplastics. A rapid foaming process which may create a polymer product by saturating thermoplastic sheet or preforms, heating, and then forming into final shape, is described. The polymer product may include an integral solid skin. This method may be utilized with any thermoplastic. The material handling, saturation methods, and end products are also described.

Claims (54)

1. A method of forming a foamed thermoplastic sheet, comprising:

disposing a thermoplastic sheet in a pressure vessel;

allowing the thermoplastic sheet to absorb an inert gas in the pressure vessel for a time period of less than 45 minutes to at least partially saturate the thermoplastic sheet, the thermoplastic sheet having a first side and a second side, the second side opposite the first side;

transferring water to the pressure vessel while the thermoplastic sheet is absorbing the inert gas; and

applying heat to the first side to induce asymmetric foaming in the thermoplastic sheet;

wherein the heat applied to the first side produces a foamed thermoplastic sheet having cells of a first average size on the first side and cells of a second average size on the second side, the first average size larger than the second average size.

2. The method of claim 1 , wherein the thermoplastic sheet includes polylactic acid.

3. The method of claim 1 , further comprising:

extruding the thermoplastic sheet.

4. The method of claim 1 , wherein the inert gas in the pressure vessel is at a pressure between 400 PSI and 1,000 PSI.

5. The method of claim 1 , further comprising:

drawing the foamed thermoplastic sheet into a mold to form a shape.

6. The method of claim 5 , wherein the mold is processed in a thermoformer.

7. The method of claim 5 , wherein the shape is a cup or a tray.

8. The method of claim 1 , further comprising:

adding a colorant to the thermoplastic sheet.

9. The method of claim 1 , further comprising:

stretching the thermoplastic sheet while applying heat to the thermoplastic sheet.

10. A method, comprising:

disposing a thermoplastic sheet in a pressure vessel;

allowing the thermoplastic sheet to absorb an inert gas in the pressure vessel for less than 45 minutes to at least partially saturate the thermoplastic sheet;

transferring water to the pressure vessel while the inert gas is being absorbed by the thermoplastic sheet;

applying heat at a first rate to a first side of the thermoplastic sheet; and

applying heat at a second rate to a second side of the thermoplastic sheet, the second rate less than the first rate, the differential between the first rate and the second rate inducing asymmetric foaming of the thermoplastic sheet.

11. The method of claim 10 , wherein the second rate is zero.

12. The method of claim 10 , wherein the thermoplastic sheet includes polylactic acid.

13. The method of claim 10 , further comprising:

extruding the thermoplastic sheet.

14. The method of claim 10 , wherein the inert gas in the pressure vessel is at a pressure between 400 PSI and 1,000 PSI.

15. The method of claim 10 , further comprising:

drawing the thermoplastic sheet into a mold to form a shape.

16. The method of claim 15 , wherein the mold is processed in a thermoformer.

17. The method of claim 15 , wherein the shape is a cup or a tray.

18. The method of claim 10 , further comprising:

adding a colorant to the thermoplastic sheet.

19. The method of claim 10 , further comprising:

stretching the thermoplastic sheet while applying heat to the thermoplastic sheet.

20. A method, comprising:

disposing a thermoplastic sheet in a pressure vessel;

allowing the thermoplastic sheet to absorb an inert gas in the pressure vessel for less than 45 minutes during a first time period to at least partially saturate the thermoplastic sheet, the thermoplastic sheet having a first side and a second side, the second side opposite the first side;

transferring water to the pressure vessel while the inert gas is being absorbed by the thermoplastic sheet;

applying heat to the first side at a first intensity while applying heat to the second side at a second intensity to form a foamed thermoplastic sheet, the second intensity less than the first intensity; and

drawing the foamed thermoplastic sheet into a shape on a mold.

21. The method of claim 20 , wherein the second intensity is zero.

22. The method of claim 20 , wherein the thermoplastic sheet includes polylactic acid.

23. The method of claim 20 , further comprising:

extruding the thermoplastic sheet.

24. The method of claim 20 , wherein the inert gas in the pressure vessel is at a pressure between 400 PSI and 1,000 PSI.

25. The method of claim 20 , wherein the mold is processed in a thermoformer.

26. The method of claim 20 , wherein the shape is a cup or a tray.

27. The method of claim 20 , further comprising:

adding a colorant to the thermoplastic sheet.

28. The method of claim 20 , further comprising:

stretching the thermoplastic sheet while applying heat to the thermoplastic sheet.

Assignments (3)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Sep 15, 2026
From: CORUMAT, INC.
To: SHELL USA, INC.,
Reel/Frame 076013/0485 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Sep 3, 2020
From: WAGGONER, MIKE
To: GROW PLASTICS LLC
Reel/Frame 053684/0563 →
CERTIFICATE OF CONVERSION Recorded Sep 3, 2020
From: GROW PLASTICS LLC
To: CORUMAT, INC.
Reel/Frame 054165/0026 →
Continuity (3)
Continuation 14308959 · Jun 19, 2014
Provisional Application 61837110 · Jun 19, 2013
Related Publication 20200325299A1 · Oct 15, 2020