Quantum dot and manufacturing method for the same and application using the same
The present disclosure provides a quantum dot and a manufacturing method for the same, and a luminescent material, a light-emitting element and a display device applying the quantum dot. The quantum dot includes a nano-crystal and a ligand. The nano-crystal is at least one selected from the group consisting of a XII-XV group compound semiconductor nano-crystal, a XII-XVI group compound semiconductor nano-crystal, a XIII-XV group compound semiconductor nano-crystal and a XIII-XVI group compound semiconductor nano-crystal. The ligand is disposed on a surface of the nano-crystal. The ligand contains 15%-70% of a fatty acid compound, 1%-35% of a phosphine compound, >0%-55% of a thiol compound, and 0%-10% of another ligand substance.
1. A quantum dot, comprising:
a nano-crystal being at least one selected from the group consisting of a XII-XV group compound semiconductor nano-crystal, a XII-XVI group compound semiconductor nano-crystal, a XIII-XV group compound semiconductor nano-crystal and a XIII-XVI group compound semiconductor nano-crystal; and
a ligand disposed on a surface of the nano-crystal, wherein the ligand contains 15%-70% of a fatty acid compound, 1%-35% of a phosphine compound, >0%-55% of a thiol compound, and 0%-10% of another ligand substance, obtained by calculating ratios of respective integrated areas to a total integrated area of spectrum peaks corresponding to the fatty acid compound, the phosphine compound, the thiol compound, and the another ligand substance in a gas chromatography spectrum.
2. The quantum dot according to claim 1 , wherein,
the fatty acid compound comprises an oleate, a stearic acid, a lauric acid, or a combination thereof;
the phosphine compound comprises trioctylphosphine, triphenylphosphine, t-butylphosphine, or a combination thereof;
the thiol compound comprises octanethiol, 1,8-octanedithiol, 1-dodecanethiol, 1-undecanethiol, 1,4-benzene dimethanethiol, 1,16-hexadecanedithiol, 1,11-undecanedithiol, 4,4′-biphenylldithiol, 11-mercapto-1-undecanol, or a combination thereof; and/or
the another ligand substance comprises octylamine, dioctylamine, 1-hexadecylamine, oleylamine, a fluorine ion, a chlorine ion, a bromine ion, an iodine ion, or a combination thereof.
3. The quantum dot according to claim 1 , wherein the nano-crystal comprises a core and a shell enclosing the core.
4. The quantum dot according to claim 1 , wherein the thiol compound occupies 5%-55% of the ligand.
5. The quantum dot according to claim 1 , wherein the fatty acid compound occupies 20%-65% of the ligand, the phosphine compound occupies 1%-30% of the ligand, the thiol compound occupies 10%-50% of the ligand.
6. The quantum dot according to claim 1 , wherein the fatty acid compound occupies 25%-65% of the ligand, the phosphine compound occupies 5%-30% of the ligand, the thiol compound occupies 10%-50% of the ligand.
7. A luminescent material comprising the quantum dot according to claim 1 .
8. A light-emitting element, comprising:
a light source; and
an encapsulating material comprising the luminescent material according to claim 7 , wherein the encapsulating material encloses the light source.
9. A display device, comprising the light-emitting element according to claim 8 , wherein the display device is at least one selected from the group consisting of a television, a digital photo camera, a digital video camera, a digital photo frame, a mobile phone, a notebook, a mobile computer, a computer screen, a portable game console, a portable information terminal, a portable audio player, a game console, a car display and a wearable device.
10. A quantum dot, comprising:
a nano-crystal being at least one selected from the group consisting of a XII-XV group compound semiconductor nano-crystal, a XII-XVI group compound semiconductor nano-crystal, a XIII-XV group compound semiconductor nano-crystal and a XIII-XVI group compound semiconductor nano-crystal; and
a ligand disposed on a surface of the nano-crystal, wherein the ligand consists essentially of a thiol compound, a fatty acid compound and a phosphine compound, wherein the fatty acid compound occupies 20%-65% of the ligand, the phosphine compound occupies 1 %- 30 % of the ligand, the thiol compound occupies 10%-50% of the ligand, obtained by calculating ratios of respective integrated areas to a total integrated area of spectrum peaks corresponding to the fatty acid compound, the phosphine compound, and the thiol compound in a gas chromatography spectrum.
11. The quantum dot according to claim 10 , wherein
the fatty acid compound comprises an oleate, a stearic acid, a lauric acid, or a combination thereof;
the phosphine compound comprises trioctylphosphine, triphenylphosphine, t-butylphosphine, or a combination thereof; and/or
the thiol compound comprises octanethiol, 1,8-octanedithiol, 1-dodecanethiol, 1-undecanethiol, 1,4-benzene dimethanethiol, 1,16-hexadecanedithiol, 1,11-undecanedithiol, 4,4′-biphenylldithiol, 11-mercapto-1-undecanol, or a combination thereof.
12. The quantum dot according to claim 10 , wherein the nano-crystal comprises a core and a shell enclosing the core.
13. The quantum dot according to claim 10 , wherein the fatty acid compound occupies 25%-65% of the ligand, the phosphine compound occupies 5%-30% of the ligand.
14. A method for manufacturing a quantum dot, comprising mixing a nano-crystal and a ligand in a liquid phase environment, wherein the nano-crystal is at least one selected from the group consisting of a XII-XV group compound semiconductor nano-crystal, a XII-XVI group compound semiconductor nano-crystal, a XIII-XV group compound semiconductor nano-crystal, and a XIII-XVI group compound semiconductor nano-crystal, the ligand contains a fatty acid compound, a phosphine compound, and a thiol compound.
15. The method for manufacturing the quantum dot according to claim 14 , wherein,
the fatty acid compound comprises an oleate, a stearic acid, a lauric acid, or a combination thereof;
the phosphine compound comprises trioctylphosphine, triphenylphosphine, t-butylphosphine, or a combination thereof;
the thiol compound comprises octanethiol, 1,8-octanedithiol, 1-dodecanethiol, 1-undecanethiol, 1,4-benzene dimethanethiol, 1,16-hexadecanedithiol, 1,11-undecanedithiol, 4,4′-biphenylldithiol, 11-mercapto-1-undecanol, or a combination thereof.
16. The method for manufacturing the quantum dot according to claim 14 , wherein the nano-crystal comprises a core and a shell enclosing the core.
17. The method for manufacturing the quantum dot according to claim 14 , wherein the thiol compound occupies 5%-55% of the ligand, obtained by calculating a ratio of an integrated area of a spectrum peak corresponding to the thiol compound to a total integrated area of spectrum peaks corresponding to all compounds of the ligand in a gas chromatography spectrum.
18. The method for manufacturing the quantum dot according to claim 14 , wherein the fatty acid compound occupies 20%-65% of the ligand, the phosphine compound occupies 1%-30% of the ligand, the thiol compound occupies 10%-50% of the ligand, obtained by calculating ratios of respective integrated areas corresponding to the fatty acid compound, the phosphine compound, and the thiol compound to a total integrated area of spectrum peaks corresponding to all compounds of the ligand in a gas chromatography spectrum.