Multilayer polymer film
In a first aspect, a multilayer polymer film includes a first transparent, colorless polymer layer comprising a polyimide, a polyamide imide, or a block copolymer of a polyimide and a second transparent, colorless polymer layer comprising a polyimide, a polyamide imide, or a block copolymer of a polyimide. An elastic modulus of the first transparent, colorless polymer layer is different than an elastic modulus of the second transparent, colorless polymer layer. The first and second transparent, colorless polymer layers are bonded by consolidation. In a second aspect, a cover window for a display includes the multilayer polymer film of the first aspect. The first transparent, colorless layer of the multilayer polymer film is the layer farthest from the display.
1. A multilayer polymer film comprising:
a first transparent, colorless polymer layer comprising a polyimide, a polyamide imide, or a block copolymer of a polyimide, and having a first elastic modulus; and
a second transparent, colorless polymer layer comprising a polyimide, a polyamide imide, or a block copolymer of a polyimide, and having a second elastic modulus, wherein:
the polymers of both the first and second transparent, colorless polymer layers are cross-linked;
the first elastic modulus is different from the second elastic modulus; and
the first and second transparent, colorless polymer layers are bonded by consolidation and cross-linking.
2. The multilayer polymer film of claim 1 , wherein the first transparent, colorless polymer layer, the second transparent, colorless layer, or both the first and second transparent, colorless polymer layers further comprise inorganic nanoparticles.
3. The multilayer polymer film of claim 1 , wherein: (i) the first transparent, colorless polymer layer further comprises an imidization catalyst, or (ii) the second transparent, colorless polymer layer further comprises an imidization catalyst, or (iii) both the first and second transparent, colorless polymer layers further comprise an imidization catalyst.
4. The multilayer polymer film of claim 1 , wherein a Mode I interlaminar fracture toughness (G Ic ) between the first and second transparent, colorless polymer layers is at least 500 J/m 2 .
5. The multilayer polymer film of claim 1 , wherein a difference between the elastic moduli of the first and second transparent, colorless polymer layers is at least 5%.
6. The multilayer polymer film of claim 1 , further comprising a third transparent, colorless polymer layer comprising a polyimide, a polyamide imide, or a block copolymer of a polyimide, and having a third elastic modulus, wherein the second transparent, colorless polymer layer is positioned between the first and third transparent, colorless polymer layers and the second and third transparent, colorless polymer layers are bonded by consolidation.
7. The multilayer polymer film of claim 6 , wherein a difference between the elastic moduli of the second and third transparent, colorless polymer layers is at least 5%.
8. The multilayer polymer film of claim 6 , wherein: (i) the second elastic modulus is smaller than the first elastic modulus and the third elastic modulus is greater than the second elastic modulus, or (ii) the second elastic modulus is greater than the first elastic modulus and the third elastic modulus is greater than the second elastic modulus, or (iii) the second elastic modulus is smaller than the first elastic modulus and third elastic modulus smaller than the second elastic modulus.
9. The multilayer polymer film of claim 6 , wherein: (i) the first elastic modulus and the third elastic modulus are essentially the same, or (ii) the first elastic modulus is greater than the third elastic modulus, or (iii) the third elastic modulus is greater than the first elastic modulus.
10. The multilayer polymer film of claim 6 , wherein the third transparent, colorless polymer layer is cross-linked.
11. The multilayer polymer film of claim 10 , wherein the second and third transparent, colorless polymer layers are further bonded by cross-linking.
12. The multilayer polymer film of claim 6 , wherein a Mode I interlaminar fracture toughness (G Ic ) between the second and third transparent, colorless polymer layers is at least 500 J/m 2 .