IP Library Granted Patent US 12,329,154
Granted Patent B2
US 12,329,154 · App. 16/694,739 · Granted Jun 17, 2025

Non-sorptive or minimally sorptive disinfectant wipes

Inventors: David D. McSherry (St. Paul, MN); Junzhong Li (Eagan, MN); Richard K. Staub (Bloomington, MN); Joy G. Herdt (Hastings, MN); Sherri L. Tischler (Inver Grove Heights, MN)
Assignee: ECOLAB USA INC.
A01N25/10A01N25/34A01N41/04
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Quick Facts
Patent No.
US 12,329,154
App. No.
16/694,739
Granted
Jun 17, 2025
Kind
B2
Abstract

A disinfectant wipe is provided including a substrate that is substantially free of polyamides, and an acid anionic disinfectant is adsorbed to the substrate such that the disinfectant readily releases from the substrate to allow at least 65% delivery of the disinfectant when wiped on a surface. The substrate may be a woven, nonwoven, knit fabric, a foam, sponge or film composition and may be formed from polyester, polypropylene, nylon, cotton, rayon, acrylic, or combinations thereof. The acid anionic disinfectant has a pH below 7, below 5, below 3 and below 2. The substrate used to prepare the disinfectant wipe is not pretreated with the disinfectant or a release composition before applying the disinfectant. That is, the disinfectant is not applied and re-applied to ensure release onto a surface. In an embodiment of the invention acid anionic disinfectant is an antimicrobial agent.

Claims (37)

1. A method of disinfecting comprising:

wiping a surface with a wipe comprising:

a disinfectant composition having a pH below 5 and consisting essentially of an aqueous solution of an acid anionic disinfectant selected from the group of linear alkylbenzene sulfonic acid, dodecylbenzene sulfonic acid, dodecylsulfonic acid, lauryl sulfonic acid, sulfonated oleic acid, and mixtures thereof and optionally one or more additives selected from the group of fragrance, dye, emollient, UV light protecting agents, insect repellency agents, and souring agents; and

a polyester microfiber substrate that is substantially free of polyamides;

wherein the wipe releases an amount of disinfectant composition on the surface sufficient to kill viruses or bacteria within 30 seconds of contact and the substrate is not pretreated before the disinfectant composition is added to it.

2. The method of claim 1 , wherein the substrate is a nonwoven material.

3. The method of claim 1 , wherein the substrate is a nonwoven material manufactured by spinbonding, meltblowing, dry laid, air laid, or wet laid processes.

4. The method of claim 1 , wherein the disinfectant composition has a pH below 4.

5. The method of claim 1 , wherein the disinfectant composition has a pH below 3.

6. The method of claim 1 , wherein the disinfectant composition has a pH below 2.

7. The method of claim 1 , wherein the substrate is not pretreated with a release composition and at least 75% of the disinfectant composition is released from the substrate when squeezed.

8. A method of applying an antimicrobial composition to a surface comprising:

wiping a surface with a wipe comprising:

a disinfectant composition having a pH below 5 and consisting essentially of an aqueous solution of an acid anionic disinfectant selected from the group of linear alkylbenzene sulfonic acid, dodecylbenzene sulfonic acid, dodecyl sulfonic acid, lauryl sulfonic acid, sulfonated oleic acid, and mixtures thereof and optionally one or more additives selected from the group of fragrance, dye, emollient, UV light protecting agents, insect repellency agents, and souring agents; and

a polyester microfiber substrate that is substantially free of polyamides;

wherein the substrate is not pretreated before the disinfectant composition is added to it and at least 75% of the disinfectant composition is released from the substrate when squeezed.

9. The method of claim 8 , wherein the substrate is a nonwoven material.

10. The method of claim 8 , wherein the substrate is a nonwoven material manufactured by spinbonding, meltblowing, dry laid, air laid, or wet laid processes.

11. The method of claim 8 , wherein the disinfectant composition has a pH below 4.

12. The method of claim 8 , wherein the disinfectant composition has a pH below 3.

13. The method of claim 8 , wherein the disinfectant composition has a pH below 2.

14. The method of claim 8 , wherein at least 80% of the disinfectant composition is released from the substrate when squeezed.

15. The method of claim 8 , wherein at least 85% of the disinfectant composition is released from the substrate when squeezed.

16. The method of claim 8 , wherein at least 90% of the disinfectant composition is released from the substrate when squeezed.

17. A method of manufacturing an antimicrobial wipe comprising:

selecting a polyester microfiber substrate that is substantially free of polyamides and not pretreated; and

coating a disinfectant composition onto the substrate, the disinfectant composition having a pH below 5 and consisting essentially of an aqueous solution of an acid anionic disinfectant selected from the group of linear alkylbenzene sulfonic acid, dodecylbenzene sulfonic acid, dodecyl sulfonic acid, lauryl sulfonic acid, sulfonated oleic acid, and mixtures thereof and optionally one or more additives selected from the group of fragrance, dye, emollient, UV light protecting agents, insect repellency agents, and souring agents;

wherein at least 75% of the disinfectant composition is released from the substrate when squeezed.

18. The method of claim 17 , wherein the disinfectant composition retains its antimicrobial properties and is able to be released from the substrate for at least one year after manufacturing.

19. The method of claim 17 , wherein the substrate is a nonwoven material.

20. The method of claim 17 , wherein the substrate is a nonwoven material manufactured by spinbonding, meltblowing, dry laid, air laid, or wet laid processes.

21. The method of claim 17 , wherein the disinfectant composition has a pH below 4.

22. The method of claim 17 , wherein the disinfectant composition has a pH below 3.

23. The method of claim 17 , wherein the disinfectant composition has a pH below 2.

24. The method of claim 17 , wherein at least 80% of the disinfectant composition is released from the substrate when squeezed.

25. The method of claim 17 , wherein at least 85% of the disinfectant composition is released from the substrate when squeezed.

26. The method of claim 17 , wherein at least 90% of the disinfectant composition is released from the substrate when squeezed.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Apr 21, 2021
From: MCSHERRY, DAVID D.; LI, JUNZHONG; STAUB, RICHARD K.; HERDT, JOY G.; TICHLER, SHERRI L.
To: ECOLAB USA INC.
Reel/Frame 055986/0944 →
Continuity (3)
Continuation 14199202 · Mar 6, 2014
Provisional Application 61790458 · Mar 15, 2013
Related Publication 20200163329A1 · May 28, 2020
References Cited (78)
US 3895474A · Bauer · 1975 [cited by applicant]
US 4408996A · Baldwin · 1983 [cited by applicant]
US 4666621A · Clark et al. · 1987 [cited by applicant]
US 4737405A · Bouchette · 1988 [cited by applicant]
US 4759867A · Choy et al. · 1988 [cited by applicant]
US 4781974A · Bouchette et al. · 1988 [cited by applicant]
US 4847088A · Blank · 1989 [cited by applicant]
US 4941989A · Kramer et al. · 1990 [cited by applicant]
US 4946617A · Sheridan et al. · 1990 [cited by applicant]
US 5141803A · Pregozen · 1992 [cited by applicant]
US 5152996A · Corey et al. · 1992 [cited by applicant]
US 5419908A · Richter et al. · 1995 [cited by applicant]
US 5421898A · Cavanagh · 1995 [cited by applicant]
US 5958491A · Knueven · 1999 [cited by examiner]
US 6258368B1 · Beerse et al. · 2001 [cited by applicant]
US 6258455B1 · Clarke · 2001 [cited by applicant]
US 6410499B1 · Julemont et al. · 2002 [cited by applicant]
US 6482423B1 · Beerse et al. · 2002 [cited by applicant]
US 6488948B1 · Danicli · 2002 [cited by applicant]
US 6610314B2 · Koenig et al. · 2003 [cited by applicant]
US 6667290B2 · Svendsen · 2003 [cited by applicant]
US 6699825B2 · Rees · 2004 [cited by third party]
US 6838078B2 · Wang et al. · 2005 [cited by applicant]
US 6916776B2 · Svendsen · 2005 [cited by applicant]
US 6936580B2 · Sherry et al. · 2005 [cited by applicant]
US 6994890B2 · Ohlhausen et al. · 2006 [cited by applicant]
US 7160846B2 · Biering et al. · 2007 [cited by applicant]
US RE40495E · Svendsen · 2008 [cited by applicant]
US 7432234B2 · Ochomogo et al. · 2008 [cited by applicant]
US 7485589B2 · Ellis · 2009 [cited by applicant]
US 7696109B2 · Ouellette · 2010 [cited by examiner]
US 7700530B2 · Mundschau et al. · 2010 [cited by applicant]
US 7799751B2 · Kilkenny et al. · 2010 [cited by applicant]
US 7858106B2 · Nonaka · 2010 [cited by applicant]
US 7998495B2 · Argo et al. · 2011 [cited by applicant]
US 8287657B2 · Song et al. · 2012 [cited by applicant]
US 8388922B2 · Sotowa et al. · 2013 [cited by applicant]
US 8486427B2 · Colman et al. · 2013 [cited by applicant]
US 8545862B2 · Toreki et al. · 2013 [cited by applicant]
US 8809213B2 · Wildeman et al. · 2014 [cited by applicant]
US 10238108B2 · Griese · 2019 [cited by third party]
US 10294444B2 · Turk et al. · 2019 [cited by applicant]
US 20020049257A1 · Natsch · 2002 [cited by applicant]
US 20020155969A1 · Rees et al. · 2002 [cited by applicant]
US 20030194932A1 · Clark et al. · 2003 [cited by applicant]
US 20040137815A1 · Ellis et al. · 2004 [cited by applicant]
US 20040157931A1 · Ra et al. · 2004 [cited by applicant]
US 20040228904A1 · Ellis et al. · 2004 [cited by applicant]
US 20050047961A1 · Bains et al. · 2005 [cited by third party]
US 20050239356A1 · Parsons et al. · 2005 [cited by applicant]
US 20060062832A1 · Lopes · 2006 [cited by applicant]
US 20060128248A1 · Ellis · 2006 [cited by applicant]
US 20070141127A1 · Casas-Sanchez et al. · 2007 [cited by applicant]
US 20070142261A1 · Clark et al. · 2007 [cited by applicant]
US 20070237807A1 · Luu et al. · 2007 [cited by applicant]
US 20090285871A1 · Cunningham et al. · 2009 [cited by third party]
US 20100101605A1 · Saint Victor · 2010 [cited by applicant]
US 20100113537A1 · Nonaka · 2010 [cited by applicant]
US 20100136074A1 · Bukshpan et al. · 2010 [cited by applicant]
US 20100207805A1 · Haworth · 2010 [cited by applicant]
US 20110097422A1 · Lopes · 2011 [cited by examiner]
US 20110177148A1 · Dicosimo et al. · 2011 [cited by applicant]
US 20120045496A1 · Short et al. · 2012 [cited by applicant]
US 20120070480A1 · Amos et al. · 2012 [cited by applicant]
US 20120070481A1 · Bolkan et al. · 2012 [cited by applicant]
US 20120171155A1 · Cunningham et al. · 2012 [cited by applicant]
US 20120171300A1 · Koenig et al. · 2012 [cited by applicant]
US 20120207805A1 · Colman et al. · 2012 [cited by applicant]
US 20130058880A1 · Dong · 2013 [cited by applicant]
EP 0131394A2 · 1985 [cited by applicant]
EP 1488815A1 · 2004 [cited by applicant]
EP 1747258B1 · 2008 [cited by applicant]
WO 0100782A1 · 2001 [cited by applicant]
WO 2004041312A2 · 2004 [cited by applicant]
Bourgeois, Michel, Index 93 Congress Session 3D: R & D—Polymer Fibres & Surface Modification, “Fibres with Antiseptic Action,” Innventia AB (1993). [cited by applicant]
Getman, Gerry, An Advanced Polymeric Antimicrobial for Non Woven Fabrics and Solid Materials including Spun Plastic Resins, Sep. 2007, Presentation from INDA/TAPPI International Nonwovens Technical Conference. [cited by applicant]
Masuku, S. M., et al. “Cleaning and decontamination efficacy of wiping cloths and sliver dihydrogen citrate on food contact surfaces,” Journal of Applied Microbiology, vol. 113, pp. 89-95, ISSN 1364-5072, 2012. [cited by applicant]
Dychdala et al. (1991), Surface-Active Agents: Acid-Anionic Compounds, in Seymour S. Block, Disinfection, Sterilization, and Preservation (4th ed., pp. 256-261), Lea & Febiger (“Dychdala”). [cited by third party]