IP Library Granted Patent US 11,361,877
Granted Patent B2
US 11,361,877 · App. 16/702,761 · Granted Jun 14, 2022

Graphene entrainment in a host

Inventors: Richard Stoltz (Rowlett, TX); Jeff Bullington (Orlando, FL)
Assignee: Asbury Graphite of North Carolina, Inc.
H01B1/04B82Y40/00C01B32/182C01B32/19C01B32/194C01B32/23B82Y30/00C01P2004/24
View Patent ↗
Loading inventors, assignments & file history…
Monitor This Case
Get email alerts when status or documents change.
Order Certified Copies
Most orders are placed with the USPTO same day — all within 24 business hours.
Order via The Patent Place →
Pre-filled with this patent's details
Quick Facts
Patent No.
US 11,361,877
App. No.
16/702,761
Granted
Jun 14, 2022
Kind
B2
Abstract

This is generally a method of producing graphene-containing suspensions of flakes of high quality graphene/graphite oxides and method of producing graphene/graphite oxides. Both the exfoliating graphite into flakes and oxidizing the graphite flakes and the preparation and suspension of the flakes can be done with high volume production and at a low cost.

Claims (11)

1. A method of entraining graphene in a bonding host comprising:

preparing graphene flakes with a surface area to thickness ratio greater than 300 Angstroms, and thickness of less than 160 Angstroms, wherein the graphene flakes have no substantial physical surface distortions, have a surface polarity, and have only edge oxidation;

preparing a polar or nonpolar fluid having the same polarity as the graphene flakes;

mixing the graphene flakes in the polar or nonpolar fluid, wherein a distribution of the graphene flakes in the polar or nonpolar fluid is uniform;

adding a bonding host, wherein surfaces of the graphene flakes have the same polarity as the bonding host;

entraining the graphene flakes in the bonding host in a partial or full vacuum to prevent incorporation of gases into the bonding host; and

applying one or more dynamic magnetic fields to enhance orientation of the graphene flakes in the bonding host.

2. The method of claim 1 , wherein the surface area to thickness ratio of 95% of the graphene flakes is greater than 300 Angstroms.

3. The method of claim 1 , wherein a maximum dimension of the graphene flakes is between 220 Angstroms and 100 microns.

4. The method of claim 1 , wherein the preparing the graphene flakes comprises mechanically exfoliating graphite into the graphene flakes in a an Attrition mill or a ball mill.

5. The method of claim 1 wherein the graphene flakes are substantially flat, the polar or nonpolar fluid is water, and the mixed substantially flat graphene flakes and the water are substantially limited to the substantially flat graphene flakes and the water.

Assignments (6)
SECURITY AGREEMENT Recorded Mar 27, 2023
From: ASBURY GRAPHITE OF NORTH CAROLINA, INC.; ASBURY CARBONS, INC.; PEC FRICTION FIGHTERS CORPORATION
To: PNC BANK, NATIONAL ASSOCIATION, AS AGENT
Reel/Frame 063169/0025 →
CORRECTIVE ASSIGNMENT TO CORRECT THE DELETE PATENT APPLICATIONS 15554974, 62899396, & 17012913 (974 ONLY LICENSED & 396 & 913 JIONLY OWNED WITH ANOTHER). PREVIOUSLY RECORDED AT REEL: 057306 FRAME: 0139. ASSIGNOR(S) HEREBY CONFIRMS THE ASSIGNMENT. Recorded Dec 15, 2022
From: GARMOR, INC.
To: ASBURY GRAPHITE OF NORTH CAROLINA, INC.
Reel/Frame 062248/0807 →
RELEASE OF SECURITY INTEREST Recorded Oct 12, 2021
From: ASBURY CARBONS, INC.
To: GARMOR, INC.
Reel/Frame 057763/0871 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Aug 27, 2021
From: GARMOR, INC.
To: ASBURY GRAPHITE OF NORTH CAROLINA, INC.
Reel/Frame 057306/0139 →
SECURITY INTEREST Recorded Mar 29, 2021
From: GARMOR, INC.
To: ASBURY CARBONS, INC.
Reel/Frame 055757/0308 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Dec 4, 2019
From: BULLINGTON, JEFF; STOLTZ, RICHARD
To: GARMOR INC.
Reel/Frame 051183/0636 →
Continuity (8)
Continuation 14773013
Provisional Application 61788247 · Mar 15, 2013
Provisional Application 61775113 · Mar 8, 2013
Provisional Application 61775071 · Mar 8, 2013
Provisional Application 61775099 · Mar 8, 2013
Provisional Application 61775024 · Mar 8, 2013
Provisional Application 61775087 · Mar 8, 2013
Related Publication 20200105435A1 · Apr 2, 2020