Electrode of nonaqueous electrolyte secondary battery, nonaqueous electrolyte secondary battery, method for producing electrode, and method for producing nonaqueous electrolyte secondary battery
A positive electrode includes a positive electrode substrate and a positive electrode active material layer disposed on at least one surface of the positive electrode substrate. The positive electrode active material layer contains a positive electrode active material, a binder, and an electroconductive agent. The positive electrode active material layer contains, as the electroconductive agent, a string-shaped agglomerate formed of fibrous carbons gathered and entangled with each other. The agglomerate has a length of 30 μm or more.
1. An electrode comprising:
a substrate; and
an active material layer disposed on at least one surface of the substrate,
wherein the active material layer contains an active material, a binder, and an electroconductive agent,
the active material layer contains, as the electroconductive agent, a string-shaped agglomerate formed of linearly connected carbon particles forming a plurality of fibrous carbons gathered and entangled with each other, and
the agglomerate has a length of 30 μm or more.
2. The electrode according to claim 1 , wherein the agglomerate has a minimum outer diameter of 40 nm or more.
3. The electrode according to claim 1 , wherein 650 to 3000 of the agglomerates are present per mm 3 of the active material layer.
4. The electrode according to claim 1 , wherein 20 to 90 of the agglomerates are present per mm 2 of the active material layer.
5. The electrode according to claim 1 , wherein the agglomerates are contained in the active material layer in an amount of 2.8 to 4.2 mass %.
6. The electrode according to claim 1 , wherein the active material layer contains a plurality of the agglomerates, and
10 mass % or more of the total agglomerates contained in the active material layer are in contact with the substrate.
7. The electrode according to claim 1 , wherein the active material layer contains a plurality of the agglomerates, and
30 mass % or more of the total agglomerates contained in the active material layer have a branched structure.
8. The electrode according to claim 1 , wherein the active material layer contains a plurality of the agglomerates, and
10 mass % or more of the total agglomerates contained in the active material layer have a length larger than a thickness of the active material layer.
9. The electrode according to claim 1 , wherein the substrate is a positive electrode substrate, and the active material layer is a positive electrode active material layer, and
the electroconductive agent contains acetylene black.
10. A nonaqueous electrolyte secondary battery comprising the electrode according to claim 1 .
11. A method for producing an electrode according to claim 1 comprising:
a first stirring step of mixing and stirring an active material, an electroconductive agent, a binder, and a dispersion medium to produce a temporary active material slurry, and
a second stirring step of adding an electroconductive agent to the temporary active material slurry and performing stirring after the first stirring step.
12. The method for producing an electrode, according to claim 11 , wherein the second stirring step includes adding a dispersion medium to the temporary active material slurry and performing stirring.
13. The method for producing an electrode, according to claim 11 , wherein a total mass of the electroconductive agent added in the second stirring step is 0.9 to 1.1 times a total mass of the electroconductive agent added in the first stirring step.
14. The method for producing an electrode, according to claim 11 , wherein the second stirring step is performed by using a kneader including a stirring blade, and
a peripheral speed of the stirring blade is 375 to 750 m/min.
15. A method for producing a nonaqueous electrolyte secondary battery, the method comprising the method according to claim 11 for producing an electrode of a nonaqueous electrolyte secondary battery.