IP Library Granted Patent US 11,125,495
Granted Patent B2
US 11,125,495 · App. 16/733,982 · Granted Sep 21, 2021

Carbon dioxide recycle stream processing in an enhanced oil recovery process

Inventor: Eric Prim (Spring, TX)
Assignee: Pilot Energy Solutions, LLC
F25J3/0204C10L3/104F25J3/0209F25J3/0233F25J3/0242F25J3/0266F25J3/044F25J2200/02F25J2200/74F25J2205/04F25J2215/04F25J2215/80F25J2220/02F25J2220/64F25J2220/66F25J2220/68F25J2260/80F25J2290/10Y02C20/40
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Quick Facts
Patent No.
US 11,125,495
App. No.
16/733,982
Granted
Sep 21, 2021
Kind
B2
Abstract

A method for recovering natural gas liquids from a recycle stream having natural gas liquids includes receiving a carbon dioxide recycle stream that comprises carbon dioxide, natural gas, and the natural gas liquids. The carbon dioxide recycle stream is separated into a purified carbon dioxide recycle stream and a natural gas liquids stream. The purified carbon dioxide recycle stream comprises the carbon dioxide and the natural gas, and the natural gas liquids stream comprises the natural gas liquids. In another embodiment, a system comprises piping and a separator. The piping is configured to receive a recycle stream, and the separator is coupled to the piping and is configured to separate the recycle stream into a purified recycle stream and a natural gas liquids stream.

Claims (42)

1. A set of process equipment for use in an enhanced oil recovery (EOR) process, the set of process equipment comprising:

a heat exchanger configured to receive a carbon dioxide recycle stream and cool the carbon dioxide recycle stream to produce a cooled carbon dioxide recycle stream, wherein the cooled carbon dioxide recycle stream comprises carbon dioxide, C 1 -C 8 hydrocarbons, and is dehydrated;

a multi-stage column configured to receive the cooled carbon dioxide recycle stream and produce a top effluent stream and a bottom effluent stream;

a single stage separator configured to receive the top effluent stream and produce a vapor stream and a liquid stream, wherein the vapor stream is transferred to the heat exchanger to produce a heated vapor stream, wherein the heated vapor stream comprises a first portion of the carbon dioxide and C 1 -C 4 hydrocarbons, wherein the first portion of the carbon dioxide comprises greater than 0.50 mole fraction of the heated vapor stream, wherein a first mole fraction of C 3 hydrocarbons in the heated vapor stream is less than a second mole fraction of C 3 hydrocarbons in the bottom effluent stream, and wherein both the first mole fraction and the second mole fraction are greater than 0.00 mole fraction;

an expander configured to receive the bottom effluent stream and produce an expanded bottom effluent stream, wherein the expanded bottom effluent stream comprises a second portion of the carbon dioxide and C 3 -C 8 hydrocarbons; and

an additional separator configured to receive the expanded bottom effluent stream from the expander and produce an acid gas stream and a sweetened hydrocarbon stream, wherein the acid gas stream comprises the second portion of the carbon dioxide, and wherein the sweetened hydrocarbon stream comprises the C 3 -C 8 hydrocarbons.

2. The set of process equipment of claim 1 , further comprising a molecular sieve dehydrator configured to receive a feed stream and dehydrate the feed stream to produce the carbon dioxide recycle stream.

3. The set of process equipment of claim 1 , wherein the carbon dioxide recycle stream, the heated vapor stream, and the bottom effluent stream are not processed by membranes.

4. The set of process equipment of claim 1 , wherein the carbon dioxide recycle stream, the heated vapor stream, and the bottom effluent stream are not subjected to carbon dioxide recovery solvents.

5. A method for use in an enhanced oil recovery (EOR) process, the method comprising:

receiving, by a dehydrator, a feed stream comprising water, carbon dioxide, and C 1 -C 8 hydrocarbons;

dehydrating, by the dehydrator, the feed stream to produce a carbon dioxide recycle stream, wherein the carbon dioxide recycle stream comprises carbon dioxide, C 1 -C 8 hydrocarbons, and is dehydrated;

cooling, by a heat exchanger, the carbon dioxide recycle stream to produce a cooled carbon dioxide recycle stream;

separating, by a multi-stage separator, the cooled carbon dioxide recycle stream into a top effluent stream and a bottom effluent stream;

separating, by a single-stage separator, the top effluent stream into a vapor stream and a liquid stream;

heating, by the heat exchanger, the vapor stream to produce a heated vapor stream, wherein the heated vapor stream comprises a first portion of the carbon dioxide and C 1 -C 4 hydrocarbons, wherein the first portion of the carbon dioxide comprises greater than 0.50 mole fraction of the heated vapor stream, wherein a first mole fraction of C 3 hydrocarbons in the heated vapor stream is less than a second mole fraction of C 3 hydrocarbons in the bottom effluent stream, and wherein both the first mole fraction and the second mole fraction are greater than 0.00 mole fraction;

expanding, by an expander, the bottom effluent stream to produce an expanded bottom effluent stream, wherein the expanded bottom effluent stream comprises a second portion of the carbon dioxide and C 3 -C 8 hydrocarbons;

receiving, by an additional separator, the expanded bottom effluent stream from the expander; and

producing, by the additional separator, an acid gas stream and a sweetened hydrocarbon stream, wherein the acid gas stream comprises the second portion of the carbon dioxide, and wherein the sweetened hydrocarbon stream comprises the C 3 -C 8 hydrocarbons.

6. The method of claim 5 , wherein the dehydrator comprises a molecular sieve.

7. The method of claim 5 , wherein the multi-stage separator comprises a distillation column.

8. The method of claim 5 , wherein the carbon dioxide recycle stream, the heated vapor stream, and the bottom effluent stream are not processed by membranes.

9. The method of claim 5 , wherein the carbon dioxide recycle stream, the heated vapor stream, and the bottom effluent stream are not subjected to carbon dioxide recovery solvents.

10. The method of claim 5 , wherein the feed stream is received from a subterranean hydrocarbon formation.

11. The method of claim 5 , wherein the heated vapor stream is injected into a subterranean hydrocarbon formation.

12. The method of claim 5 , wherein the cooled carbon dioxide recycle stream comprises vapor.

13. The method of claim 5 , wherein the bottom effluent stream comprises liquid.

14. A method for use in an enhanced oil recovery (EOR) process, the method comprising:

cooling a carbon dioxide recycle stream to produce a cooled carbon dioxide recycle stream, wherein the cooled carbon dioxide recycle stream comprises carbon dioxide, C 1 -C 8 hydrocarbons, and is dehydrated;

separating the cooled carbon dioxide recycle stream into a top effluent stream and a bottom effluent stream;

separating the top effluent stream into a vapor stream and a liquid stream;

heating the vapor stream to produce a heated vapor stream, wherein the heated vapor stream comprises a first portion of the carbon dioxide and C 1 -C 4 hydrocarbons, wherein the first portion of the carbon dioxide comprises greater than 0.50 mole fraction of the heated vapor stream, wherein a first mole fraction of C 3 hydrocarbons in the heated vapor stream is less than a second mole fraction of C 3 hydrocarbons in the bottom effluent stream, and wherein both the first mole fraction and the second mole fraction are greater than 0.00 mole fraction;

expanding the bottom effluent stream to produce an expanded bottom effluent stream, wherein the expanded bottom effluent stream comprises a second portion of the carbon dioxide and C 3 -C 8 hydrocarbons; and

separating the expanded bottom effluent stream to produce an acid gas stream and a sweetened hydrocarbon stream, wherein the acid gas stream comprises the second portion of the carbon dioxide, and wherein the sweetened hydrocarbon stream comprises the C 3 -C 8 hydrocarbons.

15. The method of claim 14 , further comprising:

receiving a feed stream; and

dehydrating the feed stream to produce the carbon dioxide recycle stream.

16. The method of claim 14 , wherein the carbon dioxide recycle stream, the heated vapor stream, and the bottom effluent stream are not processed by membranes.

17. The method of claim 14 , wherein the carbon dioxide recycle stream, the heated vapor stream, and the bottom effluent stream are not subjected to carbon dioxide recovery solvents.

18. The set of process equipment of claim 1 , wherein the acid gas stream comprises H 2 S.

19. The method of claim 5 , wherein the acid gas stream comprises H 2 S.

20. The method of claim 14 , the acid gas stream comprises H 2 S.

Assignments (2)
NUNC PRO TUNC ASSIGNMENT Recorded Jun 28, 2023
From: PILOT ENERGY SOLUTIONS, LLC
To: PILOT INTELLECTUAL PROPERTY, LLC
Reel/Frame 064089/0153 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Feb 20, 2020
From: PRIM, ERIC
To: PILOT ENERGY SOLUTIONS, LLC
Reel/Frame 051870/0119 →
Continuity (7)
Continuation 15666339 · Aug 1, 2017
Continuation 13946773 · Jul 19, 2013
Continuation In Part 12122336 · May 16, 2008
Provisional Application 60938726 · May 18, 2007
Provisional Application 61730696 · Nov 28, 2012
Provisional Application 61823047 · May 14, 2013
Related Publication 20200141638A1 · May 7, 2020
Cited By (2)
US 12,234,421 US 12,474,115