Chiral perovskite quantum dots for circularly polarized QLEDs and method of making the same
A light emitting device includes a first electrode, a second electrode, and an emissive layer between the first and second electrodes. The emissive layer comprises quantum dots that are capable of producing circularly polarized luminescence. The quantum dots are chiral structured perovskite quantum dots, each comprising a core having a chiral crystal structure.
1. A light emitting device comprising:
a first electrode;
a second electrode; and
an emissive layer between the first and second electrodes, wherein:
the emissive layer comprises quantum dots that are capable of producing circularly polarized luminescence, and
the quantum dots comprise chiral structured perovskite quantum dots.
2. The light emitting device of claim 1 , wherein the quantum dots each comprises a core having a chiral crystal structure.
3. The light emitting device of claim 1 , wherein the quantum dots comprise only right-handed circularly polarized perovskite quantum dot enantiomers.
4. The light emitting device of claim 1 , wherein the quantum dots comprise only left-handed circularly polarized perovskite quantum dot enantiomers.
5. The light emitting device of claim 1 , wherein the quantum dots comprise a racemic mix of both right and left-handed circularly polarized quantum dot materials.
6. The light emitting device of claim 1 , wherein the quantum dots comprise right-handed circularly polarized perovskite quantum dots dispersed in a matrix of cross-linked charge transport molecules.
7. The light emitting device of claim 1 , wherein the quantum dots comprise left-handed circularly polarized perovskite quantum dots dispersed in a matrix of cross-linked charge transport molecules.
8. The light emitting device of claim 1 , wherein the quantum dots comprise a racemic mixture of left and right-handed circularly polarized perovskite quantum dots dispersed in a matrix of cross-linked charge transport molecules.
9. The light emitting device of claim 1 , wherein the quantum dots each comprises a chiral quantum dot core formed of octahedral metal halide lattices interspersed with one or more organic chiral ligands.
10. The light emitting device of claim 1 , further comprising a circular polarizer disposed over the emissive layer.
11. The light emitting device of claim 10 , wherein the circular polarizer comprises a linear polarizer and a quarter wave (λ/4) retarder over the emissive layer.
12. The light emitting device of claim 2 , further comprising a window and a circular polarizer between the window and the emissive layer, wherein the chiral crystal structure is configured so that light emitted from the emissive layer toward the window has a circular polarization that is substantially transmitted through the circular polarizer.
13. The light emitting device of claim 2 , further comprising a circular polarizer disposed over the emissive layer, wherein the chiral crystal structure is configured so that light emitted from the emissive layer toward the first electrode has a first circular polarization such that the light after reflection by the first electrode has a second circular polarization that is not substantially transmitted through the circular polarizer.
14. A quantum dot comprising:
a core; and
one or more shell layers around the core, wherein:
the core comprises a chiral crystal structure for producing circularly polarized luminescence, and
the quantum dot comprises a chiral structured perovskite quantum dot.
15. The quantum dot of claim 14 , wherein the chiral crystal structure of the quantum dot comprises only right-handed chiral structures to produce only right handed circularly polarized light.
16. The quantum dot of claim 14 , wherein the chiral structured perovskite quantum dot comprises only left-handed chiral structures to produce only left handed circularly polarized light.
17. The quantum dot of claim 14 , wherein the chiral crystal structure of the quantum dot comprises a racemic mix of both right and left-handed chiral structures to produce a mix of left and right handed circularly polarized light.
18. A quantum dot comprising:
a core; and
one or more shell layers around the core, wherein:
the core comprises a chiral crystal structure for producing circularly polarized luminescence, and
the core is formed of octahedral metal halide lattices interspersed with organic chiral ligands.