Method for forming sulfur-containing electrode using salt additive
The present disclosure relates to sulfur-containing electrodes and methods for forming the same. For example, the method may include disposing an electroactive material on or near a current collector to form an electroactive material layer having a first porosity and applying pressure and heat to the electroactive material layer so that the electroactive material layer has a second porosity. The first porosity is greater than the second porosity. The electroactive material may include a plurality of electroactive material particles and one or more salt additives. The method may further include contacting the electroactive material layer and an electrolyte such that the electrolyte dissolves the plurality of one or more salt particles so that the electroactive material layer has a third porosity. The third porosity may be greater than the second porosity and less than the first porosity.
1. A method of preparing an electrode for use in an electrochemical cell that cycles lithium ions, wherein the method comprises:
disposing an electroactive material admixture on or near one or more surfaces of a current collector, wherein the electroactive material admixture is a slurry comprising a plurality of electroactive material particles, a plurality of salt additive particles, and a carrier;
drying the electroactive material admixture so as to remove the carrier and form an electroactive material layer having a first porosity;
applying pressure to the electroactive material layer so that the electroactive material layer has a second porosity, wherein the first porosity is greater than the second porosity; and
contacting the electroactive material layer with an electrolyte such that the electrolyte dissolves the plurality of salt additive particles, so that the electroactive material layer has a third porosity that is greater than the second porosity and less than the first porosity, wherein the electroactive material layer and the current collector define the electrode.
2. The method of claim 1 , wherein the plurality of salt additive particles are selected from the group consisting of: lithium hexafluorophosphate (LiPF 6 ), lithium hexafluoroarsenate (LiAsF 6 ), lithium fluorosulfonylimide (LiN(FSO 2 ) 2 ) (LiFSI), lithium bis(trifluoromethanesulfonimide) (LiN(CF 3 SO 2 ) 2 ), lithium triflate (LiCF 3 SO 3 ), lithium perchlorate (LiClO 4 ), lithium tetrafluoroborate (LiBF 4 ), lithium nitrate (LiNO 3 ), lithium iodide (LiI), lithium bromide (LiBr), lithium bis(trifluoromethanesulfonimide) (LiTFSI) (LiN(CF 3 SO 2 ) 2 ), and combinations thereof.
3. The method of claim 1 , wherein the electroactive material admixture comprises greater than or equal to about 70 wt. % to less than or equal to about 90 wt. % of the plurality of electroactive material particles based on a total weight of the electroactive material admixture and greater than or equal to about 10 wt. % to less than or equal to about 30 wt. % of the plurality of salt additive particles based on a total weight of the electroactive material admixture.
4. The method of claim 1 , wherein the first porosity is greater than or equal to about 60 vol. % to less than or equal to about 80 vol. % of the electroactive material layer and the second porosity is greater than or equal to about 30 vol. % to less than or equal to about 65 vol. % of the electroactive material layer.
5. The method of claim 1 , wherein the third porosity is greater than or equal to about 40 vol. % to less than or equal to about 70 vol. % of the electroactive material layer.
6. The method of claim 1 , wherein the electrolyte comprises one or more lithium salts that dissolve in one or more solvents selected from 1,2-dimethoxyethane (DME), 12-diethoxyethane, ethoxymethoxyethane, tetrahydrofuran, 2-methyltetrahydrofuran, 1,3-dioxolane (DOL), and sulfolane.
7. The method of claim 1 , wherein the applying pressure further includes applying heat to the electroactive material layer,
wherein the electroactive material layer is heated to greater than or equal to about 40° C. to less than or equal to about 100° C.
8. The method of claim 1 , wherein each electroactive material particle of the plurality of electroactive material particles comprises one or more of S, S 8 , Li 2 S 8 , Li 2 S 6 , Li 2 S 4 , Li 2 S 2 , and Li 2 S.
9. A method of preparing a sulfur-containing electrode for use in an electrochemical cell that cycles lithium ions, wherein the method comprises:
disposing a slurry comprising a plurality of sulfur-based electroactive material particles a plurality of salt particles, and a carrier on or near one or more surfaces of a current collector;
drying the slurring so as to remove a carrier and form an electroactive material layer having a first porosity; and
calendaring the electroactive material layer, so that the electroactive material layer has a second porosity, wherein the first porosity is greater than the second porosity; and
contacting the electroactive material layer with an electrolyte such that the electrolyte dissolves the plurality of salt additive particles, so that the electroactive material layer has a third porosity that is greater than the second porosity and less than the first porosity, wherein the electroactive material layer and the current collector define the sulfur-containing electrode.
10. The method of claim 9 , wherein the electroactive material layer comprises greater than or equal to about 70 wt. % to less than or equal to about 90 wt. % of the plurality of sulfur-based electroactive material particles based on a total weight of the electroactive material layer and greater than or equal to about 10 wt. % to less than or equal to about 30 wt. % of the plurality of salt particles based on a total weight of the electroactive material layer; and
wherein the plurality of salt particles are selected from the group consisting of: lithium hexafluorophosphate (LiPF 6 ), lithium hexafluoroarsenate (LiAsF 6 ), lithium fluorosulfonylimide (LiN(FSO 2 ) 2 ) (LiFSI), lithium bis(trifluoromethanesulfonimide) (LiN(CF 3 SO 2 ) 2 ), lithium triflate (LiCF 3 SO 3 ), lithium perchlorate (LiClO 4 ), lithium tetrafluoroborate (LiBF 4 ), lithium nitrate (LiNO 3 ), lithium iodide (LiI), lithium bromide (LiBr), lithium bis(trifluoromethanesulfonimide) (LiTFSI) (LiN(CF 3 SO 2 ) 2 ), and combinations thereof.
11. The method of claim 9 , wherein the first porosity is greater than or equal to about 60 vol. % to less than or equal to about 80 vol. % of the electroactive material layer and the second porosity is greater than or equal to about 30 vol. % to less than or equal to about 65 vol. % of the electroactive material layer.
12. The method of claim 9 , wherein the third porosity is greater than or equal to about 40 vol. % to less than or equal to about 70 vol. % of the electroactive material layer.
13. The method of claim 9 , wherein the electrolyte comprises one or more lithium salts that dissolve in one or more solvents selected from 1,2-dimethoxyethane (DME), 1-2-diethoxyethane, ethoxymethoxyethane, tetrahydrofuran, 2-methyltetrahydrofuran, 1,3-dioxolane (DOL), and sulfolane.
14. A method of preparing a sulfur-containing electrode configured to receive an electrolyte, wherein the method comprises:
disposing an electroactive material admixture on or near one or more surfaces of a current collector, wherein the electroactive material admixture comprises a plurality of electroactive material particles and a plurality of salt additive particles, and a carrier; and
drying the electroactive material admixture so as to form an electroactive material layer having a first porosity;
calendaring the electroactive material layer, so that the electroactive material layer has a second porosity, wherein the first porosity is greater than the second porosity and the electroactive material layer and the current collector define the sulfur-containing electrode configured to receive the electrolyte,
wherein, when the electrolyte is received, the electrolyte dissolves the plurality of salt particles so that the electroactive material layer has a third porosity, wherein the third porosity is greater than the second porosity and less than the first porosity.
15. The method of claim 14 , wherein the first porosity is greater than or equal to about 60 vol. % to less than or equal to about 80 vol. % of the electroactive material layer;
the second porosity is greater than or equal to about 30 vol. % to less than or equal to about 65 vol. % of the electroactive material layer; and
the third porosity is greater than or equal to about 40 vol. % to less than or equal to about 70 vol. % of the electroactive material layer.
16. The method of claim 14 , wherein the electroactive material admixture comprises greater than or equal to about 70 wt. % to less than or equal to about 90 wt. % of the plurality of electroactive material particles based on a total weight of the electroactive material admixture and greater than or equal to about 10 wt. % to less than or equal to about 30 wt. % of the plurality of salt additive particles based on a total weight of the electroactive material admixture.
17. The method of claim 14 , wherein the plurality of salt particles are selected from the group consisting of: lithium hexafluorophosphate (LiPF 6 ), lithium hexafluoroarsenate (LiAsF 6 ), lithium fluorosulfonylimide (LiN(FSO 2 ) 2 ) (LiFSII), lithium bis(trifluoromethanesulfonimide) (LiN(CF 3 SO 2 ) 2 ), lithium triflate (LiCF 3 SO 3 ), lithium perchlorate (LiClO 4 ), lithium tetrafluoroborate (LiBF 4 ), lithium nitrate (LiNO 3 ), lithium iodide (LiI), lithium bromide (LiBr), lithium bis(trifluoromethanesulfonimide) (LiTFSI) (LiN(CF 3 SO 2 ) 2 ), and combinations thereof; and
the electrolyte comprises one or more lithium salts that dissolve in one or more solvents selected from 1,2-dimethoxyethane (DME), 1-2-diethoxyethane, ethoxymethoxyethane, tetrahydrofuran, 2-methyltetrahydrofuran, 1,3-dioxolane (DOL), and sulfolane.