IP Library › Granted Patent US 11,807,588
Granted Patent B2
US 11,807,588 · App. 16/746,011 · Granted Nov 7, 2023

Hydrophobic coatings to improve the physical quality parameters of fertilizers

Inventors: Michael John McLaughlin (Montacute, AU); Jozefien Louisa Elvire Degryse (Parkside, AU); Roslyn Jane Baird (Aberfoyle Park, AU); Rodrigo Coqui da Silva (Redwood Park, AU); Jerri Light (Regina, CA)
Assignee: The Mosaic Company
C05G5/38C05B1/02C05B3/00C05B7/00C05C5/00C05C9/005C05D1/00C05D9/00C05D9/02C05G3/20C05G3/30C05G3/44C05G5/30
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Quick Facts
Patent No.
US 11,807,588
App. No.
16/746,011
Granted
Nov 7, 2023
Kind
B2
Abstract

A fertilizer composition including a base fertilizer granule with a hydrophobic or super-hydrophobic coating that reduces fertilizer caking and dust formation. The coating can include a roughening component, which creates micron-scale surface roughness, and a hydrophobic coating. Together, the components of the coating act to physically protect water soluble fertilizers granules from the ingress of moisture and from caking, and increase the resistance of the granules to abrasion.

Claims (30)

1. A fertilizer product comprising a plurality of granules coated for moisture control, each of the coated granules comprising:

a base fertilizer granule; and

a moisture control coating applied to the base fertilizer granule, the coating including a hydrophobic material component and a roughening component,

wherein the roughening component comprises particulates having a particle size in a range of from about 10 μm to about 150 μm so as to form a micron-scaled surface roughness on an outermost surface of the coated granules,

wherein the hydrophobic material component comprises an oil selected from a group consisting of a mineral white oil, petroleum oil, canola oil, sunflower oil, soy oil, castor oil, linseed oil, olive oil, modified vegetable oils, and combinations thereof, and wherein the hydrophobic material is present in an amount of from about 0.5 to about 2.0 weight percent of the entire fertilizer granule.

2. The fertilizer product of claim 1 , wherein the roughening component is present in an amount of from about 0.01 wt % to about 10 wt % based on a total weight of the granule.

3. The fertilizer product of claim 2 , wherein the roughening component is present in an amount of from about 0.1 wt % to about 1.0 wt % percent of the total weight of the granule.

4. The fertilizer product of claim 1 , wherein the roughening component has a solubility lower than the base fertilizer granule.

5. The fertilizer product of claim 1 , wherein the roughening component is selected from a group consisting of silicates, sand, phosphate rock, calcium carbonate, gypsum, zinc, manganese, iron, copper, molybdenum, boron, chloride, cobalt, sodium, sulfur in a sulfate form, elemental sulfur, zinc stearate, sodium stearate, stearic acid, potash dust, and combinations thereof.

6. The fertilizer product of claim 1 , wherein the base fertilizer granule is selected from the group consisting of nitrates, ureas, muriate of potash, sulfate of potash, monoammonium phosphate (MAP), diammonium phosphate (DAP), single superphosphate, triple superphosphate, potassium phosphates, calcium phosphates, and combinations thereof.

7. The fertilizer product of claim 1 , wherein the moisture control coating comprises sodium stearate and/or zinc stearate as the roughening component, and wherein the hydrophobic material comprises petroleum oil with amine or candelilla wax.

8. A method of providing a moisture control treatment to fertilizer granules, the method comprising:

providing a plurality of fertilizer granules; and

coating the fertilizer granules with a moisture control treatment material comprising a hydrophobic material and a roughening component, wherein the roughening component comprises particulates having a particle size in a range of from about 10 μm to about 150 μm so as to form a micron-scaled surface roughness on an outermost surface of the coated granules, wherein the hydrophobic material component comprises an oil selected from a group consisting of a mineral white oil, petroleum oil, canola oil, sunflower oil, soy oil, castor oil, linseed oil, olive oil, modified vegetable oils, and combinations thereof, and wherein the hydrophobic material is present in an amount of from about 0.5 to about 2.0 weight percent of the entire fertilizer granule.

9. The method of claim 8 , wherein the roughening component is present in an amount of from about 0.01 wt % to about 10 wt % based on a total weight of the granule.

10. The method of claim 9 , wherein the roughening component is present in an amount of from about 0.1 wt % to about 1.0 wt % percent of the total weight of the granule.

11. The method of claim 8 , wherein coating the fertilizer granules comprises:

coating the fertilizer granules with the roughening component; and

subsequently coating the fertilizer granules with the roughening component applied thereto with the hydrophobic material.

12. The method of claim 8 , wherein coating the fertilizer granules comprises:

combining the roughening component and the hydrophobic material; and

subsequently coating the fertilizer granule with the combined roughening component and hydrophobic material.

13. The method of claim 8 , wherein the roughening component is selected from a group consisting of silicates, sand, phosphate rock, calcium carbonate, gypsum, zinc, manganese, iron, copper, molybdenum, boron, chloride, cobalt, sodium, sulfur in a sulfate form, elemental sulfur, zinc stearate, sodium stearate, stearic acid, potash dust, and combinations thereof.

14. The method of claim 8 , wherein the base fertilizer granule is selected from the group consisting of nitrates, ureas, muriate of potash, sulfate of potash, monoammonium phosphate (MAP), diammonium phosphate (DAP), single superphosphate, triple superphosphate, potassium phosphates, calcium phosphates, and combinations thereof.

15. The method of claim 8 , wherein the moisture control coating comprises zinc stearate and/or sodium stearate as the roughening component, and wherein the hydrophobic material comprises petroleum oil with amine or candelilla wax.

16. A fertilizer product comprising a plurality of granules coated for moisture control, each of the coated granules comprising:

a base fertilizer granule; and

a moisture control coating applied to the base fertilizer granule, the coating including a hydrophobic material component and a roughening component, wherein the hydrophobic material is present in an amount of from about 0.5 to about 2.0 weight percent of the entire fertilizer granule,

wherein the roughening component comprises particulates having a particle size in a range of from about 10 μm to about 150 μm so as to form a micron-scaled surface roughness on an outermost surface of the coated granules, and

wherein the roughening component is present in an amount of from about 0.01 to about 10 weight percent of the fertilizer granules.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Feb 11, 2020
From: MCLAUGHLIN, MICHAEL JOHN; DEGRYSE, JOZEFIEN LOUISA ELVIRE; BAIRD, ROSLYN JANE; DA SILVA, RODRIGO COQUI; LIGHT, JERRI
To: THE MOSAIC COMPANY
Reel/Frame 051787/0969 →
Continuity (2)
Provisional Application 62793582 · Jan 17, 2019
Related Publication 20200231516A1 · Jul 23, 2020
Cited By (1)
US 12,264,114