Carbon based materials as solid-state ligands for metal nanoparticle catalysts
High activity metal nanoparticle catalysts, such as Pd or Pt nanoparticle catalyst, are provided. Adsorption of metal precursors such as Pd or Pt precursors onto carbon based materials such as graphene followed by solventless (or low-solvent) microwave irradiation at ambient conditions results in the formation of the catalysts in which metal nanoparticles are supported on i) the surface of the carbon based materials and ii) in/on/within defects/holes in the carbon based materials.
1. A method of making a Pd catalyst, comprising
i) determining an optimum pH for SEA of a Pd precursor to a graphene-based material, a graphitic material or a non-graphitic material that is activated charcoal or carbon black;
ii) adjusting the pH of an aqueous solution to the optimum pH;
iii) in the aqueous solution, depositing the Pd precursor on the graphene-based material, the graphitic material or the non-graphitic material that is activated charcoal or carbon black by loading the Pd precursor via strong electrostatic adsorption (SEA); and
iv) irradiating carbon-based material comprising deposited Pd precursor with radiant energy sufficient to attach Pd from the Pd precursor to the graphene-based material, the graphitic material or the non-graphitic material that is activated charcoal or carbon black, thereby forming a Pd catalyst.
2. The method of claim 1 , wherein the graphene-based material comprises one or more of GP1-5, graphene oxide (GO), reduced graphene oxide (rGO), graphene nanoplatelets (GN), graphene nanoplatelet aggregates, graphene nanotubes, monolayer graphene, few-layer graphene (FLG) and multilayer graphene (MLG).
3. The method of claim 1 , wherein, prior to the step of irradiating, the method further comprises the steps of: separating graphene-based material loaded with metal precursor from the aqueous solution; and drying the graphene-based material loaded with metal precursor.
4. The method of claim 1 , wherein the radiant energy is microwave energy.
5. The method of claim 1 , wherein the graphitic material is a carbon allotrope selected from the group consisting of single-walled carbon nanotubes, multi-wall carbon nanotubes, carbon nanofibers, carbon nanoribbons and fullerenes.
6. The method of claim 1 , wherein the Pd precursor is an anionic or a cationic salt of Pd.
7. The method of claim 6 wherein the anionic or a cationic salt of Pd is dihydrogen tetrachloropalladate (II) (H 2 PdCl 4 ) or tetraamminepalladium (II) chloride monohydrate (Pd(NH 3 ) 4 Cl 2 ).
8. The method of claim 7 , wherein
the graphene-based material is GP1-5, GO, rGO or GN; and
the optimum pH for SEA is 3.1 for GP1-5, 3.6 for GO, 2.9 for rGO and 3.1 for GN when the Pd precursor is the anionic salt of Pd; or
the optimum pH for SEA is 10.8 for
GP1-5, 9.8 for GO, 11.2 for rGO and 10.7 for GN when the Pd precursor is the cationic salt of Pd.
9. The method of claim 1 , wherein the step of irradiating is performed at a fixed temperature or at a fixed power level.
10. The method of claim 1 wherein the step of depositing achieves a loading of 0.1 to 1.5 μmol Pd/m 2 of the graphene-based material.
11. A Pd catalyst consisting of Pd nanoparticles of 10 nm or less in size immobilized on a graphene-based material, wherein the graphene-based material is made from a material selected from the group consisting of graphene powder, graphene oxide (GO), reduced graphene oxide (rGO), graphene nanoplatelets (GN), graphene nanoplatelet aggregates, monolayer graphene, few-layer graphene (FLG) or multilayer graphene (MLG), carbon nanotubes, carbon fibers, and carbon nanoribbons, wherein the Pd nanoparticles are 5 nm or less in size.
12. The Pd catalyst of claim 11 wherein the Pd catalyst has a Pd weight % loading of 1-15.