IP Library Granted Patent US 11,325,877
Granted Patent B2
US 11,325,877 · App. 16/765,647 · Granted May 10, 2022

Processes for the production of ethylene oxide and ethylene glycol

Inventors: Ram Paul Bajaj (Bangalore, IN); Peter Molenaar (Amsterdam, NL)
Assignee: SHELL USA, INC.
C07C29/78C07C29/74C07C29/76C07C29/80C07C31/202
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Quick Facts
Patent No.
US 11,325,877
App. No.
16/765,647
Granted
May 10, 2022
Kind
B2
Abstract

A process for the recovery of ethylene glycol from an aqueous stream comprising ethylene glycol is disclosed. The process comprises (a) subjecting an aqueous stream 5 comprising ethylene glycol to an evaporation step in a multiple-effect evaporator to obtain a concentrated stream comprising ethylene glycol; (b) subjecting said concentrated stream comprising ethylene glycol to a first dehydration step in a first dehydrator 10 operating at an overhead pressure in the range of 0 barg (bar gauge) to 4 barg (bar gauge) to obtain a partially dehydrated ethylene glycol stream, and (c) subjecting said partially dehydrated ethylene glycol stream to a second dehydration step in a second dehydrator operating under 15 vacuum to obtain a dehydrated ethylene glycol stream.

Claims (16)

1. A process for the recovery of ethylene glycol from an aqueous stream comprising ethylene glycol, said process comprising

(a) subjecting said aqueous stream comprising ethylene glycol to an evaporation step in a multiple-effect evaporator to obtain a concentrated stream comprising ethylene glycol and a stream of collected condensates;

(b) subjecting said concentrated stream comprising ethylene glycol to a first dehydration step in a first dehydrator operating at an overhead pressure in the range of 0 barg (bar gauge) to 4 barg (bar gauge) to obtain a partially dehydrated ethylene glycol stream and a low pressure steam stream at a pressure in the range of 0 barg to 4 barg, and

(c) subjecting said partially dehydrated ethylene glycol stream to a second dehydration step in a second dehydrator operating under vacuum to obtain a dehydrated ethylene glycol stream,

wherein the collected condensates of the multiple-effect evaporator are flashed to produce flash steam and flash condensate, and wherein at least a portion of the flash condensate is recycled to an ethylene glycol reactor.

2. The process according to claim 1 , wherein said aqueous stream comprising ethylene glycol is produced by a process comprising manufacturing of ethylene oxide in an ethylene oxide section and hydrolysis of ethylene oxide in an ethylene glycol section, and wherein the ethylene oxide section or the ethylene glycol section comprise one or more low-pressure steam consumers and using at least a portion of the low pressure steam produced in the first dehydrator to drive the one or more low-pressure steam consumers in the ethylene oxide section or the ethylene glycol section.

3. The process according to claim 2 , wherein said low-pressure steam consumers comprise one or more chilling units.

4. The process according to claim 1 , wherein the multiple-effect evaporation step is performed in 2 to 6 stages.

5. The process according to claim 1 , wherein the first dehydrator is operated at a pressure in the range of 0.3-3 barg.

6. The process according to claim 1 , wherein the vaporous overhead from the last evaporator vessel in the multiple-effect evaporator is used as process steam, and wherein at least a portion of said process steam is used to provide heat to the first dehydrator.

7. The process according to claim 2 , wherein at least a portion of the condensate of the one or more low-pressure steam consumers is used to supply reflux to the first dehydrator.

8. The process according to claim 2 , wherein the ethylene oxide section comprises an ethylene oxide (EO) stripper, wherein said ethylene oxide stripper contains a first and an additional, second reboiler, and wherein heat is supplied to said second ethylene oxide stripper reboiler by low-pressure steam generated in a monoethylene glycol (MEG) purification column overhead condenser.

9. The process according to claim 2 , wherein the ethylene oxide section comprises an ethylene oxide stripper to which fat absorbent is supplied, and wherein one or more external process stream feeds are provided to the ethylene oxide stripper at a location above the fat absorbent feed.

10. The process according to claim 9 , wherein at least a portion of the fat absorbent stream from an ethylene oxide absorber bottom is used as the external process stream feed.

11. The process according to claim 9 , wherein the ethylene oxide section comprises a residual ethylene oxide absorber, wherein at least a portion of the fat absorbent stream from the residual absorber bottom is used as the external process stream feed.

12. The process according to claim 2 , wherein the ethylene oxide section comprises a residual ethylene oxide absorber, wherein at least a portion of the fat absorbent stream from an ethylene oxide absorber bottom is provided above the point where a feed comprising ethylene oxide is provided to said residual ethylene oxide absorber.

Assignments (2)
CHANGE OF NAME Recorded Mar 30, 2022
From: SHELL OIL COMPANY
To: SHELL USA, INC.
Reel/Frame 059554/0473 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Nov 12, 2021
From: BAJAJ, RAM PAUL; MOLENAAR, PETER
To: SHELL OIL COMPANY
Reel/Frame 058096/0983 →
Priority Claims (1)
EP 17203352 · Nov 23, 2017 · regional
Continuity (1)
Related Publication 20200299215A1 · Sep 24, 2020