Method for partially regenerating methanol to olefin catalyst and methanol to olefin process
The present application discloses a method for partially regenerating a methanol to olefin catalyst, comprising: placing a deactivated methanol to olefin catalyst in a regenerator to carry out a partial regeneration reaction to obtain a regenerated catalyst; at least a portion of the regenerated catalyst has a coke amount of more than 1%. The present application discloses a methanol to olefin process, the methanol to olefin reaction is carried out in a fluidized bed with the use of a methanol to olefin catalyst, wherein at least a portion of the regenerated catalyst has a coke amount of more than 1%.
1. A methanol to olefin process comprising:
placing a deactivated methanol to olefin catalyst in a regenerator;
partially regenerating the deactivated methanol to olefin catalyst by gasifying coke deposited on the deactivated methanol to olefin catalyst with regeneration gas which consists of steam, to obtain a regenerated catalyst, wherein at least a portion of the regenerated catalyst has a coke amount in a range from 3.89 wt % to 6 wt % and wherein the regeneration gas does not include oxygen; and
carrying out a methanol to olefin reaction in a fluidized bed reactor comprising the regenerated catalyst.
2. The methanol to olefin process according to claim 1 , wherein the partial regeneration reaction is carried out at a temperature in a range of 710° C. to 750° C.
3. The methanol to olefin process according to claim 1 , wherein a contact time between the steam and the deactivated methanol to olefin catalyst is in a range of 10 min to 40 min.
4. The methanol to olefin process according to claim 3 , wherein the steam is introduced into the regenerator with a space velocity in a range of 4 h −1 to 8 h −1 .
5. The methanol to olefin process according to claim 1 , wherein the partial regeneration reaction is carried out at a temperature in a range of 600° C. to 750° C.
6. The methanol to olefin process according to claim 1 , wherein the deactivated methanol to olefin catalyst has a coke amount in a range of 7 wt % to 12 wt %.
7. The methanol to olefin process according to claim 1 , wherein an inert gas is also introduced into the regenerator and the inert gas is at least one selected from nitrogen, helium, argon, and neon.
8. The methanol to olefin process according to claim 1 further comprising:
carrying out a methanol to olefin reaction in a fluidized bed reactor comprising a methanol to olefin catalyst which contains a silicoaluminophosphate molecular sieve, wherein the reaction produces the deactivated methanol to olefin catalyst, and
recycling the regenerated catalyst to the fluidized bed reactor.