Negative electrode for lithium metal battery and lithium metal battery comprising same
The present invention provides a negative electrode for a lithium metal battery and a lithium metal battery comprising the same, the negative electrode comprising: a first negative electrode including a lithium metal negative electrode; and a second negative electrode which is disposed on the first negative electrode and includes a coating layer including a carbon-based material. By using the negative electrode for a lithium metal battery, a lithium metal battery can have an improved charge and discharge efficiency and life time.
1. A negative electrode for a lithium metal battery comprising:
a first negative electrode including a lithium metal negative electrode; and
a second negative electrode disposed on the first negative electrode and including a coating layer including a carbon-based material, wherein the carbon-based material includes spherical graphene balls including graphene and a silicon-based material.
2. The negative electrode of claim 1 , wherein the silicon-based material is SiO x , where 1<x<3.
3. The negative electrode of claim 1 , wherein the graphene balls include the silicon-based material in an amount of 50% to 80% by weight based on a total weight of the graphene balls.
4. The negative electrode of claim 1 , wherein the graphene balls have a specific surface area of 80 m 2 /g to 120 m 2 /g.
5. The negative electrode of claim 1 , wherein the graphene balls have an electrical conductivity of 10 S/cm to 50 S/cm at room temperature (25° C.).
6. The negative electrode of claim 1 , wherein the coating layer further comprises at least one selected from a polymer binder and a lithium salt.
7. The negative electrode of claim 6 , wherein the polymer binder includes at least one selected from the group consisting of a vinylidene fluoride/hexafluoropropylene copolymer, polyvinylidene fluoride (PVDF), polyacrylonitrile, polymethylmethacrylate, polytetrafluoroethylene, and a styrene butadiene rubber-based copolymer.
8. The negative electrode of claim 6 , wherein the lithium salt includes at least one selected from the group consisting of LiDFOB, LiFSI, LiSCN, LiN(CN) 2 , LiClO 4 , LiBF 4 , LiAsF 6 , LiPF 6 , LiCF 3 SO 3 , LiC(CF 3 SO 2 ) 3 , LiN(SO 2 C 2 F 5 ) 2 , LiN(SO 2 CF 3 ) 2 , LiN(SO 2 F) 2 , LiSbF 6 , LiPF 3 (CF 2 CF 3 ) 3 , LiPF 3 (CF 3 ) 3 , and LiB(C 2 O 4 ) 2 .
9. The negative electrode of claim 1 , wherein the coating layer has a thickness in a range of 2 μm to 100 μm.
10. The negative electrode of claim 1 , further comprising a solid electrolyte interface (SEI) film formed on the second negative electrode.
11. A lithium metal battery comprising:
a positive electrode;
the negative electrode of claim 1 ; and
an electrolyte between the positive electrode and the negative electrode.
12. The lithium metal battery of claim 11 , wherein the positive electrode includes a positive electrode active material represented by Chemical Formula 1:
LiCo 1−x M x O 2 <Chemical Formula 1>
wherein in the above formula,
M is at least one selected from the group consisting of Ni, Mn, Al, Cu, Fe, Mg, Cr, Zn, B, and Ga, and
0.5<x<1.
13. The lithium metal battery of claim 11 , wherein the electrolyte is a liquid electrolyte including a lithium salt and an organic solvent.
14. The lithium metal battery of claim 13 , wherein the organic solvent is a carbonate-based compound or an ether-based compound.