Article including a substrate, a phosphate binding layer and a fluoroplyether layer
View Patent ↗An article including a metal substrate, a phosphate binding layer, and a fluoropolyether layer. Also disclosed is a process for producing the article which includes (i) treating a surface of the metal substrate with a phosphoric acid derivative to form the phosphate binding layer on the surface of the metal substrate, and (ii) treating a surface of the phosphate binding layer with a fluoropolyether compound having a fluoropolyether group and a carbon-carbon double bond to form the fluoropolyether layer on the surface of the phosphate binding layer.
1. An article which comprises a metal substrate, a phosphate binding layer, and a fluoropolyether layer,
wherein
the fluoropolyether layer is formed of a fluoropolyether compound having a fluoropolyether group and a carbon-carbon double bond,
the fluoropolyether compound having a fluoropolyether group and a carbon-carbon double bond is a compound obtained by reacting:
(A) a triisocyanate prepared by trimerizing a diisocyanate, with
(B) a combination of at least two active hydrogen-containing compounds wherein the component (B) comprises:
(B-1) a fluoropolyether having at least one active hydrogen, and
(B-2) a monomer having an active hydrogen atom and a carbon-carbon double bond,
the phosphate binding layer is formed of a phosphoric acid derivative,
the phosphoric acid derivative is a compound of the formula:
wherein:
R 11 is each independently H or a C 1-3 alkyl group,
R 13 is each independently a divalent organic group,
the metal substrate is a SUS substrate.
2. A process for producing the article as claimed in claim 1 , which article comprises a metal substrate, a phosphate binding layer, and a fluoropolyether layer, the process comprising:
(i) treating a surface of the metal substrate with a phosphoric acid derivative to form the phosphate binding layer on the surface of the metal substrate, and
(ii) treating a surface of the phosphate binding layer with a fluoropolyether compound having a fluoropolyether group and a carbon-carbon double bond to form the fluoropolyether layer on the surface of the phosphate binding layer.
3. The process for producing as claimed in claim 2 , the process further comprising irradiating the phosphate binding layer and the fluoropolyether layer with ultraviolet light.