IP Library Granted Patent US 11,655,330
Granted Patent B2
US 11,655,330 · App. 16/768,345 · Granted May 23, 2023

Article including a substrate, a phosphate binding layer and a fluoroplyether layer

Inventors: Chad Aaron Meserole (Madison, AL); Abundio Jimenez Sandoval (Decatur, AL)
Assignees: DAIKIN AMERICA, INC.; DAIKIN INDUSTRIES, LTD.
C08G18/6279C08G18/092C09D5/002C09D175/04
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Quick Facts
Patent No.
US 11,655,330
App. No.
16/768,345
Granted
May 23, 2023
Kind
B2
Abstract

An article including a metal substrate, a phosphate binding layer, and a fluoropolyether layer. Also disclosed is a process for producing the article which includes (i) treating a surface of the metal substrate with a phosphoric acid derivative to form the phosphate binding layer on the surface of the metal substrate, and (ii) treating a surface of the phosphate binding layer with a fluoropolyether compound having a fluoropolyether group and a carbon-carbon double bond to form the fluoropolyether layer on the surface of the phosphate binding layer.

Claims (18)

1. An article which comprises a metal substrate, a phosphate binding layer, and a fluoropolyether layer,

wherein

the fluoropolyether layer is formed of a fluoropolyether compound having a fluoropolyether group and a carbon-carbon double bond,

the fluoropolyether compound having a fluoropolyether group and a carbon-carbon double bond is a compound obtained by reacting:

(A) a triisocyanate prepared by trimerizing a diisocyanate, with

(B) a combination of at least two active hydrogen-containing compounds wherein the component (B) comprises:

(B-1) a fluoropolyether having at least one active hydrogen, and

(B-2) a monomer having an active hydrogen atom and a carbon-carbon double bond,

the phosphate binding layer is formed of a phosphoric acid derivative,

the phosphoric acid derivative is a compound of the formula:

wherein:

R 11 is each independently H or a C 1-3 alkyl group,

R 13 is each independently a divalent organic group,

the metal substrate is a SUS substrate.

2. A process for producing the article as claimed in claim 1 , which article comprises a metal substrate, a phosphate binding layer, and a fluoropolyether layer, the process comprising:

(i) treating a surface of the metal substrate with a phosphoric acid derivative to form the phosphate binding layer on the surface of the metal substrate, and

(ii) treating a surface of the phosphate binding layer with a fluoropolyether compound having a fluoropolyether group and a carbon-carbon double bond to form the fluoropolyether layer on the surface of the phosphate binding layer.

3. The process for producing as claimed in claim 2 , the process further comprising irradiating the phosphate binding layer and the fluoropolyether layer with ultraviolet light.

Assignments (2)
CHANGE OF ADDRESS Recorded Jan 11, 2023
From: DAIKIN INDUSTRIES LTD.
To: DAIKIN INDUSTRIES LTD.
Reel/Frame 062355/0740 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded May 29, 2020
From: MESEROLE, CHAD AARON; SANDOVAL, ABUNDIO JIMENEZ
To: DAIKIN AMERICA, INC.; DAIKIN INDUSTRIES, LTD.
Reel/Frame 052789/0461 →
Continuity (2)
Provisional Application 62594425 · Dec 4, 2017
Related Publication 20200362089A1 · Nov 19, 2020