IP Library Granted Patent US 11,870,070
Granted Patent B2
US 11,870,070 · App. 16/771,139 · Granted Jan 9, 2024

Positive electrode active material for secondary battery, method of preparing the same, and lithium secondary battery including the positive electrode active material

Inventors: So Ra Baek (Daejeon, KR); Min Suk Kang (Daejeon, KR); Sang Wook Lee (Daejeon, KR); Wang Mo Jung (Daejeon, KR); Dong Hun Lee (Daejeon, KR); Hye Lim Jeon (Daejeon, KR); Eun Sol Lho (Daejeon, KR)
H01M4/525C01B35/121C01G53/50H01M4/0471H01M4/131H01M4/1315H01M4/1391H01M4/13915H01M4/366H01M4/505H01M4/628H01M10/0525C01P2004/80C01P2006/40C01P2006/80H01M2004/028Y02E60/10
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Quick Facts
Patent No.
US 11,870,070
App. No.
16/771,139
Granted
Jan 9, 2024
Kind
B2
Abstract

A positive electrode active material for a secondary battery includes a lithium composite transition metal oxide including nickel (Ni), cobalt (Co), and manganese (Mn), and a glassy coating layer formed on surfaces of particles of the lithium composite transition metal oxide, wherein, in the lithium composite transition metal oxide, an amount of the nickel (Ni) in a total amount of transition metals is 60 mol % or more, and an amount of the manganese (Mn) is greater than an amount of the cobalt (Co), and the glassy coating layer includes a glassy compound represented by Formula 1. Li a M 1 b O c   [Formula 1] wherein, M 1 is at least one selected from the group consisting of boron (B), aluminum (Al), silicon (Si), titanium (Ti), and phosphorus (P), and 1≤a≤4, 1≤b≤8, and 1≤c≤20.

Claims (12)

1. A method of preparing a positive electrode active material for a secondary battery, the method comprising:

preparing a lithium composite transition metal oxide including nickel (Ni), cobalt (Co), and manganese (Mn); and

forming a coating layer by dry mixing the lithium composite transition metal oxide with a coating source including at least one selected from the group consisting of boron (B), aluminum (Al), silicon (Si), titanium (Ti), and phosphorus (P), and performing a heat treatment at a temperature of 500° C. to 750° C.,

wherein, in the lithium composite transition metal oxide, an amount of the nickel (Ni) in a total amount of transition metals is 60 mol % or more, and an amount of the manganese (Mn) is greater than an amount of the cobalt (Co), and

the coating layer comprises a compound represented by Formula 1:

Li a M 1 b O c   [Formula 1]

wherein, in Formula 1, M 1 is at least one selected from the group consisting of B, Al, Si, Ti, and P, and 1≤a≤4, 1≤b≤8, and 1≤c≤20.

2. The method of claim 1 , wherein, in the forming of the coating layer, a lithium source is not added.

3. The method of claim 1 , wherein an amount of residual lithium by-products in the positive electrode active material is 1.0 wt % or less.

4. The method of claim 1 , wherein the coating source comprises a compound containing at least one selected from the group consisting of boron (B) and aluminum (Al).

5. The method of claim 1 , wherein, in the coating layer, boron and aluminum are included at a ratio of 0.3 part by weight:1 part by weight to 0.8 part by weight:1 part by weight.

6. The method of claim 1 , wherein the coating source is mixed in an amount of 0.02 part by weight to 2.0 parts by weight based on 100 parts by weight of the lithium composite transition metal oxide.

Assignments (2)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Nov 4, 2021
From: LG CHEM, LTD.
To: LG ENERGY SOLUTION, LTD.
Reel/Frame 058295/0068 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jun 10, 2020
From: BAEK, SO RA; KANG, MIN SUK; LEE, SANG WOOK; JUNG, WANG MO; LEE, DONG HUN; JEON, HYE LIM; LHO, EUN SOL
To: LG CHEM, LTD.
Reel/Frame 052891/0352 →
Priority Claims (1)
KR 10-2018-0008909 · Jan 24, 2018 · national
Continuity (1)
Related Publication 20210151754A1 · May 20, 2021