Method for manufacturing perovskite particle light-emitter where organic ligand is substituted, particle light-emitter manufactured thereby, and light emitting device using same
Provided are a method for manufacturing a perovskite nanocrystal particle light-emitter where an organic ligand is substituted, a light-emitter manufactured thereby, and a light emitting device using the same. A method for manufacturing an organic-inorganic-hybrid perovskite nanocrystal particle light-emitter where an organic ligand is substituted may comprise the steps of: preparing a solution including an organic-inorganic-hybrid perovskite nanocrystal particle light-emitter, wherein the organic-inorganic-hybrid perovskite nanocrystal particle light-emitter comprises an organic-inorganic-hybrid perovskite nanocrystal structure and a plurality of first organic ligands surrounding the organic-inorganic-hybrid perovskite nanocrystal structure; and adding, to the solution, a second organic ligand which is shorter than the first organic ligands or includes a phenyl group or a fluorine group, thereby substitutes the first organic ligands with the second organic ligand. Thus, since energy transfer or charge injection into the nanocrystal structure increases through ligand substitution, it is possible to further increase light emitting efficiency and increase durability and stability by means of a hydrophobic ligand.
1. A method for manufacturing an inorganic metal halide perovskite nanocrystal particle light-emitter, in which an organic ligand is substituted, the method comprising:
preparing a solution comprising the inorganic metal halide perovskite nanocrystal particle light-emitter including an inorganic metal halide perovskite nanocrystal structure and a plurality of first organic ligands surrounding a surface of the inorganic metal halide perovskite nanocrystal structure; and
adding a second organic ligand, which has a length less than that of each of the first organic ligands or comprises a phenyl group or fluorine group, to the solution to substitute the first organic ligand with the second organic ligand.
2. The method of claim 1 , wherein each of the first organic ligand and the second organic ligand comprises alkyl halide, and a halogen element of the second organic ligand comprises an element having affinity higher than that of a halogen element of the first organic ligand with respect to a center metal of the inorganic metal halide perovskite nanocrystal structure.
3. The method of claim 1 , wherein the inorganic metal halide perovskite comprises a structure of ABX 3 , A 2 BX 4 , ABX 4 , or A n−1 Pb n X 3n+1 (where n is an integer between 2 to 6), and
the A is an alkali metal, the B is a metal material, and the X is a halogen element.
4. The method of claim 3 , wherein the A is Na, K, Rb, Cs, or Fr, the B is a divalent transition metal, a rare earth metal, an alkali earth metal, Pb, Sn, Ge, Ga, In, Al, Sb, Bi, Po, or a combination thereof, and the X is CI, Br, I, or a combination thereof.