Ink jet method and ink jet apparatus
An ink jet method includes: a discharging step of discharging a radiation-curable ink jet composition onto a recording medium at an ink weight per dot of 22 ng/dot or less by using an ink jet head having a nozzle density of 600 npi or more and configured to discharge the radiation-curable ink jet composition; and an irradiating step of irradiating, with radiation, the radiation-curable ink jet composition attached to the recording medium. The radiation-curable ink jet composition contains polymerizable compounds containing a monofunctional monomer and a multifunctional monomer. The monofunctional monomer includes a nitrogen-containing monofunctional monomer. The amount of the monofunctional monomer is 90 mass % or more relative to the total amount of the polymerizable compound. The amount of the nitrogen-containing monofunctional monomer is from 1 to 15 mass % relative to the total amount of the polymerizable compounds.
1. An ink jet method comprising:
a discharging step of discharging a radiation-curable ink jet composition onto a recording medium at an ink weight per dot of 22 ng/dot or less by using an ink jet head configured to discharge ink droplets at a resolution of 600 dpi or more in one scan; and
an irradiating step of irradiating, with radiation, the radiation-curable ink jet composition attached to the recording medium, wherein
the radiation-curable ink jet composition contains polymerizable compounds including a monofunctional monomer and a multifunctional monomer,
the monofunctional monomer includes a nitrogen-containing monofunctional monomer,
an amount of the monofunctional monomer is 90 mass % or more relative to a total amount of the polymerizable compounds, and
an amount of the nitrogen-containing monofunctional monomer is from 1 to 15 mass % relative to the total amount of the polymerizable compounds.
2. The ink jet method according to claim 1 , wherein a weighted mean of glass transition temperatures of homopolymers of the polymerizable compounds with a content mass ratio of each of the polymerizable compounds taken as a weight is 47° C. or higher.
3. The ink jet method according to claim 1 , wherein
the discharging step involves discharging the radiation-curable ink jet composition from the ink jet head and attaching the radiation-curable ink jet composition to the recording medium while a carriage carrying the ink jet head and a radiation source disposed downstream of the ink jet head in a scanning direction is scanned in a width direction of the recording medium, and
the irradiating step involves irradiating the radiation-curable ink jet composition attached to the recording medium in the scanning with radiation from the radiation source in the same scanning as in the discharging step.
4. The ink jet method according to claim 1 , wherein the nitrogen-containing monofunctional monomer includes either N-vinylcaprolactam or acryloylmorpholine.
5. The ink jet method according to claim 1 , wherein the monofunctional monomer includes one or more selected from the group consisting of phenoxyethyl acrylate, isobornyl acrylate, t-butylcyclohexyl acrylate, dicyclopentenyl acrylate, and dicyclopentanyl acrylate.
6. The ink jet method according to claim 1 , wherein ultraviolet radiation is emitted from an ultraviolet light-emitting diode in the irradiating step.
7. An ink jet apparatus comprising:
an ink jet head having a nozzle density of 600 npi or more and configured to discharge a radiation-curable ink jet composition onto a recording medium at an ink weight per dot of 22 ng/dot or less; and
a radiation source that emits radiation to the radiation-curable ink jet composition attached to the recording medium, wherein
the radiation-curable ink jet composition to be discharged contains polymerizable compounds containing a monofunctional monomer and a multifunctional monomer,
the monofunctional monomer includes a nitrogen-containing monofunctional monomer,
an amount of the monofunctional monomer is 90 mass % or more relative to a total amount of the polymerizable compounds, and
an amount of the nitrogen-containing monofunctional monomer is from 1 to 15 mass % relative to the total amount of the polymerizable compounds.
8. The ink jet apparatus according claim 7 , further comprising a carriage, wherein
the carriage carries the ink jet head, and
the ink jet head discharges the radiation-curable ink jet composition when the carriage is scanned in a width direction of the recording medium.
9. The ink jet apparatus according to claim 7 , wherein the radiation source is carried by a carriage and disposed adjacent to the ink jet head in a scanning direction of the ink jet head.