IP Library Granted Patent US 11,086,028
Granted Patent B2
US 11,086,028 · App. 16/785,932 · Granted Aug 10, 2021

Colorimetric radiation detector

Inventors: Timothy J. Boyle (Albuquerque, NM); Fernando Henry Garzon (Santa Fe, NM)
Assignee: National Technology & Engineering Solutions of Sandia, LLC
G01T1/105G01T1/2045G01T1/2047
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Quick Facts
Patent No.
US 11,086,028
App. No.
16/785,932
Granted
Aug 10, 2021
Kind
B2
Abstract

A low cost, rapid, flexible radiation detector uses inorganic metal halide precursors and dyes that respond to self-quenching hybrid scintillation. Remote, high-contrast, laser sensing can be used to determine when exposure of the detector to radiation occurs (even temporally).

Claims (21)

1. A colorimetric radiation detector, comprising:

a metal halide that decomposes on exposure to radiation; and

a dye whose fluorescence is quenched by a product of the metal halide decomposition.

2. The colorimetric radiation detector of claim 1 , wherein the metal halide comprises a post-transition metal halide.

3. The colorimetric radiation detector of claim 2 , wherein the post-transition metal halide comprises bismuth chloride.

4. The colorimetric radiation detector of claim 1 , wherein the metal halide comprises a transition metal halide or a lanthanide series heavy metal halide.

5. The colorimetric radiation detector of claim 1 , wherein the metal halide comprises a metal chloride.

6. The colorimetric radiation detector of claim 1 , wherein the metal halide further comprises a co-ligand.

7. The colorimetric radiation detector of claim 6 , wherein the co-ligand comprises an alkoxide.

8. The colorimetric radiation detector of claim 1 , wherein the dye comprises fluorescein.

9. The colorimetric radiation detector of claim 1 , further comprising a solvent and wherein the metal halide and the dye are dissolved in the solvent.

10. The colorimetric radiation detector of claim 9 , wherein the solvent comprises a Lewis base solvent.

11. The colorimetric radiation detector of claim 10 , wherein the Lewis base solvent comprises water or an alcohol.

12. The colorimetric radiation detector of claim 9 , wherein the solvent comprises an organic solvent.

13. The colorimetric radiation detector of claim 12 , wherein the organic solvent comprises toluene or xylene.

14. A method for detecting radiation, comprising:

providing a colorimetric radiation detector, the detector comprising:

a metal halide that decomposes on exposure to radiation; and

a dye whose fluorescence is quenched by a product of the metal halide decomposition;

exposing the colorimetric radiation detector to radiation; and

detecting a change in color of the colorimetric radiation detector.

Assignments (4)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jul 20, 2021
From: GARZON, FERNANDO
To: THE REGENTS OF THE UNIVERSITY OF NEW MEXICO
Reel/Frame 056916/0214 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jul 20, 2021
From: THE REGENTS OF THE UNIVERSITY OF NEW MEXICO
To: UNM RAINFOREST INNOVATIONS
Reel/Frame 056916/0285 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded May 12, 2020
From: BOYLE, TIMOTHY J
To: NATIONAL TECHNOLOGY & ENGINEERING SOLUTIONS OF SANDIA, LLC
Reel/Frame 052634/0487 →
CONFIRMATORY LICENSE Recorded Mar 26, 2020
From: NATIONAL TECHNOLOGY & ENGINEERING SOLUTIONS OF SANDIA, LLC
To: U.S. DEPARTMENT OF ENERGY
Reel/Frame 052233/0830 →
Continuity (2)
Provisional Application 62803880 · Feb 11, 2019
Related Publication 20200257004A1 · Aug 13, 2020