IP Library Granted Patent US 11,459,522
Granted Patent B2
US 11,459,522 · App. 16/807,477 · Granted Oct 4, 2022

Oilfield drilling lubricant for water-based and oil-based systems

Inventors: Nicholas Carrejo (Katy, TX); Seth Wiman (Benton, LA)
Assignee: Centurion Technologies, LLC
C10M169/04C09K8/032C09K8/04C09K8/34C09K2208/28C09K2208/34C10M2201/041C10M2201/10C10M2203/1025C10M2207/401C10N2050/015
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Quick Facts
Patent No.
US 11,459,522
App. No.
16/807,477
Granted
Oct 4, 2022
Kind
B2
Abstract

This disclosure provides compositions comprising a suspension package, wherein the suspension packaging consists of solids for suspending in one or more liquids, wherein the solids comprise at least one of: (1) diamond dust, nano-diamonds, or combinations thereof; (2) tungsten; (3) graphite, graphene, or combinations thereof; and (4) silicon carbide. Further, 0.25% through 6% by volume of the composition, with the one or more liquids being present, in a 14.0 ppg aqueous CaBr 2 solution, provides a coefficient of friction of less than 0.06 at a temperature between 250° F. and 400° F. at any time up through 10 minutes after combination of the 0.25% through 6% by volume of the composition to the 14.0 ppg aqueous CaBr 2 .

Claims (21)

1. A composition comprising:

a suspension package, wherein the suspension package comprises solids for suspending in one or more liquids, wherein the solids comprise tungsten and at least one of: (1) diamond dust, nano-diamonds, or combinations thereof; (2) graphite, graphene, or combinations thereof; and (3) silicon carbide,

one or more activators consisting of clay-based activators and optionally: (i) water, (ii) surfactant(s), or (iii) both (i) and (ii); and

one or more clay-based thixotropic additives;

wherein from 0.25% through 6% by volume of the composition, with the one or more liquids being present, in a 14.0 ppg aqueous CaBr 2 solution, provides a coefficient of friction of equal to or less than 0.06 at a temperature between 250° F. and 400° F. at any time up through 10 minutes after combining the 0.25% through 6% by volume of the composition with the 14.0 ppg aqueous CaBr 2 .

2. The composition of claim 1 , wherein the one or more liquids are present in the composition, wherein the one or more liquids comprise one or more vegetable oils.

3. The composition of claim 1 , wherein the suspension package comprises at least two of: (1) diamond dust, nano-diamonds, or combinations thereof; (2) graphite, graphene, or combinations thereof; and (3) silicon carbide.

4. The composition of claim 1 , wherein the one or more liquids are present in the composition, wherein the one or more liquids comprise one or more synthetic oils.

5. The composition of claim 1 , wherein the water is present as one of the one or more activators in the composition.

6. The composition of claim 4 , wherein the one or more liquids further comprise one or more vegetable oils.

7. The composition of claim 1 , wherein the suspension package is 10 wt. % or less of the composition when the one or more liquids are present in the composition.

8. The composition of claim 1 , wherein the particle size of each of the diamond dust, nano-diamonds or combinations thereof is within a range from 5 through 25 nm.

9. The composition of claim 1 , wherein the particle size of each of the graphite, graphene, or combinations thereof is greater than 50 nm.

10. The composition of claim 1 , wherein the particle size of the silicon carbide is within a range from 10 through 160 nm.

11. The composition of claim 1 , wherein the particle size of the tungsten is within a range from 35 through 90 nm.

12. The composition of claim 1 , wherein the suspension package further comprises one or more additives.

13. The composition of claim 1 , wherein the suspension package comprises: (1) diamond dust, nano-diamonds, or combinations thereof; (2) graphite, graphene, or combinations thereof; and (3) silicon carbide.

14. The composition of claim 1 , wherein from 2% through 6% by volume of the composition, with the one or more liquids being present, in a 9.6 ppg aqueous CaCl 2 solution, provides a coefficient of friction of equal to or less than 0.03 at a temperature of 75° F. at any time up through 10 minutes after combining the from 2% through 6% by volume of the composition with the 9.6 ppg aqueous CaCl 2 solution.

15. The composition of claim 1 , wherein from 2% through 6% by volume of the composition, with the one or more liquids being present, in a 11.6 ppg aqueous CaCl 2 solution, provides a coefficient of friction of equal to or less than 0.12 at a temperature of 75° F. at any time up through 10 minutes after combining of the from 2% through 6% by volume of the composition with the 11.6 ppg aqueous CaCl 2 solution.

16. The composition of claim 1 , wherein from 2% through 6% by volume of the composition, with the one or more liquids being present, in a 12.0 ppg aqueous CaBr 2 solution, provides a coefficient of friction of less than 0.04 at a temperature of 75° F. at any time up through 10 minutes after combining of equal to or the from 2% through 6% by volume of the composition with the 12.6 ppg aqueous CaBr 2 solution.

17. The composition of claim 1 , wherein from 2% through 6% by volume of the composition, with the one or more liquids being present, in a 13.0 ppg aqueous CaBr 2 solution, provides a coefficient of friction of equal to or less than 0.11 at a temperature of 75° F. at any time up through 10 minutes after combining of the from 0.25% through 6% by volume of the composition with the 13.0 ppg aqueous CaBr 2 solution.

Assignments (1)
SECURITY INTEREST Recorded Jun 5, 2020
From: CENTURION TECHNOLOGIES LLC
To: ZIONS BANCORPORATION, N.A. DBA AMEGY BANK (F/K/A ZB, N.A. DBA AMEGY BANK)
Reel/Frame 052856/0748 →
Continuity (1)
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