IP Library › Granted Patent US 11,329,257
Granted Patent B2
US 11,329,257 · App. 16/810,107 · Granted May 10, 2022

Organic light-emitting diode display device including a thin film encapsulation layer

Inventors: Yongchan Ju (Yongin-si, KR); Yisu Kim (Seoul, KR); Eungseok Park (Seoul, KR); Wonmin Yun (Suwon-si, KR); Byoungduk Lee (Seongnam-si, KR); Yoonhyeung Cho (Yongin-si, KR)
Assignee: SAMSUNG DISPLAY CO., LTD.
H01L51/5265H01L51/004H01L51/0035H01L51/0037H01L51/0059H01L51/0067H01L51/0072H01L51/5012H01L51/5056H01L51/5072H01L51/5088H01L51/5092H01L51/5218H01L51/5234H01L51/5253H01L51/5275H01L27/3244H01L51/5256H01L2251/5315
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Quick Facts
Patent No.
US 11,329,257
App. No.
16/810,107
Granted
May 10, 2022
Kind
B2
Abstract

A display device includes: a substrate; an organic light-emitting diode positioned above the substrate; and a thin film encapsulation layer disposed on the organic light-emitting diode. The thin film encapsulation layer includes: at least one inorganic layer; and at least one organic layer disposed on the at least one inorganic layer. The at least one organic layer has a refractive index of about 1.66 or greater.

Claims (62)

1. A display device, comprising:

a substrate;

an organic light-emitting diode positioned above the substrate;

a thin film encapsulation layer disposed on the organic light-emitting diode; and

a capping layer disposed between the organic light-emitting diode and the thin film encapsulation layer,

wherein the capping layer has a refractive index in a range from about 1.3 to about 1.4,

wherein the thin film encapsulation layer comprises:

at least one inorganic layer; and

at least one organic layer disposed on the at least one inorganic layer,

wherein the at least one inorganic layer and the at least one organic layer have a refractive index difference of about 0.06 or less.

2. The display device of claim 1 , wherein the at least one organic layer has a refractive index in a range of from about 1.66 to about 2.8.

3. The display device of claim 1 , wherein the at least one inorganic layer has a refractive index in a range of from about 1.6 to about 2.8.

4. The display device of claim 1 , wherein the at least one organic layer is formed by polymerization of at least one monomer selected from: pentabromophenyl acrylate, 2-(9H-carbazol-9-yl) ethyl methacrylate, N-vinylcarbazole, bis (methacryloylthiophenyl) sulfide or zirconium acrylate.

5. The display device of claim 1 , wherein the at least one organic layer comprises at least one of: poly(3,4-ethylenedioxythiophene) (PEDOT), 4,4′-bis[N-(3-methylphenyl)-N-phenylamino]biphenyl (TPD), 4,4′,4″-tris[(3-methylphenyl)phenylamino] triphenylamine (m-MTDATA), 1,3,5-tris[N,N-bis(2-methylphenyl)-amino]benzene (o-MTDAB), 1,3,5-tris[N,N-bis(3-methylphenyl)-amino]benzene (m-MTDAB), 1,3,5-tris[N,N-bis(4-methylphenyl)amino]benzene (p-MTDAB), 4,4′-bis[N,N-bis(3-methylphenyl)-amino] diphenylmethane (BPPM), 4,4-dicarbazolyl-1,1′-biphenyl (CBP), 4,4′,4″-tris(N-carbazole) triphenylamine (TCTA), 2,2′,2″-(1,3,5-benzenetolyl)tris-[1-phenyl-1H-benzoimidazol] (TPBI) or 3-(4-biphenyl)-4-phenyl-5-t-butylphenyl-1,2,4-triazole (TAZ).

6. The display device of claim 1 , wherein the at least one inorganic layer comprises a first inorganic layer and a second inorganic layer, and

the at least one organic layer comprises a first organic layer disposed between the first inorganic layer and the second inorganic layer.

7. The display device of claim 1 , wherein the thin film encapsulation layer comprises:

at least two inorganic layers; and

at least two organic layers alternatingly disposed with the at least two inorganic layers,

wherein the at least two inorganic layers and the at least two organic layers have a refractive index difference of about 0.06 or less.

8. The display device of claim 1 , wherein the organic light-emitting diode comprises:

a first electrode disposed on the substrate;

an organic light-emitting layer disposed on the first electrode; and

a second electrode disposed on the organic light-emitting layer.

9. The display device of claim 8 , wherein the organic light-emitting diode comprises at least one of a hole injection layer and a hole transport layer disposed between the first electrode and the organic light-emitting layer, and at least one of an electron transport layer and an electron injection layer disposed between the organic light-emitting layer and the second electrode.

10. The display device of claim 1 , further comprising a low refractive index layer disposed between the capping layer and the thin film encapsulation layer.

11. The display device of claim 10 , wherein the low refractive index layer has a refractive index in a range of from about 1.3 to about 1.4.

12. The display device of claim 10 , wherein the low refractive index layer comprises lithium fluoride (LiF).

13. A display device, comprising:

a substrate;

an organic light-emitting diode positioned above the substrate; and

a thin film encapsulation layer disposed on the organic light-emitting diode,

wherein the thin film encapsulation layer comprises:

at least one inorganic layer; and

at least one organic layer disposed on the at least one inorganic layer,

wherein the at least one organic layer has a refractive index of about 1.66 or greater,

wherein the at least one organic layer is formed by polymerization of at least one monomer selected from: pentabromophenyl acrylate, 2-(9H-carbazol-9-yl) ethyl methacrylate, N-vinylcarbazole, bis (methacryloylthiophenyl) sulfide or zirconium acrylate.

14. The display device of claim 13 , wherein the at least one organic layer comprises at least one of: poly(3,4-ethylenedioxythiophene) (PEDOT), 4,4′-bis[N-(3-methylphenyl)-N-phenylamino]biphenyl (TPD), 4,4′,4″-tris[(3-methylphenyl)phenylamino] triphenylamine (m-MTDATA), 1,3,5-tris[N,N-bis(2-methylphenyl)-amino]benzene (o-MTDAB), 1,3,5-tris[N,N-bis(3-methylphenyl)-amino]benzene (m-MTDAB), 1,3,5-tris[N,N-bis(4-methylphenyl)amino]benzene (p-MTDAB), 4,4′-bis[N,N-bis(3-methylphenyl)-amino]diphenylmethane (BPPM), 4,4-dicarbazolyl-1,1′-biphenyl (CBP), 4,4′,4″-tris(N-carbazole) triphenylamine (TCTA), 2,2′,2″-(1,3,5-benzenetolyl)tris-[1-phenyl-1H-benzoimidazol] (TPBI) or 3-(4-biphenyl)-4-phenyl-5-t-butylphenyl-1,2,4-triazole (TAZ).

15. The display device of claim 13 ,

wherein the organic light-emitting diode comprises:

a first electrode disposed on the substrate; and

an organic light-emitting layer disposed on the first electrode,

wherein the display device further comprises a first light emission auxiliary layer disposed between the first electrode and the organic light-emitting layer.

16. The display device of claim 15 , wherein the organic light-emitting diode further comprises a second electrode disposed on the organic light-emitting layer,

wherein the display device further comprises a second light emission auxiliary layer disposed between the organic light-emitting layer and the second electrode.

17. A display device, comprising:

a substrate;

an organic light-emitting diode positioned above the substrate; and

a thin film encapsulation layer disposed on the organic light-emitting diode,

wherein the thin film encapsulation layer comprises:

at least one inorganic layer; and

at least one organic layer disposed on the at least one inorganic layer,

wherein the at least one inorganic layer and the at least one organic layer have a refractive index difference of about 0.06 or less,

wherein the at least one organic layer is formed by polymerization of at least one monomer selected from: pentabromophenyl acrylate, 2-(9H-carbazol-9-yl) ethyl methacrylate, N-vinylcarbazole, bis (methacryloylthiophenyl) sulfide or zirconium acrylate.

18. The display device of claim 17 , wherein the at least one organic layer comprises at least one of: poly(3,4-ethylenedioxythiophene) (PEDOT), 4,4′-bis[N-(3-methylphenyl)-N-phenylamino]biphenyl (TPD), 4,4′,4″-tris[(3-methylphenyl)phenylamino] triphenylamine (m-MTDATA), 1,3,5-tris[N,N-bis(2-methylphenyl)-amino]benzene (o-MTDAB), 1,3,5-tris[N,N-bis(3-methylphenyl)-amino]benzene (m-MTDAB), 1,3,5-tris[N,N-bis(4-methylphenyl)amino]benzene (p-MTDAB), 4,4′-bis[N,N-bis(3-methylphenyl)-amino]diphenylmethane (BPPM), 4,4-dicarbazolyl-1,1′-biphenyl (CBP), 4,4′,4″-tris(N-carbazole) triphenylamine (TCTA), 2,2′,2″-(1,3,5-benzenetolyl)tris-[1-phenyl-1H-benzoimidazol] (TPBI) or 3-(4-biphenyl)-4-phenyl-5-t-butylphenyl-1,2,4-triazole (TAZ).

19. The display device of claim 17 ,

wherein the organic light-emitting diode comprises:

a first electrode disposed on the substrate; and

an organic light-emitting layer disposed on the first electrode,

wherein the display device further comprises a first light emission auxiliary layer disposed between the first electrode and the organic light-emitting layer.

20. The display device of claim 19 , wherein the organic light-emitting diode further comprises a second electrode disposed on the organic light-emitting layer,

wherein the display device further comprises a second light emission auxiliary layer disposed between the organic light-emitting layer and the second electrode.

Priority Claims (1)
KR 10-2016-0120123 · Sep 20, 2016 · national
Continuity (2)
Continuation 15704218 · Sep 14, 2017
Related Publication 20200203663A1 · Jun 25, 2020
Cited By (1)
US 12,317,675