IP Library Granted Patent US 11,374,171
Granted Patent B2
US 11,374,171 · App. 16/823,865 · Granted Jun 28, 2022

Memristor and neuromorphic device comprising the same

Inventors: Minhyun Lee (Suwon-si, KR); Dovran Amanov (Cambridge, MA); Renjing Xu (Cambridge, MA); Houk Jang (Cambridge, MA); Haeryong Kim (Seongnam-si, KR); Hyeonjin Shin (Suwon-si, KR); Yeonchoo Cho (Seongnam-si, KR); Donhee Ham (Cambridge, MA)
Assignees: Samsung Electronics Co., Ltd.; President and Fellows of Harvard College
H01L45/1233H01L27/2463H01L45/08H01L45/1266
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Quick Facts
Patent No.
US 11,374,171
App. No.
16/823,865
Granted
Jun 28, 2022
Kind
B2
Abstract

Provided are memristors and neuromorphic devices including the memristors. A memristor includes a lower electrode and an upper electrode that are apart from each other and first and second two-dimensional material layers that are arranged between the lower electrode and the upper electrode and stacked without a chemical bond therebetween.

Claims (40)

1. A memristor comprising:

a lower electrode and an upper electrode that are spaced apart from each other; and

a resistance change layer between the lower electrode and the upper electrode, the resistance change layer including only a first two-dimensional material layer and a second two-dimensional material layer that are stacked on each other as a double-layer,

wherein the lower electrode and the upper electrode include different materials from each other, and

wherein the resistance change layer has resistance characteristics that decrease as a number of sweeps of an applied positive electrical signal increases, and increases as a number of sweeps of an applied negative electrical signal increases,

wherein each of the first two-dimensional material layer and the second two-dimensional material layer includes at least one of MoS 2 , WS 2 , MoSe 2 , WSe 2 , MoTe 2 , WTe 2 , ZrS 2 , ZrSe 2 , HfS 2 , HfSe 2 , GaSe, GaTe, InSe, In 2 Se 3 , Bi 2 Se 3 , and black phosphorus.

2. The memristor of claim 1 , wherein the resistance change layer includes defective grain boundaries.

3. The memristor of claim 2 , wherein

the resistance change layer is configured to form a conductive filament on the defective grain boundaries in response to an application of an electrical signal to the lower electrode and the upper electrode.

4. The memristor of claim 2 , wherein each of the first two-dimensional material layer and the second two-dimensional material layer includes line-type defects.

5. The memristor of claim 1 , wherein the resistance change layer includes dot-type defects.

6. The memristor of claim 1 , wherein the memristor is configured to operate with a set voltage in a range that is equal to or higher than 0.1 V and equal to or lower than 0.5 V.

7. The memristor of claim 1 , wherein the memristor is configured to perform a bipolar resistive switching operation.

8. The memristor of claim 1 , wherein, in the memristor after undergoing a forming operation,

an ohmic conduction slope of the memristor in a high resistance state is constant, and

an ohmic conduction slope of the memristor in a low resistance state is constant.

9. The memristor of claim 8 , wherein the ohmic conduction slope of the memristor in the high resistance state, the low resistance state, or both the high resistance state and the low resistance state is in a range of 0.8 to 1.2.

10. The memristor of claim 1 , wherein a distance between the lower electrode and the upper electrode is two to ten times a size of atoms in the resistance change layer.

11. The memristor of claim 1 , wherein the first two-dimensional material laver and the second two-dimensional material include a same material.

12. The memristor of claim 1 , wherein the first two-dimensional material layer and the second two-dimensional material layer have semiconductor characteristics.

13. The memristor of claim 1 , wherein each of the first two-dimensional material layer and the second two-dimensional material layer is a single layer.

14. The memristor of claim 1 , wherein at least one of the lower electrode and the upper electrode includes a metal.

15. The memristor of claim 1 , wherein

the first two-dimensional material layer directly contacts the lower electrode and the second two-dimensional material layer, and

the second two-dimensional material layer directly contacts the upper electrode.

16. The memristor of claim 1 , wherein

one of the lower electrode and the upper electrode includes an active electrode, and

an other of the lower electrode and the upper electrode includes a non-active electrode.

17. The memristor of claim 1 , wherein the resistance change layer is arranged in an area where the lower electrode and the upper electrode overlap each other.

18. The memristor of claim 1 , wherein the upper electrode, the first two-dimensional material layer, the second two-dimensional material layer, and the lower electrode are sequentially arranged to contact each other.

19. The memristor of claim 1 , wherein

the upper electrode includes a plurality of first electrodes that are spaced apart from each other in a first direction perpendicular to a thickness direction of the resistance change layer,

the lower electrode includes a plurality of second electrodes that are spaced apart from each other in a second direction that is perpendicular to the thickness direction of the resistance change layer, and

the second direction is different than the first direction.

20. The memristor of claim 19 , wherein

the resistance change layer includes a plurality of sub-resistance change layers that are arranged in an area where the plurality of first electrodes and the plurality of second electrodes overlap with each other, and

the plurality of sub-resistance change layers are spaced apart from each other.

21. A device comprising:

the memristor according to claim 1 .

22. The device of claim 21 , wherein the device is a neuromorphic device, memory device, or computing device.

Assignments (4)
CONFIRMATORY LICENSE Recorded May 24, 2024
From: HARVARD UNIVERSITY
To: NATIONAL SCIENCE FOUNDATION
Reel/Frame 067528/0549 →
CONFIRMATORY LICENSE Recorded Jan 31, 2024
From: HARVARD UNIVERSITY
To: NATIONAL SCIENCE FOUNDATION
Reel/Frame 066383/0462 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jul 24, 2020
From: LEE, MINHYUN; KIM, HAERYONG; SHIN, HYEONJIN; CHO, YEONCHOO
To: SAMSUNG ELECTRONICS CO., LTD.
Reel/Frame 053304/0116 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jul 24, 2020
From: HAM, DONHEE; AMANOV, DOVRAN; XU, RENJING; JANG, HOUK
To: PRESIDENT AND FELLOWS OF HARVARD COLLEGE
Reel/Frame 053304/0257 →
Priority Claims (1)
KR 10-2019-0112371 · Sep 10, 2019 · national
Continuity (2)
Provisional Application 62862172 · Jun 17, 2019
Related Publication 20200395540A1 · Dec 17, 2020