Refrigeration cycles with liquid-liquid phase transitions
The present invention pertains to cooling, heating, and refrigeration cycles using, for example, phase transitions to pump heat. Embodiments of the present invention may comprise systems, methods, or processes for liquid-liquid phase transition refrigeration cycles pumping heat across temperature differences greater than the adiabatic temperature change of a liquid-liquid phase transition within said liquid-liquid phase transition refrigeration cycle. Embodiments of the present invention also may comprise powering said liquid-liquid phase transition refrigeration cycle using electricity, heat, ‘cold’, the mixing of a saltwater and freshwater, the mixing of high osmotic pressure liquid and low osmotic pressure liquid, or a combination thereof.
1. A refrigeration cycle process comprising:
endothermically liquid-liquid phase transitioning a first composition in a first temperature zone; and
exothermically liquid-liquid phase transitioning a second composition in a second temperature zone;
wherein the first temperature zone is operably connected to the second temperature zone; and
wherein said second temperature zone is greater in temperature than said first temperature zone.
2. The process of claim 1 wherein said second temperature zone is greater in temperature than said first temperature zone by a temperature differential which is greater than (1) an adiabatic temperature change of the exothermic phase transition, or (2) an adiabatic temperature change of the endothermic phase transition, or (3) both (1) and (2).
3. The process of claim 1 further comprising heat exchanging at least a portion of the first composition in the first temperature zone with at least a portion of the second composition in the operably connected second temperature zone.
4. The process of claim 1 wherein said endothermic liquid-liquid phase transitioning occurs at a lesser temperature than said exothermic phase transitioning due to a phase transition temperature adjustment.
5. The process of claim 4 wherein said phase transition temperature adjustment comprises adjusting the concentration of a reagent.
6. The process of claim 1 wherein said endothermic phase transitioning, or said exothermic phase transitioning, or both occurs due to a change in a concentration of a reagent.
7. The process of claim 6 wherein said change in concentration of a reagent comprises using a membrane-based process selected from reverse osmosis, forward osmosis, nanofiltration, osmotically assisted reverse osmosis, ultrafiltration, or a combination thereof.
8. The process of claim 6 which further comprises reversing said change in concentration of a reagent.