IP Library Granted Patent US 11,008,645
Granted Patent B2
US 11,008,645 · App. 16/839,507 · Granted May 18, 2021

Wear-resistant Cu—Ni—Sn coating

Inventors: Fritz C. Grensing (Perrysburg, OH); Robert E. Kusner (Mayfield Heights, OH); David J. Krus (Mayfield Heights, OH); William D. Nielsen (Kingwood, TX); Karl Ziegler (Mayfield Heights, OH)
Assignee: MATERION CORPORATION
C23C4/08C22C9/06C23C24/04F16C33/121F16C2223/42
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Quick Facts
Patent No.
US 11,008,645
App. No.
16/839,507
Granted
May 18, 2021
Kind
B2
Abstract

The present disclosure relates to a method of applying a wear-resistant copper-nickel-tin coating to a substrate using a thermal spray process. Briefly, a copper-nickel-tin alloy feedstock is converted into a powder or droplet form, then sprayed onto a substrate to form a coating thereon.

Claims (16)

1. An article, comprising:

a substrate, and

a spinodal coating adhered to the substrate at an interface therebetween,

wherein the coating comprises a copper-nickel-tin-alloy, the coating having a thickness of at least 100 micrometers.

2. The article of claim 1 , wherein the coating has a thickness of about 100 micrometers to about 2000 micrometers.

3. The article of claim 1 , wherein the coating is deposited by a thermal spray process.

4. The article of claim 3 , wherein the thermal spray process is a cold spray, plasma spray, warm spray, detonation spray, high-velocity oxy fuel spray, or arc spray process.

5. The article of claim 3 , wherein the spraying occurs at a pressure of about 20 bar to about 40 bar.

6. The article of claim 3 , wherein the alloy mixture has a temperature of about 350° C. to about 700° C.

7. The article of claim 3 , wherein the alloy mixture is sprayed at a velocity of 50 m/s to 1500 m/s.

8. The article of claim 1 , wherein the copper-nickel-tin alloy is about 8 wt % to about 22 wt % nickel, about 4 wt % to about 10 wt % tin, and the remaining balance is copper.

9. The article of claim 1 , wherein the article is a ring.

10. A device containing an article therein, wherein the article comprises:

a substrate, and

a spinodal coating adhered to the substrate at an interface therebetween, and

wherein the coating comprises a copper-nickel-tin-alloy.

Assignments (2)
SECURITY INTEREST Recorded Oct 27, 2021
From: MATERION CORPORATION
To: JPMORGAN CHASE BANK, N.A., AS ADMINISTRATIVE AGENT
Reel/Frame 057937/0428 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Apr 3, 2020
From: GRENSING, FRITZ C.; KRUS, DAVID J.; KUSNER, ROBERT E.; NIELSEN, WILLIAM D.; ZIEGLER, KARL
To: MATERION CORPORATION
Reel/Frame 052306/0040 →
Continuity (3)
Continuation 15792295 · Oct 24, 2017
Provisional Application 62411828 · Oct 24, 2016
Related Publication 20200232084A1 · Jul 23, 2020