Nonaqueous electrolyte secondary battery laminated separator
The present invention provides a nonaqueous electrolyte secondary battery laminated separator which improves a long-term battery characteristic of a nonaqueous electrolyte secondary battery. According to the nonaqueous electrolyte secondary battery laminated separator in accordance with an aspect of the present invention, an absolute value of a difference between (i) a standard deviation of whiteness index in one outermost layer and (ii) a standard deviation of whiteness index of the other outermost layer is greater than 0.01 and is 0.60 or less, and a greater one of the two standard deviation values of whiteness index is 0.06 or more and 0.91 or less.
1. A nonaqueous electrolyte secondary battery laminated separator comprising:
a polyolefin porous film; and
a nonaqueous electrolyte secondary battery porous layer which is stacked on one surface or both surfaces of the polyolefin porous film,
an absolute value of a difference between (i) a standard deviation value of a whiteness index defined in E313 of the American Standards Test Methods in a first outermost layer of said nonaqueous electrolyte secondary battery laminated separator and (ii) a standard deviation value of the whiteness index of a second outermost layer of said nonaqueous electrolyte secondary battery laminated separator being greater than 0.01 and being 0.60 or less,
a greater one of the standard deviation value of the whiteness index in the first outermost layer and the standard deviation value of the whiteness index in the second outermost layer being 0.06 or more and 0.91 or less.
2. The nonaqueous electrolyte secondary battery laminated separator as set forth in claim 1 , wherein:
the first outermost layer is the polyolefin porous film; and
the second outermost layer is the nonaqueous electrolyte secondary battery porous layer.
3. The nonaqueous electrolyte secondary battery laminated separator as set forth in claim 1 , wherein the nonaqueous electrolyte secondary battery porous layer contains one or more resins selected from the group consisting of polyolefin, a (meth)acrylate resin, a fluorine-containing resin, a polyamide resin, a polyester resin, and a water-soluble polymer.
4. The nonaqueous electrolyte secondary battery laminated separator as set forth in claim 1 , wherein the nonaqueous electrolyte secondary battery porous layer contains a polyamide resin.
5. The nonaqueous electrolyte secondary battery laminated separator as set forth in claim 4 , wherein the polyamide resin is an aramid resin.
6. The nonaqueous electrolyte secondary battery laminated separator as set forth in claim 5 , wherein the aramid resin is one or more aramid resins selected from the group consisting of poly(paraphenylene terephthalamide), poly(metaphenylene terephthalamide), and a paraphenylene terephthalamide/metaphenylene terephthalamide copolymer.
7. The nonaqueous electrolyte secondary battery laminated separator as set forth in claim 1 , wherein the nonaqueous electrolyte secondary battery porous layer contains a heat-resistant filler.
8. The nonaqueous electrolyte secondary battery laminated separator as set forth in claim 7 , wherein the heat-resistant filler is an inorganic filler.
9. The nonaqueous electrolyte secondary battery laminated separator as set forth in claim 8 , wherein the inorganic filler contains one or more inorganic substances selected from the group consisting of alumina, boehmite, aluminum hydroxide, magnesium hydroxide, magnesium oxide, titanium oxide, and silica.
10. A nonaqueous electrolyte secondary battery comprising a nonaqueous electrolyte secondary battery laminated separator recited in claim 1 .