Processes for the removal of rubber from non-hevea plants
Provided herein are organic solvent-based processes for the removal of rubber from non- Hevea plants such as guayule shrubs. By the use of the processes, solid purified rubber can be obtained that contains 0.05-0.5 weight % dirt, 0.2-1.5 weight % ash, and 0.1-4 weight % resin (when it has been dried so as to contain 0.8 weight % volatile matter).
1. An organic solvent-based process for the removal of rubber from guayule plant matter comprising:
a. utilizing a slurry containing (i) guayule plant matter, the guayule plant matter comprising bagasse, rubber and resin; (ii) at least one non-polar organic solvent; and (iii) at least one polar organic solvent, wherein the slurry contains 10-50% by weight plant matter, 50-90% by weight of (ii) and (iii) combined, and 0.5-10 weight % water from the plant matter, and wherein the at least one polar organic solvent and at least one non-polar organic solvent are present in relative weight amounts of 50-90% and 10-50%, respectively;
b. removing a majority of the bagasse from the slurry to produce a miscella and a first bagasse portion;
c. removing 80-95 weight % of bagasse from the miscella, based on the total weight of bagasse present in the miscella, to form a purified miscella and a second bagasse fraction wherein the majority of the bagasse that is removed has a particle size of less than 105 microns;
d. increasing the relative amount of polar organic solvent as compared to non-polar organic solvent within the purified miscella so as to coagulate rubber having a molecular weight of at least 1 million grams/mole; and
e. producing solid purified rubber from the coagulated rubber where when said solid purified rubber contains 0.8 weight % volatile matter it also contains 0.05-0.5 weight % dirt, 0.2-1.5 weight % ash and 0.1-4 weight % resin;
wherein at least (a)-(c) are conducted at a temperature or temperatures of 10-80° C. and a pressure of 35 to 1000 kPa.
2. The process of claim 1 , wherein in (d) the relative amount of polar organic solvent as compared to non-polar organic solvent within the clarified rubber solution is increased by adding additional polar organic solvent.
3. The process of claim 1 , wherein in (d) the relative amount of polar organic solvent as compared to non-polar organic solvent within the clarified rubber solution is increased by removing non-polar organic solvent.
4. The process of claim 1 , wherein in (d), the coagulated rubber has a molecular weight of at least 1 million to 1.5 million grams/mole.
5. The process of claim 2 , wherein in (d), the coagulated rubber has a molecular weight of at least 1 million to 1.5 million grams/mole.
6. The process of claim 3 , wherein in (d), the coagulated rubber has a molecular weight of at 1 million to 1.5 million grams/mole.
7. The process of claim 1 , wherein in (d), the coagulated rubber has a molecular weight of about 1.5 million grams/mole.
8. The process of claim 2 , wherein in (d), the coagulated rubber has a molecular weight of about 1.5 million grams/mole.
9. The process of claim 3 , wherein in (d), the coagulated rubber has a molecular weight of about 1.5 million grams/mole.
10. The process of claim 1 , wherein the at least one polar solvent in (a) and (d) comprises acetone.
11. The process of claim 1 , wherein the at least one non-polar solvent in (a) and (d) comprises at least one of hexane and cyclohexane.
12. An organic solvent-based process for the removal of rubber from guayule plant matter comprising:
a. utilizing a slurry containing (i) guayule plant matter, the guayule plant matter comprising bagasse, rubber and resin; (ii) at least one non-polar organic solvent; and (iii) at least one polar organic solvent, wherein the slurry contains 10-50% by weight plant matter, 50-90% by weight of (ii) and (iii) combined, and 0.5-10 weight % water from the plant matter, and wherein the at least one polar organic solvent and at least one non-polar organic solvent are present in relative weight amounts of 50-90% and 10-50%, respectively;
b. removing a majority of the bagasse from the slurry to produce a miscella and a first bagasse portion;
c. optionally adding additional polar organic solvent, non-polar organic solvent or a combination thereof to the miscella to form a reduced viscosity miscella where any polar organic solvent and non-polar organic solvent may be the same or different than those utilized in (a) and where the amount of any additional polar organic solvent that is added is less than the amount that causes the rubber contained with the reduced viscosity miscella to coagulate
d. removing 80-95 weight % of bagasse from the miscella resulting from (b) or (c), based on the total weight of bagasse present in the miscella, to form a purified miscella and a second bagasse fraction wherein the majority of the bagasse that is removed has a particle size of less than 105 microns;
e. optionally treating the purified miscella to remove additional bagasse thereby producing a clarified rubber solution that contains 0.01-1% by weight of bagasse, based on the total weight of bagasse present in the slurry, wherein 90-99% of the additional bagasse that is removed has a particle size greater than 45 microns;
f. using a cone-shaped fractionator to increase the relative amount of polar organic solvent as compared to non-polar organic solvent within the purified miscella so as to coagulate rubber having a molecular weight of 1 million to about 1.5 million grams/mole; and
g. producing solid purified rubber from the coagulated rubber where when said solid purified rubber contains 0.8 weight % volatile matter it also contains 0.05-0.5 weight % dirt, 0.2-1.5 weight % ash and 0.1-4 weight % resin;
wherein at least (a)-(e) are conducted at a temperature or temperatures of 10-80° C. and a pressure of 35 to 1000 kPa, wherein the at least one polar solvent in (a), (c) and (f) comprises acetone, and wherein the at least one non-polar solvent in (a), (c) and (f) comprises at least one of hexane and cyclohexane.
13. The process of claim 12 , wherein in (f) the relative amount of polar organic solvent as compared to non-polar organic solvent within the clarified rubber solution is increased by adding additional polar organic solvent.
14. The process of claim 12 , wherein in (f) the relative amount of polar organic solvent as compared to non-polar organic solvent within the clarified rubber solution is increased by removing non-polar organic solvent.
15. The process of claim 12 , wherein in (f), the coagulated rubber has a molecular weight of about 1.5 million grams/mole.
16. The process of claim 13 , wherein in (f), the coagulated rubber has a molecular weight of about 1.5 million grams/mole.
17. The process of claim 14 , wherein in (f), the coagulated rubber has a molecular weight of about 1.5 million grams/mole.
18. The process of claim 12 , wherein (c) is not optional.
19. The process of claim 12 , wherein (e) is not optional.
20. The process of claim 18 , wherein (e) is not optional.