Composite graphene structures
Graphene has been used in nanocomposites as constituents/doping in plastics or epoxy providing dramatic enhancement of the mechanical properties but have not progressed past the laboratory level novelty. This invention can provide a graphene based composite structure with a density less that 1.9 g/cm 3 for a fiber, yarn, rope or cable and a density less that 1.5 g/cm 3 for a sheet both structure have tensile and shear strength greater than either Aluminum or Steel; thus providing a graphene material that is both much lighter and stronger.
1. A method of making a high-strength composite, comprising:
plating a conducting surface on a substrate;
electroplating flat graphene flakes onto the conducting surface from a carrier fluid suspension of the graphene flakes in a vessel to give a plated layer, wherein the flakes have an average width of 0.5 to 100 microns;
removing the plated substrate from the vessel;
drying to remove the carrier fluid from the plated graphene;
applying a layer of polymer containing a solvent to infiltrate between the graphene flakes, wherein the polymer comprises an epoxy and forms a chemical bond to the graphene, and the solvent containing polymer has a viscosity between 1 and 30,000 centipoises;
removing air from between the graphene flakes infiltrated by the layer of polymer; and
removing the solvent from the polymer and leaving the polymer chemically bonded to the graphene.
2. The method of claim 1 , wherein the substrate is a fiber or has a flat surface, a shaped surface, or a formed surface.
3. The method of claim 1 , wherein the substrate is at least one of a plastic, a wood, a metal, or a grass.
4. The method of claim 1 , wherein the substrate is formed before the plating of the conducting surface.
5. The method of claim 1 , wherein the drying to remove the carrier fluid is done in a vacuum-furnace chamber.
6. The method of claim 1 , wherein the removing of the solvent from the polymer is done in a vacuum-furnace chamber.
7. The method of claim 1 , wherein the polymer further comprises is at least one of a thermoplastic or a thermosetting polymer.
8. The method of claim 1 , wherein the polymer further comprises a mixture of thermoplastic and thermosetting plastics.
9. The method of claim 1 , wherein the graphene flakes are 5 to 50 micron across.
10. The method of claim 1 , wherein the graphene flakes are 5 to 20 micron across.
11. The method of claim 1 , wherein the graphene flakes are 5 to 14 micron across.
12. The method of claim 1 , wherein the removing air from between the graphene flakes from the layer of polymer is vacuum facilitated.
13. The method of claim 1 , wherein the conducting surface is nickel or copper.
14. The method of claim 3 , wherein the grass is bamboo.
15. The method of claim 1 , wherein the carrier fluid is water.
16. A method of making a high-strength composite, comprising:
plating a conducting surface on a substrate;
electroplating flat graphene flakes onto the conducting surface from a suspension of the graphene flakes in a carrier fluid in a vessel to give a plated layer, wherein the flakes are 5 to 20 micron across;
removing the plated substrate from the vessel;
drying to remove the carrier fluid from the plated graphene;
applying a layer of polymer containing a solvent to infiltrate between the graphene flakes, wherein the polymer comprises an epoxy and forms a chemical bond to the graphene, and the solvent-containing polymer has a viscosity between 1 and 30,000 centipoises;
and removing solvent from the polymer and air from between the graphene flakes infiltrated by the layer of polymer and leaving the polymer chemically bonded to the graphene.
17. The method of claim 16 , wherein the removing solvent from the polymer and air from between the graphene flakes from said polymer layer is vacuum facilitated.