Transport stabilization of portable items

1. A transport stabilizing combination for stabilizing an item during conditions of movement comprising:

A. a vehicular support member having at least one exposed surface, and

B. a cohesive and adhesive viscoelastomeric thermoset overlay;

wherein the viscoelastomeric thermoset overlay is disposed upon the at least one exposed surface of the vehicular support member.

2. The transport stabilizing combination of claim 1 further comprising a vehicle.

3. The transport stabilizing combination of claim 1 wherein the viscoelastomeric thermoset overlay is formed from a thermosetting reaction media comprising:

A. about 1 wt % to about 10 wt % isocyanate prepolymer;

B. about 35 wt % to about 70 wt % polyols; and

C. about 20 wt % to about 55 wt % plasticizer;

wherein the polyols comprise a straight chain linking diol and a crosslinking triol present in a diol to triol weight ratio of about 1:3 to about 3:1; and

wherein the plasticizer comprises about 20 wt % to about 50 wt % of the total reaction media weight triglyceride plasticizer and 0 wt % to about 40 wt % of the total reaction media weight ester plasticizer.

4. The transport stabilizing combination of claim 3 wherein the isocyanate prepolymer comprises a diisocyanate prepolymer.

5. The transport stabilizing combination of claim 3 wherein the straight chain linking diol comprises a polyether diol and the crosslinking triol comprises a polyether triol.

6. The transport stabilizing combination of claim 5 wherein the polyether diol and the polyether triol each have a molecular weight of about 1,000 to about 10,000.

7. The transport stabilizing combination of claim 3 wherein the triglyceride plasticizer and the ester plasticizer are present in the thermosetting reaction media in a triglyceride plasticizer to ester plasticizer weight ratio of about 1:0 to about 1:1.

8. The transport stabilizing combination of claim 3 wherein the triglyceride plasticizer comprises an epoxidized triglyceride plasticizer.

9. The transport stabilizing combination of claim 8 wherein the epoxidized triglyceride plasticizer comprises an epoxidized vegetable oil.

10. The transport stabilizing combination of claim 9 wherein the epoxidized vegetable oil comprises an epoxidized soybean oil.

11. The transport stabilizing combination of claim 3 wherein the ester plasticizer has a dipole moment of at least 1.5 D.

12. The transport stabilizing combination of claim 3 wherein the ester plasticizer has a molecular weight of less than about 750.

13. The transport stabilizing combination of claim 12 wherein the ester plasticizer is selected from the group consisting of sebacates, adipates, phthalates, isophthalates, maleates, azelates and glutarates.

14. The transport stabilizing combination of claim 13 wherein the ester plasticizer comprises dibutyl sebacate.

15. The transport stabilizing combination of claim 14 wherein the dibutyl sebacate is present in an amount of about 2 wt % to about 20 wt % of the total reaction media weight.

16. The transport stabilizing combination of claim 3 wherein the thermosetting reaction media is reacted in the presence of a catalytic amount of a catalyst.

17. The transport stabilizing combination of claim 16 wherein the catalyst is an organobismuth catalyst.

18. The transport stabilizing combination of claim 3 further comprising a colorant.

19. The transport stabilizing combination of claim 3 further comprising a UV inhibitor.

20. The transport stabilizing combination of claim 1 wherein the viscoelastomeric thermoset overlay has been prefabricated prior to being disposed upon the at least one exposed surface of the vehicular support member.

21. The transport stabilizing combination of claim 20 wherein the viscoelastomeric thermoset overlay has a thickness of about 1 mm to about 25 mm.

22. The transport stabilizing combination of claim 1 wherein the viscoelastomeric thermoset overlay has been cured in situ upon the at least one exposed surface of the vehicular support member.

23. The transport stabilizing combination of claim 22 wherein the viscoelastomeric thermoset overlay has a thickness of about 0.3 mm to about 20 mm.

24. A transport stabilizing combination for adhesively restraining and cohesively releasing a portable item stowed at a stabilized position comprising:

A. a vehicle;

B. a vehicular support member disposed upon the vehicle and having a sufficient size and structural integrity to support a portable item; and

C. a viscoelastomeric thermoset overlay possessing sufficient adhesiveness and cohesiveness to restrain the portable item at a stabilized position and to release the portable item upon application of a force sufficient to overcome an adhesive attraction between the portable item and the viscoelastomeric thermoset overlay while leaving no more than a nominal amount of a polymer residue upon the portable item;

wherein the viscoelastomeric thermoset overlay is disposed upon at least a portion of the vehicular support member.

25. The transport stabilizing combination of claim 24 wherein the viscoelastomeric thermoset overlay comprises a substantially uniform admixture of:

A. about 4 wt % to about 8 wt % diisocyanate prepolymer;

B. about 35 wt % to about 70 wt % polyols; and

C. about 20 wt % to about 55 wt % plasticizer;

wherein the polyols comprise polyether diols and polyether triols in a diol to triol weight ratio of about 3:1 to about 1:3; and

wherein the plasticizer comprises about 20 wt % to about 50 wt % epoxidized triglyceride plasticizer and 0 wt % to about 40 wt % ester plasticizer.

26. The transport stabilizing combination of claim 25 wherein the diisocyanate prepolymer comprises methylene diphenyl diisocyanate.

27. The transport stabilizing combination of claim 25 wherein the epoxidized triglyceride plasticizer comprises an epoxidized vegetable oil plasticizer.

28. The transport stabilizing combination of claim 27 wherein the epoxidized vegetable oil plasticizer comprises epoxidized soybean oil.

29. The transport stabilizing combination of claim 25 wherein the ester plasticizer comprises dibutyl sebacate.

30. The transport stabilizing combination of claim 24 wherein the vehicular support member is flexible.

31. A method for making a transport stabilizing combination for stabilizing a portable item upon a vehicle during conditions of movement comprising:

A. providing a vehicle comprising a vehicular support member having at least one exposed surface;

B. providing a thermosetting reaction media comprising:

1) about 1 wt % to about 10 wt % diisocyanate prepolymer;

2) about 10 wt % to about 40 wt % polyether diol having a molecular weight ranging from about 2,000 to about 6,000;

3) about 10 wt % to about 50 wt % polyether triol having a molecular weight ranging from about 3,000 to about 7,000;

4) about 20 wt % to about 50 wt % epoxidized vegetable oil plasticizer, and

5) 0 wt % to about 40 wt % ester plasticizer having a molecular weight of less than about 750; and

C. performing one of the following first or second sequence of steps;

wherein the first sequence of steps comprises:

1) disposing a quantity of the thermosetting reaction media upon the at least one exposed surface of the vehicular support member; and

2) allowing the quantity of the thermosetting reaction media to fully cure to form a viscoelastomeric thermoset overlay, to provide the transport stabilizing combination; and

wherein the second sequence of steps comprises:

1) allowing a quantity of the thermosetting reaction media to fully cure to form a viscoelastomeric thermoset overlay; and

2) disposing the viscoelastomeric thermoset overlay upon the at least one exposed surface of the vehicular support member, to provide the transport stabilizing combination.

32. The method of claim 31 wherein the diisocyanate prepolymer comprises methylene diphenyl diisocyanate.

33. The method of claim 31 wherein the epoxidized vegetable oil plasticizer comprises epoxidized soybean oil.

34. The method of claim 31 wherein the ester plasticizer comprises dibutyl sebacate.