Method for sulfur removal from coal fly ash
A method of reducing sulfur concentration in fly ash, flue gas desulfurization (FGD) ash, and mixtures thereof by contacting the fly ash, FGD ash, or mixtures thereof with an aqueous acidic solution, for a time, at a temperature, and at a liquid-to-solid ratio wherein the sulfur concentration within the fly ash, FGD ash, or mixture thereof is reduced to no more than 5 wt % SO 3 based on the total weight of dry fly ash, FGD ash, or mixture thereof so treated.
1. A method of reducing sulfur concentration in fly ash, flue gas desulfurization (FGD) ash, and mixtures thereof, the method comprising contacting fly ash, FGD ash, or mixtures thereof with an aqueous acidic solution, for a time, at a temperature, and at a liquid-to-solid ratio wherein sulfur concentration within the fly ash, FGD ash, or mixture thereof is reduced to no more than 5 wt % SO 3 based on total weight of dry fly ash, FGD ash, or mixture thereof so contacted.
2. The method of claim 1 , comprising contacting the fly ash, FGD ash, or mixtures thereof with the aqueous, acidic solution at a liquid-to-solid ratio of no more than 2 liters aqueous, acidic solution per gram of fly ash, FGD ash, or mixture thereof.
3. The method of claim 1 , comprising contacting the fly ash, FGD ash, or mixtures thereof with the aqueous, acidic solution at a liquid-to-solid ratio of no more than 1 liter aqueous, acidic solution per gram of fly ash, FGD ash, or mixture thereof.
4. The method of claim 1 , comprising contacting the fly ash, FGD ash, or mixtures thereof with the aqueous, acidic solution at a liquid-to-solid ratio of no more than 100 mL aqueous, acidic solution per gram of fly ash, FGD ash, or mixture thereof.
5. The method of claim 1 , comprising contacting the fly ash, FGD ash, or mixtures thereof with the aqueous, acidic solution at a liquid-to-solid ratio of no more than 50 mL aqueous, acidic solution per gram of fly ash, FGD ash, or mixture thereof.
6. The method of claim 1 , comprising contacting the fly ash, FGD ash, or mixtures thereof with the aqueous, acidic solution at a liquid-to-solid ratio of no more than 25 mL aqueous, acidic solution per gram of fly ash, FGD ash, or mixture thereof.
7. The method claim 1 , wherein pH of the aqueous, acidic solution is from about 2.0 to about 6.5.
8. The method claim 1 , wherein pH of the aqueous, acidic solution is from about 4.0 to about 6.0.
9. The method claim 1 , wherein pH of the aqueous, acidic solution is from about 4.0 to about 5.0.
10. The method of claim 1 , wherein the aqueous acidic solution comprises carbonic acid.
11. The method of claim 10 , wherein the fly ash, FGD ash, or mixture thereof is contacted with water in the presence of a gas phase comprising a partial pressure of carbon dioxide of from about 0.12 atm to about 10 atm.
12. The method of claim 10 , wherein the fly ash, FGD ash, or mixture thereof is contacted with water in the presence of a gas phase comprising a partial pressure of carbon dioxide of from about 1 atm to about 5 atm.
13. The method of claim 1 , wherein the aqueous acidic solution comprises a mineral acid.
14. The method of claim 13 , wherein the mineral acid is selected from the group consisting of hydrochloric acid (HCl), nitric acid (HNO 3 ), phosphoric acid (H 3 PO 4 ), sulfuric acid (H 2 SO 4 ), boric acid (H 3 BO 3 ), hydrofluoric acid (HF), hydrobromic acid (HBr), and perchloric acid (HClO 4 ).
15. The method of claim 1 , wherein the fly ash, FGD ash, or mixture thereof is contacted with the aqueous acidic solution at a liquid-to-solid ratio wherein hydrogen ion concentration ([H + ]) in the aqueous acidic solution is at least 1.95 mmol [H + ] per mole of sulfur to be washed.