Liquid formulations of urease inhibitors for fertilizers
An improved solvent system for the formulation and application of N-alkyl thiophosphoric triamide urease inhibitors. These formulations provide safety and performance benefits relative to existing alternatives and enable storage, transport and subsequent coating or blending with urea based or organic based fertilizers. These formulations are comprised primarily of environmentally friendly aprotic and protic solvents (particularly dimethyl sulfoxide and alcohols/polyols) to stabilize the urease inhibitor.
1. A composition of a liquid fertilizer additive solution comprising a) urease inhibitor, b) dimethyl sulfoxide, and optionally c) dyes and colorants, wherein said urease inhibitor comprises N-(n-butyl) thiophosphoric triamide (NBPT) and wherein said liquid fertilizer additive solution comprises a compositional weight percent of at least 40% of said urease inhibitor.
2. The composition of claim 1 , wherein a compositional weight of said N-(n-butyl) thiophosphoric triamide comprises at least 58.9%.
3. The composition of claim 1 , wherein a compositional weight % of said N-(n-butyl) thiophosphoric triamide comprises 40% to 50%.
4. The composition of claim 1 , wherein a compositional weight % of said N-(n-butyl) thiophosphoric triamide comprises 40% to 45%.
5. The composition of claim 1 , wherein a compositional weight % of said N-(n-butyl) thiophosphoric triamide comprises 45% to 58.9%.
6. The composition of claim 1 , wherein a compositional weight % of said N-(n-butyl) thiophosphoric triamide comprises 45% to 50%.
7. The composition of claim 1 , wherein a compositional weight % of said N-(n-butyl) thiophosphoric triamide comprises 50% to 58.9%.
8. The composition of claim 1 , wherein the composition further comprises one or more solvents selected from the group consisting of a) one or more aprotic solvents, and b) one or more protic solvents.
9. The composition of claim 8 , wherein the composition of said one or more solvents comprises an aprotic solvent.
10. The composition of claim 8 , wherein the one or more aprotic solvents comprises one or more members selected from the group consisting of a) one or more alkylene carbonates selected from the group consisting of i) propylene carbonate, ii) ethylene carbonate and iii) butylene carbonate, b) 2-methoxyethyl ether, c) cyclohexylpyrrolidone, d) 1,3 dimethyl-2-imidazolidinone e) acetone, and f) hexamethyl phosphoramide.
11. The composition of claim 8 , wherein the one or more protic solvents comprises one or more members selected from the group consisting of a) one or more alkylene glycols, c) one or more poly(alkylene) glycols, d) glycerin, c) glycerol derivatives, f) one or more alkanolamines, and g) one or more alkyl lactates selected from the group consisting of i) ethyl lactate, ii) propyl lactate, and iii) butyl lactate.
12. The composition of claim 11 , wherein the one or more alkylene glycols comprise one or more members selected from the group consisting of a) ethylene glycol, b) propylene glycol, and c) butylene glycol, wherein the one or more poly(alkylene) glycols comprise one or more members selected from the group consisting of a) polymethylene glycols, b) polyethylene glycols, c) polypropylene glycols, and d) polybutylene glycols, and wherein the one or more alkanolamines comprise one or more members selected from the group consisting of a) ethanolamine, b) diethanolamine, c) dipropanolamine, d) methyl diethanolamine, e) monoisopropanolamine, and f) triethanolamine.
13. The composition of claim 1 , wherein the composition further comprises one or more members selected from the group consisting of a) flow aids, b) silicas, and c) surfactants.
14. The composition of claim 1 , wherein the composition comprises dyes/colorants and wherein the dyes/colorants provide a visual confirmation that the composition of claim 1 has been delivered as an even coating to urea.
15. The composition of claim 1 , wherein the composition further comprises a) urea and optionally b) one or more members selected from the group consisting of i) urea formaldehyde polymer and ii) dicyandiamide.
16. The composition of claim 15 , wherein the composition further comprises a) urea, b) one or more solvents selected from the group consisting of one or more aprotic solvents and one or more protic solvents and optionally c) one or more members selected from the group consisting of i) urea formaldehyde polymer and ii) dicyandiamide.
17. The composition of claim 1 , wherein the composition further comprises a) water, b) urea, and c) optionally one or more members selected from the group consisting of i) urea formaldehyde polymer and ii) dicyandiamide thereby resulting in a liquid urea fertilizer.
18. The composition of claim 1 , wherein said liquid fertilizer additive solution is combined with a nitrogen fertilizer comprising of one or more members selected from the group consisting of a) one or more dry nitrogen fertilizers and b) one or more liquid nitrogen fertilizers, wherein said nitrogen fertilizers are made more effective when applied to the soil for plant growth, wherein the composition reduces hydrolysis of urea to ammonia, thereby reducing ammonia losses to an atmosphere resulting in improved nitrogen retention in soil.
19. A composition of a liquid fertilizer additive solution comprising a) at least 50% by weight N-(n-butyl) thiophosphoric triamide (NBPT), and b) dimethyl sulfoxide.
20. The composition of claim 19 , wherein the composition further comprises an aprotic solvent other than dimethyl sulfoxide.
21. The composition of claim 19 , wherein the composition further comprises dyes/colorants.