Coated films and electronic devices
In a first aspect, a coated film includes a polyimide film, a curable resin coating composition and an adhesion-promoter. The curable resin coating composition includes a curable oligomer and first nanoparticles. The adhesion-promoter includes a polyamic acid composition and is on a surface of the polyimide film that is in contact with the curable resin coating composition. In a second aspect, an electronic device includes the coated film of first aspect.
1. A coated film comprising:
a polyimide film;
a curable resin coating composition comprising a curable oligomer and first nanoparticles; and
an adhesion-promoter comprising a polyamic acid composition, wherein the adhesion-promoter is on a surface of the polyimide film that is in contact with the curable resin coating composition.
2. The coated film of claim 1 , wherein the curable oligomer is selected from the group consisting of (meth)acrylate oligomers, urethane oligomers, (meth)acrylate-urethane oligomers, siloxane oligomers, and combinations thereof.
3. The coated film of claim 1 , wherein the curable resin coating composition further comprises an organic coating solvent selected from the group consisting of 2,6-dimethylcyclohexanone, 2,4-dimethyl-3-pentanone; 2,4-dimethyl-3-pentanol, 2,2,4,4-tetramethyl-3-pentanone, 2,6-dimethyl-4-heptanone, and methyl 2-hydroxy-2-methylpropanoate, isopropyl acetate and isoamyl acetate.
4. The coated film of claim 1 , wherein the first nanoparticles comprise inorganic particles and are present in an amount of from 35 to 66 wt %, based on the total weight of the composition excluding organic solvent.
5. The coated film of claim 4 , wherein the inorganic particles comprise non-porous nanoparticles of silica, a metal oxide, or a mixture thereof.
6. The coated film of claim 1 , wherein the adhesion-promoter further comprises filler.
7. The coated film of claim 6 , wherein the filler comprises second nanoparticles.
8. The coated film of claim 1 , wherein the polyimide comprises a dianhydride selected from the group consisting of 3,3′,4,4′-biphenyl tetracarboxylic dianhydride, pyromellitic dianhydride, cyclobutane-1,2,3,4-tetracarboxylic dianhydride (CBDA); 4,4′-(hexafluoroisopropylidene)diphthalic anhydride and mixtures thereof.
9. The coated film of claim 1 , wherein the polyimide comprises a fluorinated dianhydride.
10. The coated film of claim 9 , wherein the fluorinated dianhydride comprises 4,4′-(hexafluoroisopropylidene)diphthalic anhydride.
11. The coated film of claim 1 , wherein the polyimide comprises a fluorinated diamine.
12. The coated film of claim 11 , wherein the fluorinated diamine comprises 2,2′-bis(trifluoromethyl) benzidine.
13. An electronic device comprising the coated film of claim 1 .
14. The electronic device of claim 13 , wherein the coated film is used in device components selected from the group consisting of substrates for color filter sheets, cover sheets, and touch sensor panels.
15. The electronic device of claim 14 , wherein the cover sheet further comprises an anti-reflection layer.