Nanoparticle capsules for photonic crystal color display in magnetic field
View Patent ↗Described are composite photonic materials that incorporate magnetic nanoparticles inside hollow or solvent-filled nano-scale or micro-scale shells and methods of making and using such composite photonic materials. When these photonic materials are present in a magnetic field, they exhibit a change in reflected, scattered, and/or transmitted light as compared to when the materials are not in the presence of the magnetic field. This results in the materials appearing to have a different color, such as when observed by the human eye or a light detecting device, such as a camera.
1. A method of preparing a composite photonic material comprising:
aggregating a plurality of photonic nanoparticles comprising a magnetic material;
coating the plurality of photonic nanoparticles with a polymer material;
forming an oxide material around the coated plurality of photonic nanoparticles; and
removing the polymer material to form a hollow shell comprising the oxide material within which the plurality of photonic nanoparticles are disposed, thereby preparing the composite photonic material.
2. The method of claim 1 , further comprising:
introducing a solvent within the hollow shell and surrounding the plurality of photonic nanoparticles.
3. The method of claim 2 , wherein introducing the solvent comprises:
evacuating the composite photonic material; and
dissolving the composite photonic material in the solvent.
4. The method of claim 2 , wherein a viscosity of the solvent determines a time scale over which the plurality of photonic nanoparticles transitions from an aligned arrangement in a presence of a magnetic field to a randomly distributed arrangement when not in the presence of the magnetic field, wherein the plurality of photonic nanoparticles reflect a first wavelength of electromagnetic radiation in a visible spectrum when in the randomly distributed arrangement, and wherein the plurality of photonic nanoparticles reflect a second wavelength of electromagnetic radiation in the visible spectrum when in the aligned arrangement, the second wavelength being different than the first wavelength.
5. The method of claim 2 , further comprising:
sealing the hollow shell after introducing the solvent.
6. The method of claim 5 , wherein sealing the hollow shell comprises forming an additional oxide material on an outer surface of the hollow shell, wherein the additional oxide material is selected from the group consisting of SiO 2 , Al 2 O 3 , and ZnO.
7. The method of claim 2 , wherein the solvent comprises one or more members selected from the group consisting of H 2 O, C 6 H 14 , C 2 H 6 O 2 , C 3 H 8 O, C 6 H 14 O, and mineral oil.
8. The method of claim 1 , wherein removing the polymer material comprises performing a removal process at a temperature of about 300 to about 500° C.
9. The method of claim 8 , wherein the removal process is selected from the group consisting of chemical etching and calcination.
10. The method of claim 1 , wherein the oxide material is selected from the group consisting of SiO 2 , Al 2 O 3 , and ZnO.
11. The method of claim 1 , wherein the magnetic material is selected from the group consisting of an iron oxide and an iron oxide composite material.
12. The method of claim 1 , wherein the polymer material comprises (C 8 H 8 ) n .
13. The method of claim 1 , further comprising:
applying heat to the composite photonic material to cure the hollow shell.