Filtration apparatus containing graphene oxide membrane
Embodiments described herein relate generally to graphene oxide membranes for fluid filtration and more specifically to graphene oxide membranes having tunable permeability, rejection rate, and flux. Some embodiments of the graphene oxide membranes disclosed herein are characterized as having a flux of at least about 2.5×10 −4 gallons per square foot per day per psi with a 1 wt % lactose solution at room temperature, and a lactose rejection rate of at least 50% with a 1 wt % lactose solution.
1. A filtration apparatus, comprising:
a support substrate; and
a graphene oxide membrane disposed on the support substrate, the graphene oxide membrane including a plurality of graphene oxide sheets, each of the graphene oxide sheets coupled to an adjacent graphene oxide sheet via a chemical linker, the chemical linker having Formula Ia-1:
or Formula Ib:
wherein:
L 1 is selected from —NH—, —C(═O)—NH—, or absent;
L 2 is selected from —C(═O)—NH—(CH 2 ) n —, —(CH 2 ) 2 —O—(CH 2 ) n —, or —NH—(CH 2 ) n —;
L 3 is selected from —C(═O)—NH—(CH 2 ) m —, —C(═O)—NH—C(═O)—(CH 3 ) 2 —S—(CH 2 ) m —, or —NH—C(═O)—(CH 3 ) 2 —S—(CH 2 ) m —;
A 2 is selected from aryl, heteroaryl, C 4 -C 10 heterocycloalkyl, C 4 -C 10 cycloalkyl, or C 4 -C 10 alkyl, wherein the aryl, heteroaryl, heterocycloalkyl, cycloalkyl, and alkyl can each be optionally substituted by one or more substituents selected from halo, C 1 -C 4 alkoxy, or C 1 -C 4 alkyl;
n is 0-4;
m is 0-4;
denotes the point of coupling with a carbon atom on a graphene oxide sheet;
the graphene oxide membrane has a flux of at least about 2.5×10 −4 gallons per square foot per day per psi (GFD/psi) with a 1 wt % lactose solution at room temperature, and
the graphene oxide membrane has a lactose rejection rate of at least 50% with a 1 wt % lactose solution.
2. The filtration apparatus of claim 1 , wherein the lactose rejection rate is measured at room temperature.
3. The filtration apparatus of claim 1 , wherein the support substrate is a microporous polymer substrate.
4. The filtration apparatus of claim 1 , wherein the support substrate has a root mean squared surface roughness of less than about 3 μm.
5. The filtration apparatus of claim 1 , wherein the support substrate has an average pore size of 0.1 μm to 5 μm.
6. The filtration apparatus of claim 1 , wherein the support substrate includes a material selected from polypropylene, polystyrene, polyethylene, polyethylene oxide, polyethersulfone, polytetrafluoroethylene, polyvinylidene fluoride, polymethylmethacrylate, polydimethylsiloxane, polyester, cellulose, cellulose acetate, cellulose nitrate, polyacrylonitrile, glass fiber, quartz, alumina, silver, polycarbonate, nylon, Kevlar or other aramid, or polyether ether ketone.
7. The filtration apparatus of claim 1 , wherein the graphene oxide membrane has a flux of at least about 2.5×10 −3 GFD/psi with a 1 wt % lactose solution at room temperature.
8. The filtration apparatus of claim 1 , wherein the graphene oxide membrane has a lactose rejection rate of at least 95% with a 1 wt % lactose solution.
9. The filtration apparatus of claim 1 , wherein the graphene oxide membrane has a MgSO 4 rejection rate of at least 30% with a 0.1 wt % MgSO 4 solution.
10. The filtration apparatus of claim 1 , including about 0.1 mg to 6 mg of the graphene oxide membrane per 5000 mm 2 .
11. The filtration apparatus of claim 1 , wherein n is 0 or 1.
12. The filtration apparatus of claim 1 , wherein A 2 is phenyl or linear C 5 -C 6 alkyl.
13. The filtration apparatus of claim 1 , wherein the chemical linker has Formula Ib-1:
14. The filtration apparatus of claim 1 , wherein m is 0 or 1.
15. A method for processing black liquor, the method comprising flowing black liquor through the filtration apparatus of claim 1 , wherein the black liquor comprises lignin, sodium sulfate, sodium carbonate, sodium hydrosulfide, sodium thiosulfate, sodium hydroxide, or a combination thereof.
16. The method of claim 15 , wherein at least 50% of the lignin, sodium sulfate, sodium carbonate, sodium hydrosulfide, sodium thiosulfate, or sodium hydroxide is rejected by the graphene oxide membrane.
17. A filtration apparatus, comprising:
a support substrate; and
a graphene oxide membrane disposed on the support substrate, the graphene oxide membrane including a plurality of graphene oxide sheets, each of the graphene oxide sheets coupled to an adjacent graphene oxide sheet via a chemical linker, the chemical linker having Formula Ia-1:
or Formula Ib:
wherein:
L 1 is selected from —NH—, —C(═O)—NH—, or absent;
L 2 is selected from —C(═O)—NH—(CH 2 ) n —, —(CH 2 ) 2 —O—(CH 2 ) n —, or —NH—(CH 2 ) n —;
L 3 is selected from —C(═O)—NH—(CH 2 ) m —, —C(═O)—NH—C(═O)—(CH 3 ) 2 —S—(CH 2 ) m —, or —NH—C(═O)—(CH 3 ) 2 —S—(CH 2 ) m —;
A 2 is selected from aryl, heteroaryl, C 4 -C 10 heterocycloalkyl, C 4 -C 10 cycloalkyl, or C 4 -C 10 alkyl, wherein the aryl, heteroaryl, heterocycloalkyl, cycloalkyl, and alkyl can each be optionally substituted by one or more substituents selected from halo, C 1 -C 4 alkoxy, or C 1 -C 4 alkyl;
n is 0-4;
m is 0-4;
denotes the point of coupling with a carbon atom on a graphene oxide sheet;
the graphene oxide membrane has a first lactose rejection rate of at least 50% with a first 1 wt % lactose solution at room temperature; and
after the graphene oxide membrane is contacted with a solution that is at least 80° C. for a period of time, the graphene oxide membrane has a second lactose rejection rate of at least 50% with a second 1 wt % lactose solution at room temperature.
18. A filtration apparatus, comprising:
a support substrate; and
a graphene oxide membrane disposed on the support substrate, the graphene oxide membrane including a plurality of graphene oxide sheets, each of the graphene oxide sheets coupled to an adjacent graphene oxide sheet via a chemical linker, the chemical linker having Formula Ia-1:
or Formula Ib:
wherein:
L 1 is selected from —NH—, —C(═O)—NH—, or absent;
L 2 is selected from —C(═O)—NH—(CH 2 ) n —, —(CH 2 ) 2 —O—(CH 2 ) n —, or —NH—(CH 2 ) n —;
L 3 is selected from —C(═O)—NH—(CH 2 ) m —, —(═O)—NH—C(═O)—(CH 3 ) 2 —S—(CH 2 ) m —, or —NH—C(═O)—(CH 3 ) 2 —S—(CH 2 ) m —;
A 2 is selected from aryl, heteroaryl, C 4 -C 10 heterocycloalkyl, C 4 -C 10 cycloalkyl, or C 4 -C 10 alkyl, wherein the aryl, heteroaryl, heterocycloalkyl, cycloalkyl, and alkyl can each be optionally substituted by one or more substituents selected from halo, C 1 -C 4 alkoxy, or C 1 -C 4 alkyl;
n is 0-4;
m is 0-4;
denotes the point of coupling with a carbon atom on a graphene oxide sheet;
the graphene oxide membrane has a first lactose rejection rate of at least 50% with a first 1 wt % lactose solution at room temperature; and
after the graphene oxide membrane is contacted with a solution having a pH of at least 11 for a period of time at room temperature, the graphene oxide membrane has a second lactose rejection rate of at least 50% with a second 1 wt % lactose solution at room temperature.