Selective carbon dioxide reduction catalyzed by single metal sites on carbon nitride under visible light irradiation
A composition of a photocatalyst, a method of manufacturing the photocatalyst, and a method of chemically reducing carbon dioxide to carbon monoxide using the photocatalyst under visible-light irradiation is provided. The photocatalyst comprises a transition metal ion and graphitic carbon nitride and includes single metal sites on carbon nitride. Under visible light, the metal sites that are coordinated to nitrogen atoms get activated, without the use of additional ligands, to catalyze the reduction of carbon dioxide to selectively produce carbon monoxide. The photocatalytic reduction of carbon dioxide to carbon monoxide is highly efficient, resulting a turnover number of more than 800 for carbon monoxide production in 2 hours. The composition is useful in converting carbon dioxide into useful chemicals and carbon-based fuels. A functional model of molecular catalysts for efficient carbon dioxide reduction is also present.
1. A photocatalyst comprising:
graphitic carbon nitride flakes providing nitrogen atoms for direct coordination with a transition metal ion in absence of additional ligands, the transition metal ion forming four coordinate bonds with the nitrogen atoms at edge sites of the graphitic carbon nitride flakes, two of the coordinate bonds with nitrogen atoms on an edge site of a first flake and two of the coordinate bonds with nitrogen atoms on an edge site of a second flake.
2. The photocatalyst of claim 1 , wherein the transition metal ion is Co 2+ .
3. The photocatalyst of claim 2 , wherein Co 2+ is at a concentration between 0.004 and 0.430 μmol/mg of the photocatalyst.
4. The photocatalyst of claim 2 , wherein Co 2+ is atomically dispersed on the graphitic carbon nitride flakes.
5. The photocatalyst of claim 2 , wherein a molar ratio of Co 2+ to cobalt oxide in the photocatalyst is greater than 1000.
6. The photocatalyst of claim 1 , wherein the graphitic carbon nitride flakes are planar.
7. The photocatalyst of claim 1 , wherein the graphitic carbon nitride flakes include carbon doping.
8. The photocatalyst of claim 1 , wherein the transition metal ion is positioned outside a plane formed by the nitrogen atoms by a distance less than 0.5 Angstrom.
9. The photocatalyst of claim 1 , wherein the transition metal ion forms coordinate bonds with four nitrogen atoms at edge sites of the graphitic carbon nitride flakes.
10. The photocatalyst of claim 1 , comprising a transition metal selected from Ni, Fe, Cu, Pt, Pd, and Co.