Glass for chemical strengthening
The present invention relates to a glass for chemical strengthening including, in mole percentage on an oxide basis: 45 to 75% of SiO 2 ; 1 to 30% of Al 2 O 3 ; 1 to 20% of Li 2 O; 0 to 5% of Y 2 O 3 ; 0 to 5% of ZrO 2 ; and 0 to 1% of TiO 2 , having a total content of one or more kinds of MgO, CaO, SrO, BaO and ZnO of 1 to 20%, having a total content of Na 2 O and K 2 O of 0 to 10%, having a total content of B 2 O 3 and P 2 O 5 of 0 to 10%, and having a value M expressed by the following expression of 1,000 or more: M=−5×[SiO 2 ]+121×[Al 2 O 3 ]+50×[Li 2 O]−35×[Na 2 O]+32×[K 2 O]+85×[MgO]+54×[CaO]−41×[Sr O]−4×[P 2 O 5 ]+218×[Y 2 O 3 ]+436×[ZrO 2 ]−1180, in which each of [SiO 2 ], [Al 2 O 3 ], [Li 2 O], [Na 2 O], [K 2 O], [MgO], [CaO], [SrO], [P 2 O 5 ], [Y 2 O 3 ], and [ZrO 2 ] designates a content of each component in mole percentage on an oxide basis.
1. A glass for chemical strengthening comprising, in mole percentage on an oxide basis:
45 to 75% of SiO 2 ;
9 to 30% of Al 2 O 3 ;
1 to 20% of Li 2 O;
0.1 to 5% of Y 2 O 3 ,
0 to 1.5% of ZrO 2 ; and
0 to 1% of TiO 2 ,
having a total content of one or more kinds of MgO, CaO, SrO, BaO and ZnO of 1 to 20%,
having a total content of Na 2 O and K 2 O of from 1.5% to 10%,
having a total content of B 2 O 3 and P 2 O 5 of 0 to 10%,
wherein a ratio [Li 2 O]/([Na 2 O]+[K 2 O]) is from 0.5 to 3, and
having a value M expressed by the following expression of 1,000 or more:
M=−5×[SiO 2 ]+121×[Al 2 O 3 ]+50×[Li 2 O]−35×[Na 2 O]+32×[K 2 O]+85×[MgO]+54×[Ca O]−41×[SrO]−4×[P 2 O 5 ]+218×[Y 2 O 3 ]+436×[ZrO 2 ]−1180.
wherein each of [SiO 2 ], [Al 2 O 3 ], [Li 2 o], [Na 2 O], [K 2 O], [MgO], [CaO], [SrO], [P 2 O 5 ]; [Y 2 O 3 ], and [ZrO 2 ] designates a content of each component in mole percentage on an oxide basis.
2. The glass for chemical strengthening according to claim 1 , having the value I expressed by the following expression of 850 or less:
I=−4.8×[SiO 2 ]+102×[Al 2 O 3 ]+81×[Li 2 O]−272×[Na 2 O]−281×[K 2 O]−16×[MgO]−25×[Y 2 O 3 ]+0.028×[ZrO 2 ]+63
wherein each of [SiO 2 ], [Al 2 O], [Na 2 O], [K 2 O], [MgO], [Y 2 O 3 ], and [ZrO 2 ] designates a content of each component in mole percentage on an oxide basis.
3. The glass for chemical strengthening according to claim 1 , having the value 12 expressed by the following expression of 5 or less:
I2=0.27×[SiO 2 ]+1.4×[Al 2 O 3 ]−1.1×[Na 2 ]−1.7×[K 2 O]+0.38×[MgO]−1.36×[Y 2 O 3 ]−0.59×[ZrO 2 ]−23
wherein each of [SiO 2 ], [Al 2 O 3 ], [Na 2 O], [K 2 O], [MgO], [Y 2 O 3 ], and [ZrO 2 ] designates a content of each component in mole percentage on an oxide basis.
4. The glass for chemical strengthening according to claim 1 , having a temperature (T4) at which a viscosity is 10 4 dPa·s of 1,350° C. or lower.
5. The glass for chemical strengthening according to claim 1 , wherein when the glass is chemically strengthened by an immersion in a sodium nitrate at 450° C. for I hour, a surface compressive stress value thereof is 300 MPa or more, and
when the glass is chemically strengthened by an immersion in a sodium nitrate at 450° C. for 3 hour and a subsequent immersion in a potassium nitrate at 450° C. for 1.5 hours, a surface compressive stress value thereof is 800 MPa or more.